Citation: LIU Lu, JIN Ping-Ning, LI Ying, LOU Hui-Hui, WANG Jian-Ji, ZHANG Yu-Ping, HOU Hong-Wei, DU Jin-Ge. Syntheses, Characterization and Crystal Structures of Five 1D Complexes Based on Semi-rigid Bis(thiazolylbenzimidazole) and Different Types of Carboxylic Acid Linkers[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(6): 1076-1084. doi: 10.11862/CJIC.2019.101 shu

Syntheses, Characterization and Crystal Structures of Five 1D Complexes Based on Semi-rigid Bis(thiazolylbenzimidazole) and Different Types of Carboxylic Acid Linkers

LIU Lu ^1,, ,
JIN Ping-Ning ² ,
LI Ying ¹ ,
LOU Hui-Hui ¹ ,
WANG Jian-Ji ^3,, ,
ZHANG Yu-Ping ¹ ,
HOU Hong-Wei ⁴ ,
DU Jin-Ge ⁵

1.
School of Chemistry and Chemical Engineering, Henan Institute of Science and Technology, Xinxiang, Henan 453003, China
2.
Xinxiang Medical University, Xinxiang, Henan 453000, China
3.
School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang, Henan 453007, China
4.
College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450052, China
5.
Department of Chemistry, Sanquan College of Xinxiang Medical University, Xinxiang, Henan 453003, China

Corresponding author: LIU Lu, liululiulu2012@126.com WANG Jian-Ji, Jwang@henannu.edu.cn
Received Date: 10 December 2018
Revised Date: 3 March 2019

Figures(5)

Five coordination complexes, formulated as {[Zn(btbb)_0.5(m-phda)]·0.5H₂O}_n (1), {[Cd₂(btbb)(adtda)₂(H₂O)]·H₂O}_n (2), [Mn₂(btbb)(tbi)₂]_n (3), {[Cd(btbb)_0.5(3-Nitro-o-bdc)(H₂O)]·H₂O}_n (4) and[Cd₂(btbb)(tbi)₂]_n (5) (btbb=1, 4-bis(2-(4-thiazolyl)benzimidazole-1-ylmethyl)benzene, m-H₂phda=m-phenylenediacetic acid, H₂adtda=1, 3-adaman-tanedicarboxylic acid, H₂tbi=5-tert-butylisophthalic acid, 3-Nitro-o-H₂bdc=3-Nitro-1, 2-benzenedicarboxylic acid), have been obtained by hydro(solv)thermal reactions and structurally characterized. Complex 1 exhibits a 1D chain structure containing 22-membered rings. Complex 2 features a 1D chain structure having an 8-membered rings and btbb serves only as an ornament here. Complex 3 is a 1D double chain structure. Complex 4 possesses a 1D chain structure containing 14-membered rings. Complex 5 shows a 1D double chain taking on stair-step. CCDC: 1883643,1;1883644,2;1883645,3;1883646,4;1883647,5.
- complex,
- semi-rigid ligand,
- carboxylate,
- crystal structure
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