Citation: YANG Kang, TAN Yu-Hui, WANG Bin, ZHOU Hai-Tao, LI Chao, YANG Chang-Shang, LIU Yi, GAO Ji-Xing, TANG Yun-Zhi. Syntheses, Crystal Structures and Properties of Zn(Ⅱ), Mn(Ⅱ) Complexes Based on 5-Amino-1H-1, 2, 4-triazole-3- carboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(4): 703-710. doi: 10.11862/CJIC.2019.075 shu

Syntheses, Crystal Structures and Properties of Zn(Ⅱ), Mn(Ⅱ) Complexes Based on 5-Amino-1H-1, 2, 4-triazole-3- carboxylic Acid

School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou, Jiangxi 341000, China

Author Bio:
谭育慧, E-mail:tyxcn@163.com
Corresponding author: TANG Yun-Zhi, tangyunzhi75@163.com
Received Date: 13 November 2018
Revised Date: 13 January 2019

Fund Project: 国家自然科学基金 21761013国家自然科学基金(No.21471070, 21761013, 21671086, 21461010)资助项目国家自然科学基金 21471070国家自然科学基金 21461010国家自然科学基金 21671086

Figures(7)

Two coordination polymers[Zn(Athy)Br]_n (1, HAthy=5-amino-1H-1, 2, 4-triazol-3-ol) and[Mn(Atca)₂(H₂O)₂] (2, HAtca=5-amino-1H-1, 2, 4-triazole-3-carboxylic acid) were separately synthesized by hydrothermal method and solution diffusion method using HAtca, ZnBr₂ and MnCl₂, respectively. X-ray single crystal diffraction analyses indicate both 1 and 2 have different crystal structures. Complex 1 crystallizes in the orthorhombic system, space group Pbca. Complex 2 crystallizes in the monoclinic system, space group P2₁/c. Complex 1 is a 2D grid structure without any hydrogen bonds, but complex 2 has a 3D grid structure constructed by highly stable hydrogen bonds. Moreover, 1 and 2 show strong fluorescence emission at 360, 462 nm and 382, 402 nm at room temperature, respectively.
- triazole complexes,
- fluorescence,
- crystal structure
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