Citation: LIU Lu, LI Ying, WANG Jian-Ji, ZHANG Yu-Ping, HOU Hong-Wei. Two 3D Zn(Ⅱ) Coordination Complexes Constructed From a Semi-rigid Bis(dimethylbenzimidazole) Ligand and Different Multi-carboxylic Acids: Structures and Fluorescence Properties[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(3): 546-552. doi: 10.11862/CJIC.2019.064 shu

Two 3D Zn(Ⅱ) Coordination Complexes Constructed From a Semi-rigid Bis(dimethylbenzimidazole) Ligand and Different Multi-carboxylic Acids: Structures and Fluorescence Properties

LIU Lu ^1,2,, ,
LI Ying ² ,
WANG Jian-Ji ¹ ,
ZHANG Yu-Ping ² ,
HOU Hong-Wei ³

1.
Postdoctoral Research Base, School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang Henan 453007, China
2.
Postdoctoral Research Base, School of Chemistry and Chemical Engineering, Henan Institute of Science and Technology, Xinxiang, Henan 453003, China
3.
College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450052, China

Corresponding author: LIU Lu, liululiulu2012@126.com
Received Date: 13 December 2018
Revised Date: 27 December 2018

Figures(4)

Two Zn(Ⅱ) coordination complexes, formulated as {[Zn_1.5(dbim)_1.5(btc)]·6H₂O}_n (1) and {[Zn(dbim)_0.5(btec)_0.5(H₂O)]·H₂O}_n (2) (dbim=1-(4-((2, 6-dimethyl-2H-benzo[d]imidazol-3(3H)-yl)methyl)benzyl)-2, 7-dihydro-2, 5-dimethyl-1H-benzo[d]imidazole, H₃btc=trimesic acid, H₄btec=1, 2, 4, 5-benzene tetracarboxylic), have been obtained by hydrothermal reactions. Complex 1 is a trinodal (3, 4, 4)-connected topology net with the point symbol of (5²·6·7·8²)(5²·6) (5²·6²·8²), while complex 2 possesses a (3, 4)-connected 3D topology with the point symbol of (8³)(8⁵·10) topology. Additionally, complexes 1 and 2 exhibit different photoluminescence behaviors in solid state compared to ligand dbim.
- Zn(Ⅱ),
- crystal structure,
- topology,
- fluorescence
1. [1]
  Sun L X, Qi Y, Wang Y M, et al. CrystEngComm, 2010, 12:1540-1547 doi: 10.1039/b909590j
2. [2]
  Zhang J P, Lin Y Y, Huang X C, et al. Chem. Commun., 2005:1258-1260
3. [3]
  Janiak C. Dalton Trans., 2003:2781-2804
4. [4]
  Janiak C, Vieth J K. New J. Chem., 2010, 34:2366-2388 doi: 10.1039/c0nj00275e
5. [5]
  LEI Xue, CHEN Yun-Zhou, LI Yuan-Xiang, et al. Chinese J. Inorg. Chem., 2018, 34(3):545-550
6. [6]
  WU Qi, SU Zhi, WANG Hong-Yan, et al. Chinese J. Inorg. Chem., 2017, 33(10):1889-1895
7. [7]
  Xie Z, Ma L, deKrafft K E, et al. J. Am. Chem. Soc., 2010, 132:922-923 doi: 10.1021/ja909629f
8. [8]
  Seo J S, Whang D, Lee H, et al. Nature, 2000, 404:982-986 doi: 10.1038/35010088
9. [9]
  James S L. Chem. Soc. Rev., 2003, 32:276-288 doi: 10.1039/b200393g
10. [10]
  Dong Y B, Zhao X, Huang R Q, et al. Inorg. Chem., 2004, 43:5603-5612 doi: 10.1021/ic049787a
11. [11]
  Liu X G, Wang L Y, Zhu X, et al. Cryst. Growth Des., 2009, 9:3997-4005 doi: 10.1021/cg900134f
12. [12]
  Hagrman P J, Hagrman D, Zubieta J. Angew. Chem. Int. Ed., 1999, 38:2638-2684 doi: 10.1002/(ISSN)1521-3773
13. [13]
  Du M, Jiang X J, Zhao X J. Inorg. Chem., 2007, 46:3984-3995 doi: 10.1021/ic062098+
14. [14]
  Zheng B, Bai J, Duan J, et al. J. Am. Chem. Soc., 2011, 133:748-751 doi: 10.1021/ja110042b
15. [15]
  Li H, Eddaoudi M, O'Keeffe M, et al. Nature, 1999, 402:276-279 doi: 10.1038/46248
16. [16]
  Sun D, Zhang N, Huang R B, et al. Cryst. Growth Des., 2010, 10:3699-3709 doi: 10.1021/cg100554u
17. [17]
  Deng H, Doonan C J, Furukawa H, et al. Science, 2010, 327:846-850 doi: 10.1126/science.1181761
18. [18]
  Bronisz R. Inorg. Chem., 2005, 44:4463-4465 doi: 10.1021/ic050449z
19. [19]
  Dolomanov O V, Bourhis L J, Gildea R J, et al. J. Appl. Cryst., 2009, 42:339-341 doi: 10.1107/S0021889808042726
20. [20]
  Sheldrick G M. Acta Crystallogr. Sect. A:Found. Crystallogr., 2008, A64:112-122
21. [21]
  Bai H Y, Ma J F, Yang J, et al. Cryst. Growth Des., 2010, 10:995-1016 doi: 10.1021/cg901332m
22. [22]
  Wu Q, Esteghamatian M, Hu N X, et al. Chem. Mater., 2000, 12:79-83 doi: 10.1021/cm990372a
23. [23]
  Santis G D, Fabbrizzi L, Licchelli M, et al. Angew. Chem. Int. Ed., 1996, 35:202-204 doi: 10.1002/(ISSN)1521-3773
24. [24]
  Hua Q, Zhao Y, Xu G C, et al. Cryst. Growth Des., 2010, 10:2553-2562 doi: 10.1021/cg901480y
25. [25]
  Stadler M, Puntoriero F, Campagna S, et al. Chem. Eur. J., 2005, 11:3997-4009 doi: 10.1002/(ISSN)1521-3765
26. [26]
  Censo D D, Fantacci S, Angelis F D, et al. Inorg. Chem., 2008, 47:980-989 doi: 10.1021/ic701814h
27. [27]
  Wang J H, Fang Y Q, Bourget-Merle L, et al. Chem. Eur. J., 2006, 12:8539-8548 doi: 10.1002/(ISSN)1521-3765
28. [28]
  Ohkoshi S, Tokoro H, Hozumi T, et al. J. Am. Chem. Soc., 2006, 128:270-277 doi: 10.1021/ja0559092
1. [1]
  Shuwen SUN , Gaofeng WANG . Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 613-620. doi: 10.11862/CJIC.20230368
2. [2]
  Lulu DONG , Jie LIU , Hua YANG , Yupei FU , Hongli LIU , Xiaoli CHEN , Huali CUI , Lin LIU , Jijiang WANG . Synthesis, crystal structure, and fluorescence properties of Cd-based complex with pcu topology. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 809-820. doi: 10.11862/CJIC.20240171
3. [3]
  Shuwen SUN , Gaofeng WANG . Design and synthesis of a Zn(Ⅱ)-based coordination polymer as a fluorescent probe for trace monitoring 2, 4, 6-trinitrophenol. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 753-760. doi: 10.11862/CJIC.20240399
4. [4]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
5. [5]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
6. [6]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
7. [7]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
8. [8]
  Yao HUANG , Yingshu WU , Zhichun BAO , Yue HUANG , Shangfeng TANG , Ruixue LIU , Yancheng LIU , Hong LIANG . Copper complexes of anthrahydrazone bearing pyridyl side chain: Synthesis, crystal structure, anticancer activity, and DNA binding. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 213-224. doi: 10.11862/CJIC.20240359
9. [9]
  Jia JI , Zhaoyang GUO , Wenni LEI , Jiawei ZHENG , Haorong QIN , Jiahong YAN , Yinling HOU , Xiaoyan XIN , Wenmin WANG . Two dinuclear Gd(Ⅲ)-based complexes constructed by a multidentate diacylhydrazone ligand: Crystal structure, magnetocaloric effect, and biological activity. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 761-772. doi: 10.11862/CJIC.20240344
10. [10]
  Gaofeng WANG , Shuwen SUN , Yanfei ZHAO , Lixin MENG , Bohui WEI . Structural diversity and luminescence properties of three zinc coordination polymers based on bis(4-(1H-imidazol-1-yl)phenyl)methanone. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 849-856. doi: 10.11862/CJIC.20230479
11. [11]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
12. [12]
  Xiumei LI , Linlin LI , Bo LIU , Yaru PAN . Syntheses, crystal structures, and characterizations of two cadmium(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 613-623. doi: 10.11862/CJIC.20240273
13. [13]
  Chao LIU , Jiang WU , Zhaolei JIN . Synthesis, crystal structures, and antibacterial activities of two zinc(Ⅱ) complexes bearing 5-phenyl-1H-pyrazole group. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1986-1994. doi: 10.11862/CJIC.20240153
14. [14]
  Yukun CHEN , Kexin FENG , Bolun ZHANG , Wentao SONG , Jianjun ZHANG . Syntheses, crystal structures, and diametrically opposed mechanically-stimulated luminescence response of two Mg(Ⅱ) metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1227-1234. doi: 10.11862/CJIC.20240448
15. [15]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
16. [16]
  Xiaoling WANG , Hongwu ZHANG , Daofu LIU . Synthesis, structure, and magnetic property of a cobalt(Ⅱ) complex based on pyridyl-substituted imino nitroxide radical. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 407-412. doi: 10.11862/CJIC.20240214
17. [17]
  Yan XU , Suzhi LI , Yan LI , Lushun FENG , Wentao SUN , Xinxing LI . Structure variation of cadmium naphthalene-diphosphonates with the changing rigidity of N-donor auxiliary ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 395-406. doi: 10.11862/CJIC.20240226
18. [18]
  Dongdong YANG , Jianhua XUE , Yuanyu YANG , Meixia WU , Yujia BAI , Zongxuan WANG , Qi MA . Design and synthesis of two coordination polymers for the rapid detection of ciprofloxacin based on triphenylpolycarboxylic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2466-2474. doi: 10.11862/CJIC.20240266
19. [19]
  Jiming XI , Yukang TENG , Rui ZHANG , Zhenzhong LU . Fluorescent coordination polymers based on anthracene-and pyrene-derivative ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 847-854. doi: 10.11862/CJIC.20240367
20. [20]
  Yuanyu YANG , Jianhua XUE , Yujia BAI , Lulu CUI , Dongdong YANG , Qi MA . Design, synthesis, and detection of Al³⁺ of two zinc complexes based on Schiff base ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1207-1216. doi: 10.11862/CJIC.20250005

Get Citation

PDF

XML

Metrics

PDF Downloads(6)
Abstract views(464)
HTML views(95)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142