Citation: JIANG Hai-Yan, ZHANG Fan, YU Shu-Guang, LI Yu-Zhen. Efficient F-Doped BiVO₄ Photocatalyst Synthesized by One-Step Alcohol-Hydrothermal Method[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(4): 695-702. doi: 10.11862/CJIC.2019.074 shu

Efficient F-Doped BiVO₄ Photocatalyst Synthesized by One-Step Alcohol-Hydrothermal Method

1.
College of Chemistry and Pharmaceutical Sciences, Qingdao Agricultural University, Qingdao, Shandong 266109, China
2.
College of Environmental Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, China

Corresponding author: YU Shu-Guang, yushuguang_2000@163.com LI Yu-Zhen, liyuzhen123456@126.com
Received Date: 2 November 2018
Revised Date: 1 January 2019

Fund Project: 山西省重点研发计划(一般)社会发展项目 201703D321009-5青岛农业大学博士基金 663/1118005国家自然科学基金(No.21676028), 山西省重点研发计划(一般)社会发展项目(No.201703D321009-5)和青岛农业大学博士基金(No.663/1113317, 663/1118005)资助项目国家自然科学基金 21676028青岛农业大学博士基金 663/1113317

Figures(7)

F-doped BiVO₄ photocatalysts were fabricated by using a simple one-step alcohol-hydrothermal method with NH₄F as the precursor of the dopant. The physicochemical properties of the photocatalysts were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), ultraviolet-visible diffuse reflectance spectroscopy (UV-Vis), and photoluminescence spectra (PL). Their photocatalytic activities were determined through the degradation of phenol in the presence of a small amount of H₂O₂ under visible-light illumination. It is found that compared to the un-doped BiVO₄ sample, the F-doped BiVO₄ samples retained the monoclinic structure and had higher crystallinity, surface oxygen vacancy densities and separation efficiency of photogenerated charge carriers, stronger optical absorbance performances, and lower bandgap energies. Among these F-doped BiVO₄ samples, the F-doped BiVO₄ sample (nominal n_F/n_Bi=1.0, bandgap energy=2.43 eV) exhibited the best photocatalytic performance (the conversion of phenol up to 95% in 90 min), due to the highest crystallinity, surface oxygen vacancy density, and separation efficiency of photogenerated charge carriers, the strongest optical absorbance performance, and the lowest bandgap energy.
- one-step alcohol-hydrothermal method,
- F-doped BiVO₄,
- photocatalysis,
- phenol,
- photodegradation
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沈阳化工大学材料科学与工程学院沈阳 110142

Efficient F-Doped BiVO4 Photocatalyst Synthesized by One-Step Alcohol-Hydrothermal Method

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通讯作者: 陈斌, bchen63@163.com

Efficient F-Doped BiVO₄ Photocatalyst Synthesized by One-Step Alcohol-Hydrothermal Method