Citation: HAN Jia-Xing, LIU Zheng, LIANG Chu-Xin, TANG Qun, LI Qing-Wei, ZHANG Shu-Fen. Syntheses, Crystal Structures and Properties of Transition Metal Complexes Based on Pyridine-2, 5-dicarboxylic Acid or Thiophene-2, 5-dicarboxylic Acid Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(4): 605-612. doi: 10.11862/CJIC.2019.069 shu

Syntheses, Crystal Structures and Properties of Transition Metal Complexes Based on Pyridine-2, 5-dicarboxylic Acid or Thiophene-2, 5-dicarboxylic Acid Ligand

HAN Jia-Xing ¹ ,
LIU Zheng ^1,, ,
LIANG Chu-Xin ¹ ,
TANG Qun ^1,, ,
LI Qing-Wei ¹ ,
ZHANG Shu-Fen ^1,2

1.
Guangxi Key Laboratory of Electrochemical and Magneto-chemical Functional Materials, College of Chemistry and Bioengineering, Guilin University of Technology, Guilin, Guangxi 541004, China
2.
State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, Liaoning 116024, China

Corresponding author: LIU Zheng, lisa4.6@163.com TANG Qun, tangq@glut.edu.cn
Received Date: 3 July 2018
Revised Date: 7 December 2018

Figures(15)

Three transition metal coordination polymer materials were successfully synthesized by solvothermal method with the main ligand 2, 5-pyridinedicarboxylic acid (H₂L₁) or thiophene 2, 5-dicarboxylic acid (H₂L₂), and co-ligand 4, 4'-bipyridyl (4, 4'-bipy) or 1, 10-phenanthroline (phen). The complexes were characterized by X-ray single crystal diffraction, infrared spectroscopy (IR), fluorescence spectroscopy (FL) and thermogravimetric analysis (TG/DTG). The analysis of single crystal structure shows that all complexes belong to monoclinic system. Complexes 1 and 2 crystalize in P1 space group, and complex 3 crystalizes in P2/n. Complex 1 and complex 3 are zero-dimensional dinuclear small molecules, and complex 2 has a two-dimensional network structure.
- heterocyclic carboxyl ligand,
- transition metal complex,
- crystal structure,
- property
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沈阳化工大学材料科学与工程学院沈阳 110142