Citation: WANG Bin, ZHENG Jin-Hui, LIU Zhe-Lin, WANG Xiao-Hong, DUAN Li-Mei, BAI Suo-Zhu, XU Liang, LIU Zong-Rui. Reversible Electrochromic/Luminescent Switching Behaviors and Spectroscopy for H₂O₂ Based on P₂W₁₈O₆₂^6-@Tb³⁺ Mixed Solution[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(3): 385-392. doi: 10.11862/CJIC.2019.054 shu

Reversible Electrochromic/Luminescent Switching Behaviors and Spectroscopy for H₂O₂ Based on P₂W₁₈O₆₂^6-@Tb³⁺ Mixed Solution

WANG Bin ^1,2,, ,
ZHENG Jin-Hui ¹ ,
LIU Zhe-Lin ³ ,
WANG Xiao-Hong ¹ ,
DUAN Li-Mei ¹ ,
BAI Suo-Zhu ¹ ,
XU Liang ^1,2 ,
LIU Zong-Rui ^1,,

1.
College of Chemistry and Chemical Engineering, Inner Mongolia University for the Nationalities, Tongliao, Inner Mongolia 028043, China
2.
Key Laboratory of the Natural Products Chemistry and Functional Molecular Synthesis of Autonomous Region, Tongliao, Inner Mongolia 028000, China
3.
School of Chemistry & Environment Engineering, Changchun University of Science and Technology, Changchun 130022, China

Corresponding author: WANG Bin, jluwangbin09@163.com LIU Zong-Rui, liuzr716@163.com
Received Date: 17 October 2018
Revised Date: 4 January 2019

Figures(10)

Based on the functional complementarity between the reversible electrochromic property of the Dawson type polyanions P₂W₁₈O₆₂^6- and the excellent luminescent property of Tb³⁺, the reversible electrochromic and luminescent switching properties of P₂W₁₈O₆₂^6-@Tb³⁺ mixed solution were achieved under redox potential stimulation. The effects of applied reduction potential on electrochromic response time and the energy transfer efficiency of luminescent switch were investigated. And the energy transfer efficiency of the mixed solution P₂W₁₈O₆₂^6-@Tb³⁺ were 85.97%, 87.53% and 93.42% when applied different reduction potential -0.38, -0.69 and -0.85 V, respectively. On this basis, the UV-Vis and fluorescence spectroscopy bi-functional detection for H₂O₂ were realized by combining electrochemical reduction with chemical oxidation methods. The detection limits for H₂O₂ were 1.76×10^-2 and 3.04 μmol·L^-1 by the UV-Vis and fluorescence spectroscopy, respectively.
- polyoxometalates,
- electrochemistry,
- electrochromism,
- fluorescence switch,
- fluorescence spectroscopy
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Reversible Electrochromic/Luminescent Switching Behaviors and Spectroscopy for H₂O₂ Based on P₂W₁₈O₆₂^6-@Tb³⁺ Mixed Solution