Citation: LUO Wu-Kui, CHEN Feng, YAN Gui-Yang, BAI Yun-Shan. Synthesis, Characterization and Adsorption Property for the Methylene Blue of the Sphere-like TiSAPO-34 Molecular Sieve[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(4): 629-634. doi: 10.11862/CJIC.2019.080 shu

Synthesis, Characterization and Adsorption Property for the Methylene Blue of the Sphere-like TiSAPO-34 Molecular Sieve

1.
Fujian Province Key Laboratory of Featured Materials in Biochemical Industry, College of Chemistry and Materials, Ningde Normal University, Ningde, Fujian 352100, China
2.
College of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi′an 710062, China;

Corresponding author: LUO Wu-Kui, luowukui222@163.com
Received Date: 29 October 2018
Revised Date: 20 January 2019

Figures(8)

The TiSAPO-34 molecular sieves have been successfully synthesized via a facile hydrothermal method. Scanning electron microscopy (SEM), powder X-ray diffraction (XRD), Fourier transform infrared (FT-IR), N₂ adsorption-desorption, UV-Vis diffuse reflectance spectra (UV-Vis DRS) and thermogravimetric (TG) have been employed to determine the properties of the samples. The TiSAPO-34 molecular sieves could be served as efficient adsorbents for adsorbing a typical contaminants, methylene blue (MB) from water. Moreover, the doped amount of titanium, the stability and recyclability of the catalysts have been investigated in detail. The results revealed that the resulting samples were the spherical microporous molecular sieve, which with good thermal stability. Interestingly, a certain amount of Ti atoms could embed the matrix of SAPO-34 molecular sieves successfully, and the skeleton structure of SAPO-34 molecular sieves still maintained. Importantly, the samples synthetic after crystallization at 190℃ for 24 h exhibited the optimal adsorption performance for the adsorption of MB, giving an adsorption rate of 80% after 1 hour.
- microporous materials,
- molecular sieve,
- synthesis,
- adsorption
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沈阳化工大学材料科学与工程学院沈阳 110142