Citation: SUI Jing-Ting, CHEN Zi-Yu, LIU Gui-Xia, SONG Chao, DONG Xiang-Ting. Synthesis and Properties of Core-Shell Structure Ag@BaGdF₅: Yb³⁺, Ho³⁺ Multifunctional Nanocomposites[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(6): 987-995. doi: 10.11862/CJIC.2019.119 shu

Synthesis and Properties of Core-Shell Structure Ag@BaGdF₅: Yb³⁺, Ho³⁺ Multifunctional Nanocomposites

Key Laboratory of Applied Chemistry and Nanotechnology at Universities of Jilin Province, School of Chemistry and Environmental Engineering, Changchun University of Science and Technology, Changchun 130022, China

Corresponding author: LIU Gui-Xia, liuguixia22@163.com SONG Chao, songchaocc@126.com
Received Date: 26 December 2018
Revised Date: 27 March 2019

Figures(11)

Core-shell structure multifunctional Ag@BaGdF₅:Yb³⁺, Ho³⁺ nanocomposites were prepared by a simple wet method. XRD patterns showed that the nanocomposites consisted of cubic phase Ag and BaGdF₅. Electron microscope images indicated that the nanocomposites were spherical shape with the thickness of~14 nm (BaGdF₅:Yb³⁺, Ho³⁺ as shell) and a diameter of 77 nm (Ag nanoparticles as core). The nanocomposites had good upconversion emission with the strongest green emission centered at about 540 nm from the photoluminescence spectra, which is helpful to apply in intracellular imaging to diagnose lesion. Furthermore, the samples possessed better paramagnetism and photothermal conversion properties. MTT measurement demonstrates that the nanocomposites have better biocompatibility. When incubated with HeLa cells, the nanocomposites had bright green upconversion imaging under 980 nm irradiation. Compared with commercial computed tomography (CT) imaging contrast agent iobitridol, the Ag@BaGdF₅:Yb³⁺, Ho³⁺ nanocomposites had higher CT imaging properties. The heat converted from the nanocomposites could kill HeLa cells.
- nanostructures,
- fluorescence,
- nanocomposites,
- upconversion
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Synthesis and Properties of Core-Shell Structure Ag@BaGdF5: Yb3+, Ho3+ Multifunctional Nanocomposites

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通讯作者: 陈斌, bchen63@163.com

Synthesis and Properties of Core-Shell Structure Ag@BaGdF₅: Yb³⁺, Ho³⁺ Multifunctional Nanocomposites