Citation: ZHAO Chen, ZHANG Ting, HE Yong, QU Liang-Wu, ZHOU Qing-Jun. Preparation and Performance of Sr₃Fe_2-xNi_xO_7-δ (x=0, 0.1, 0.2, 0.3) Cathode for Intermediate-Temperature Solid Oxide Fuel Cells[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(6): 1027-1033. doi: 10.11862/CJIC.2019.113 shu

Preparation and Performance of Sr₃Fe_2-xNi_xO_7-δ (x=0, 0.1, 0.2, 0.3) Cathode for Intermediate-Temperature Solid Oxide Fuel Cells

College of Science, Civil Aviation University of China, Tianjin 300300, China

Corresponding author: ZHOU Qing-Jun, qjzhou@cauc.edu.cn
Received Date: 10 January 2019
Revised Date: 28 March 2019

Figures(6)

Sr₃Fe_2-xNi_xO_7-δ (x=0, 0.1, 0.2, 0.3) were synthesized by a modified complexing sol-gel process as cathode for intermediate temperature solid oxide fuel cells (IT-SOFCs). The phase structure, thermodynamic properties and electrochemical properties of the materials were characterized by X-ray diffraction, thermal expansion coefficient test, conductivity test, polarization impedance (R_p) test and single cell performance test. The results showed that all samples were successfully synthesized with perovskite-like structure. The Sr₃Fe_2-xNi_xO_7-δ cathode exhibited good chemical compatibility with the Ce_0.8Sm_0.2O_1.9 (SDC) electrolyte at 1 000℃ for 5 h. The coefficient of thermal expansion (TEC) decreased with the increase of x, and the minimum value was 1.839×10^-5 K^-1. Its high temperature conductivity increased with the increase of Ni doping content, and SFN30 had the highest conductivity of 101 S·cm^-1. The R_p of this series of samples showed a trend of decrease first and then increase with the increase of the doping content of Ni. SFN10 had the lowest polarization impedance of 0.078 8 Ω·cm² at 800℃. The trend of the output power of the electrolyte-supported cell was consistent with the trend of polarization impedance. The SFN10 achieved an output power density of 421.6 mW·cm^-2 at 800℃.
- Sr₃Fe_2-xNi_xO_7-δ,
- perovskite-like structure,
- intermediate temperature solid oxide fuel cells,
- cathode material
1. [1]
  Tsipis E V, Kharton V V. J. Solid State Electrochem., 2011, 15:1007-1040 doi: 10.1007/s10008-011-1341-8
2. [2]
  Jacobson A J. Chem. Mater., 2010, 22:660-674 doi: 10.1021/cm902640j
3. [3]
  Cheng Y, Zhou Q J, Chen L B, et al. Mater. Lett., 2017, 193:105-107 doi: 10.1016/j.matlet.2017.01.066
4. [4]
  Inprasit T, Skinner S J, Burriel M, et al. RSC Adv., 2015, 5:2486-2492 doi: 10.1039/C4RA11672K
5. [5]
  Pelosato R, Cordaro G, Stucchi D, et al. J. Power Sources, 2015, 298:46-67 doi: 10.1016/j.jpowsour.2015.08.034
6. [6]
  Khandale A P, Punde J D, Bhoga S S. J. Solid State Electrochem., 2013, 17:617-626 doi: 10.1007/s10008-012-1892-3
7. [7]
  Yoo S Y, Choi S, Shin J, et al. RSC Adv., 2012, 2:4648-4655 doi: 10.1039/c2ra20402a
8. [8]
  Zhou X D, Templeton J W, Nie Z, et al. Electrochim. Acta, 2012, 71:44-49 doi: 10.1016/j.electacta.2012.03.067
9. [9]
  Sun C, Hui R, Roller J. J. Solid State Electrochem., 2010, 14:1125-1144 doi: 10.1007/s10008-009-0932-0
10. [10]
  Laberty C, Zhao F, Virkar A V. J. Solid State Electrochem., 2007, 10:170-174 doi: 10.1149/1.2760188
11. [11]
  Takahashi S, Nishimoto S, Matsuda M, et al. J. Am. Ceram. Soc., 2010, 93:2329-2333 doi: 10.1111/jace.2010.93.issue-8
12. [12]
  Wang Z Q, Yang W Q, Shafi S P, et al. J. Mater. Chem. A, 2015, 3:8405-8412 doi: 10.1039/C5TA00391A
13. [13]
  Sharma R K, Celikbilek O, Burriel M, et al. ECS Trans., 2016, 72:1-8
14. [14]
  Mogni L, Prado F, Caneiro A. Chem. Mater., 2006, 18:4163-4170 doi: 10.1021/cm0604007
15. [15]
  Huan D M, Wang Z Q, Wang Z B, et al. ACS Appl. Mater. Interfaces, 2016, 8:4592-4599 doi: 10.1021/acsami.5b10844
16. [16]
  Shannon R D. Acta Cryst., 1976, 32:751-767 doi: 10.1107/S0567739476001551
17. [17]
  Zhou Q J, Wei T, Shi Y H, et al. Curr. Appl. Phys., 2012, 12:1092-1095 doi: 10.1016/j.cap.2012.01.012
18. [18]
  Wei B, Lü Z, Huang X Q, et al. J. Eur. Ceram. Soc., 2006, 26:2827-2832 doi: 10.1016/j.jeurceramsoc.2005.06.047
19. [19]
  Zhou Q J, Gao Y, Wang F, et al. Ceram. Int., 2015, 41:639-643 doi: 10.1016/j.ceramint.2014.08.114
20. [20]
  Zhao C, Zhou Q J, Zhang T, et al. Mater. Res. Bull., 2019, 113:25-30 doi: 10.1016/j.materresbull.2019.01.016
21. [21]
  Wang Y X, Zhao X Y, Lü S Q, et al. Ceram. Int., 2014, 40:7321-7327 doi: 10.1016/j.ceramint.2013.12.074
22. [22]
  Mogni L, Prado F, Caneiro A, et al. Solid State Ionics, 2006, 177:1807-1810 doi: 10.1016/j.ssi.2006.03.050
23. [23]
  Hyodo J, Tominaga K, Ju Y W, et al. Solid State Ionics, 2014, 256:5-10 doi: 10.1016/j.ssi.2013.12.036
24. [24]
  Mogni L, Prado F, Ascolani H, et al. J. Solid State Chem., 2005, 178:1559-1568 doi: 10.1016/j.jssc.2005.02.018
1. [1]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
2. [2]
  Zeyuan WANG , Songzhi ZHENG , Hao LI , Jingbo WENG , Wei WANG , Yang WANG , Weihai SUN . Effect of I₂ interface modification engineering on the performance of all-inorganic CsPbBr₃ perovskite solar cells. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1290-1300. doi: 10.11862/CJIC.20240021
3. [3]
  Xiaoyao YIN , Wenhao ZHU , Puyao SHI , Zongsheng LI , Yichao WANG , Nengmin ZHU , Yang WANG , Weihai SUN . Fabrication of all-inorganic CsPbBr₃ perovskite solar cells with SnCl₂ interface modification. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 469-479. doi: 10.11862/CJIC.20240309
4. [4]
  Ru SONG , Biao WANG , Chunling LU , Bingbing NIU , Dongchao QIU . Electrochemical properties of stable and highly active PrBa_0.5Sr_0.5Fe_1.6Ni_0.4O_5+δ cathode material. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 639-649. doi: 10.11862/CJIC.20240397
5. [5]
  Rui Li , Huan Liu , Yinan Jiao , Shengjian Qin , Jie Meng , Jiayu Song , Rongrong Yan , Hang Su , Hengbin Chen , Zixuan Shang , Jinjin Zhao . 卤化物钙钛矿的单双向离子迁移. Acta Physico-Chimica Sinica, 2024, 40(11): 2311011-. doi: 10.3866/PKU.WHXB202311011
6. [6]
  Xinyuan Shi , Chenyangjiang , Changyu Zhai , Xuemei Lu , Jia Li , Zhu Mao . Preparation and Photoelectric Performance Characterization of Perovskite CsPbBr₃ Thin Films. University Chemistry, 2024, 39(6): 383-389. doi: 10.3866/PKU.DXHX202312019
7. [7]
  Yixuan Gao , Lingxing Zan , Wenlin Zhang , Qingbo Wei . Comprehensive Innovation Experiment: Preparation and Characterization of Carbon-based Perovskite Solar Cells. University Chemistry, 2024, 39(4): 178-183. doi: 10.3866/PKU.DXHX202311091
8. [8]
  Lin Song , Dourong Wang , Biao Zhang . Innovative Experimental Design and Research on Preparing Flexible Perovskite Fluorescent Gels Using 3D Printing. University Chemistry, 2024, 39(7): 337-344. doi: 10.3866/PKU.DXHX202310107
9. [9]
  Jizhou Liu , Chenbin Ai , Chenrui Hu , Bei Cheng , Jianjun Zhang . 六氯锡酸铵促进钙钛矿太阳能电池界面电子转移及其飞秒瞬态吸收光谱研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2402006-. doi: 10.3866/PKU.WHXB202402006
10. [10]
  Yingqi BAI , Hua ZHAO , Huipeng LI , Xinran REN , Jun LI . Perovskite LaCoO₃/g-C₃N₄ heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 480-490. doi: 10.11862/CJIC.20240259
11. [11]
  Xiaotian ZHU , Fangding HUANG , Wenchang ZHU , Jianqing ZHAO . Layered oxide cathode for sodium-ion batteries: Surface and interface modification and suppressed gas generation effect. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 254-266. doi: 10.11862/CJIC.20240260
12. [12]
  Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn²⁺ doped quasi-two-dimensional perovskites (PEA)₂Pb_yMn_1-yBr₄. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473
13. [13]
  Yikai Wang , Xiaolin Jiang , Haoming Song , Nan Wei , Yifan Wang , Xinjun Xu , Cuihong Li , Hao Lu , Yahui Liu , Zhishan Bo . 氰基修饰的苝二酰亚胺衍生物作为膜厚不敏感型阴极界面材料用于高效有机太阳能电池. Acta Physico-Chimica Sinica, 2025, 41(3): 2406007-. doi: 10.3866/PKU.WHXB202406007
14. [14]
  Cheng PENG , Jianwei WEI , Yating CHEN , Nan HU , Hui ZENG . First principles investigation about interference effects of electronic and optical properties of inorganic and lead-free perovskite Cs₃Bi₂X₉ (X=Cl, Br, I). Chinese Journal of Inorganic Chemistry, 2024, 40(3): 555-560. doi: 10.11862/CJIC.20230282
15. [15]
  Pengyu Dong , Yue Jiang , Zhengchi Yang , Licheng Liu , Gu Li , Xinyang Wen , Zhen Wang , Xinbo Shi , Guofu Zhou , Jun-Ming Liu , Jinwei Gao . NbSe₂纳米片优化钙钛矿太阳能电池的埋底界面. Acta Physico-Chimica Sinica, 2025, 41(3): 2407025-. doi: 10.3866/PKU.WHXB202407025
16. [16]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
17. [17]
  Yaping ZHANG , Tongchen WU , Yun ZHENG , Bizhou LIN . Z-scheme heterojunction β-Bi₂O₃ pillared CoAl layered double hydroxide nanohybrid: Fabrication and photocatalytic degradation property. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 531-539. doi: 10.11862/CJIC.20240256
18. [18]
  Junli Liu . Practice and Exploration of Research-Oriented Classroom Teaching in the Integration of Science and Education: a Case Study on the Synthesis of Sub-Nanometer Metal Oxide Materials and Their Application in Battery Energy Storage. University Chemistry, 2024, 39(10): 249-254. doi: 10.12461/PKU.DXHX202404023
19. [19]
  Qianwen Han , Tenglong Zhu , Qiuqiu Lü , Mahong Yu , Qin Zhong . 氢电极支撑可逆固体氧化物电池性能及电化学不对称性优化. Acta Physico-Chimica Sinica, 2025, 41(1): 2309037-. doi: 10.3866/PKU.WHXB202309037
20. [20]
  Yao Ma , Xin Zhao , Hongxu Chen , Wei Wei , Liang Shen . Progress and Perspective of Perovskite Thin Single Crystal Photodetectors. Acta Physico-Chimica Sinica, 2025, 41(4): 100030-. doi: 10.3866/PKU.WHXB202309045

Get Citation

PDF

XML

Metrics

PDF Downloads(7)
Abstract views(671)
HTML views(103)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Performance of Sr3Fe2-xNixO7-δ (x=0, 0.1, 0.2, 0.3) Cathode for Intermediate-Temperature Solid Oxide Fuel Cells

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation and Performance of Sr₃Fe_2-xNi_xO_7-δ (x=0, 0.1, 0.2, 0.3) Cathode for Intermediate-Temperature Solid Oxide Fuel Cells