Citation: LIU Qin, YAO Xun, ZHANG Bo-Jian, LIU Fei, LIU Yang, LI Peng, XUE Rui-Ting, FAN Xi-Mei. Preparation and Photocatalytic Performance of Cu₂O/CNTs Composites[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(3): 459-466. doi: 10.11862/CJIC.2019.052 shu

Preparation and Photocatalytic Performance of Cu₂O/CNTs Composites

LIU Qin ¹ ,
YAO Xun ² ,
ZHANG Bo-Jian ¹ ,
LIU Fei ¹ ,
LIU Yang ¹ ,
LI Peng ¹ ,
XUE Rui-Ting ¹ ,
FAN Xi-Mei ^1,,

1.
Key Laboratory of Advanced Technologies of Materials, Ministry of Education, School of Materials Science and Engineering, Southwest Jiaotong University, Chengdu 610031, China
2.
BOECD, Chengdu 611731, China

Corresponding author: FAN Xi-Mei, fanximei@126.com
Received Date: 15 October 2018
Revised Date: 29 December 2018

Figures(10)

Carbon nanotubes (CNTs)were treated with the mixed acid (V_H₂SO₄/V_HNO₃=3:1). Cu₂O/CNTs spherical composites were synthesized by one-step solvothermal method, using ethylene glycol as reductant and acid-treated CNTs as the carrier. Cu₂O/CNTs were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), energy spectrum analysis (EDS), N₂ adsorption-desorption, ultraviolet-visible diffuse reflectance spectrometer (DRS)and organic total carbon (TOC). The influence of CNTs on the crystal structure, morphology, surface area, pore size and optical characteristics of Cu₂O/CNTs composites was investigated. The relationship between CNTs and photocatalytic performance of Cu₂O/CNTs in combination with photocatalytic mechanism was analyzed. The results showed that the photocatalytic activity of Cu₂O/CNTs was the best when the content of CNTs was 0.2 g, and the degradation rate of methyl orange reached 92.1% after degradation for 60 min.
- catalysis,
- copper oxide,
- carbon nanotubes,
- visible light irradiation,
- methl orange
1. [1]
  Zhang X X, Song J M, Jiao J, et al. Solid State Sci., 2010, 12(7):1215-1219 doi: 10.1016/j.solidstatesciences.2010.03.009
2. [2]
  Hara M, Kondo T, Komoda M, et al. Chem. Commun., 1998(3):357-358 doi: 10.1039/a707440i
3. [3]
  Ramirez O J, Ogura T, Medina V J, et al. Appl. Surf. Sci., 2001, 174(3/4):177-184
4. [4]
  GAO Xin, LIU Xiang-Xuan, WANG Xuan-Jun, et al. Journal of Materials Engineering, 2016, 44(1):120-128
5. [5]
  Zhang H, Ren X, Cui Z L. J. Cryst. Growth, 2007, 304(1):206-210 doi: 10.1016/j.jcrysgro.2007.01.043
6. [6]
7. [7]
  LI Yong, KONG Guang-Lu, GENG Xiao-Ju, et al. New Chemical Materials, 2010, 38(3):95-97 doi: 10.3969/j.issn.1006-3536.2010.03.032
8. [8]
  Tasis D, Tagmatarchis N, Bianco A. Chem. Rev., 2006, 106(3):1105-1136 doi: 10.1021/cr050569o
9. [9]
  Zhang A M, Dong J L, Xu Q H. Catal. Today, 2004, 93:347-352
10. [10]
  Xu L S, Chen X H, Wu Y R, et al. Proceedings of 2011 China Functional Materials Technology and Industry Forum. Chongqing:Scientific Research Publishing, 2011:815-819
11. [11]
  Zhang H, Zhou D, Zhang L. J. Nanosci. Nanotechnol., 2009, 9(2):1321-1325 doi: 10.1166/jnn.2009.C147
12. [12]
13. [13]
  Titus E, Ali N, Cabral G, et al. J. Mater. Eng. Perform., 2006, 15(2):182-186 doi: 10.1361/105994906X95841
14. [14]
  SUI Gang, LIANG Ji, ZHU Yue-Feng, et al. High Technology Letter, 2004, 8:41-46
15. [15]
  HUANG Jian-Xin, LIN Ruo-Bo. Chinese Journal of Spectroscopy Laboratory, 2012, 29(6):3857-3859
16. [16]
  CHEN Xiao-Hua, WANG Wei, YI Bing, et al. Journal of Hunan University:Natural Sciences, 2011, 38(1):45-46
17. [17]
  Feng L, Sadana A, Peera A. Nano Lett., 2004, 4(7):1257-1259 doi: 10.1021/nl049428c
18. [18]
  Zhao L P, Gao L. Carbon, 2004, 42(8/9):1858-1861
19. [19]
  Zhu H T, Zhang C Y, Yin Y S. J. Cryst. Growth, 2004, 270(3/4):722-728
20. [20]
  Leelaviwat N, Monchayapisut S, Poonjarernsilp C. Curr. Appl. Phys., 2012, 12(6):1575-1579 doi: 10.1016/j.cap.2012.05.002
21. [21]
  Zeng B, Chen X H, Ning X T, et al. Nano, 2013, 8(5):1350052 doi: 10.1142/S1793292013500525
22. [22]
23. [23]
  Jin Y X, Cui Q L, Wang K, et al. J. Appl. Phys., 2011, 109(5):053521 doi: 10.1063/1.3549826
24. [24]
  Li P W, Li D D, Liu L N, et al. CrystEngComm., 2018, 20(41):6580-6588 doi: 10.1039/C8CE01332B
25. [25]
  Mukherjee I, Das S, Jena B, et al. New J. Chem., 2018, 42(5):3692-3702 doi: 10.1039/C7NJ04474G
26. [26]
  Zhu J W, Wang Y P, Wang X, et al. Powder Technol., 2008, 181(3):249-254 doi: 10.1016/j.powtec.2007.05.008
27. [27]
  Xiu F R, Zhang F S. J. Hazard. Mater., 2012, 233-234:200-206 doi: 10.1016/j.jhazmat.2012.07.019
28. [28]
  Sun W, Sun W D, Zhuo Y J, et al. J. Solid State Chem., 2011, 184(7):1638-1643 doi: 10.1016/j.jssc.2011.03.055
1. [1]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
2. [2]
  Haihua Yang , Minjie Zhou , Binhong He , Wenyuan Xu , Bing Chen , Enxiang Liang . Synthesis and Electrocatalytic Performance of Iron Phosphide@Carbon Nanotubes as Cathode Material for Zinc-Air Battery: a Comprehensive Undergraduate Chemical Experiment. University Chemistry, 2024, 39(10): 426-432. doi: 10.12461/PKU.DXHX202405100
3. [3]
  Yi YANG , Shuang WANG , Wendan WANG , Limiao CHEN . Photocatalytic CO₂ reduction performance of Z-scheme Ag-Cu₂O/BiVO₄ photocatalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 895-906. doi: 10.11862/CJIC.20230434
4. [4]
  Qiang ZHAO , Zhinan GUO , Shuying LI , Junli WANG , Zuopeng LI , Zhifang JIA , Kewei WANG , Yong GUO . Cu₂O/Bi₂MoO₆ Z-type heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 885-894. doi: 10.11862/CJIC.20230435
5. [5]
  Bowen Yang , Rui Wang , Benjian Xin , Lili Liu , Zhiqiang Niu . C-SnO₂/MWCNTs Composite with Stable Conductive Network for Lithium-based Semi-Solid Flow Batteries. Acta Physico-Chimica Sinica, 2025, 41(2): 100015-. doi: 10.3866/PKU.WHXB202310024
6. [6]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346
7. [7]
  Simin Fang , Wei Huang , Guanghua Yu , Cong Wei , Mingli Gao , Guangshui Li , Hongjun Tian , Wan Li . Integrating Science and Education in a Comprehensive Chemistry Design Experiment: The Preparation of Copper(I) Oxide Nanoparticles and Its Application in Dye Water Remediation. University Chemistry, 2024, 39(8): 282-289. doi: 10.3866/PKU.DXHX202401023
8. [8]
  Kaihui Huang , Dejun Chen , Xin Zhang , Rongchen Shen , Peng Zhang , Difa Xu , Xin Li . Constructing Covalent Triazine Frameworks/N-Doped Carbon-Coated Cu₂O S-Scheme Heterojunctions for Boosting Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(12): 2407020-. doi: 10.3866/PKU.WHXB202407020
9. [9]
  Meng Lin , Hanrui Chen , Congcong Xu . Preparation and Study of Photo-Enhanced Electrocatalytic Oxygen Evolution Performance of ZIF-67/Copper(I) Oxide Composite: A Recommended Comprehensive Physical Chemistry Experiment. University Chemistry, 2024, 39(4): 163-168. doi: 10.3866/PKU.DXHX202308117
10. [10]
  Qin Li , Huihui Zhang , Huajun Gu , Yuanyuan Cui , Ruihua Gao , Wei-Lin Dai . In situ Growth of Cd_0.5Zn_0.5S Nanorods on Ti₃C₂ MXene Nanosheet for Efficient Visible-Light-Driven Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2025, 41(4): 100031-. doi: 10.3866/PKU.WHXB202402016
11. [11]
  Xinzhe HUANG , Lihui XU , Yue YANG , Liming WANG , Zhangyong LIU , Zhongjian WANG . Preparation and visible light responsive photocatalytic properties of BiSbO₄/BiOBr. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 284-292. doi: 10.11862/CJIC.20240212
12. [12]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
13. [13]
  Yurong Tang , Yunren Shi , Yi Xu , Bo Qin , Yanqin Xu , Yunfei Cai . Innovative Experiment and Course Transformation Practice of Visible-Light-Mediated Photocatalytic Synthesis of Isoquinolinone. University Chemistry, 2024, 39(5): 296-306. doi: 10.3866/PKU.DXHX202311087
14. [14]
  Dan Liu . 可见光-有机小分子协同催化的不对称自由基反应研究进展. University Chemistry, 2025, 40(6): 118-128. doi: 10.12461/PKU.DXHX202408101
15. [15]
  Xiufang Wang , Donglin Zhao , Kehua Zhang , Xiaojie Song . “Preparation of Carbon Nanotube/SnS₂ Photoanode Materials”: A Comprehensive University Chemistry Experiment. University Chemistry, 2024, 39(4): 157-162. doi: 10.3866/PKU.DXHX202308025
16. [16]
  Jie Li , Huida Qian , Deyang Pan , Wenjing Wang , Daliang Zhu , Zhongxue Fang . Efficient Synthesis of Anethaldehyde Induced by Visible Light. University Chemistry, 2024, 39(4): 343-350. doi: 10.3866/PKU.DXHX202310076
17. [17]
  Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216
18. [18]
  Zhen Yao , Bing Lin , Youping Tian , Tao Li , Wenhui Zhang , Xiongwei Liu , Wude Yang . Visible-Light-Mediated One-Pot Synthesis of Secondary Amines and Mechanistic Exploration. University Chemistry, 2024, 39(5): 201-208. doi: 10.3866/PKU.DXHX202311033
19. [19]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
20. [20]
  Yichang Liu , Li An , Dan Qu , Zaicheng Sun . “双碳”背景下的综合设计实验——以PbCrO₄催化甲基蓝的光降解速率常数测定为例. University Chemistry, 2025, 40(6): 222-229. doi: 10.12461/PKU.DXHX202407105

Get Citation

PDF

XML

Metrics

PDF Downloads(7)
Abstract views(1427)
HTML views(330)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Photocatalytic Performance of Cu2O/CNTs Composites

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation and Photocatalytic Performance of Cu₂O/CNTs Composites