Citation: LUO Han-Yu, HU Li-Yang, WANG Kai-Ying, CHEN Yuan-Ting, ZHANG Ting-Ting. Preparation by Hydrothermal Method and Property of Catalytic Oxidation of Gaseous Chlorobenzene for Metal Ion Doped MnO₂[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(3): 413-421. doi: 10.11862/CJIC.2019.051 shu

Preparation by Hydrothermal Method and Property of Catalytic Oxidation of Gaseous Chlorobenzene for Metal Ion Doped MnO₂

College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China

Corresponding author: ZHANG Ting-Ting, zhangtt@mail.buct.edu.cn
Received Date: 31 August 2018
Revised Date: 30 November 2018

Figures(8)

The δ-MnO₂ catalysts doped with different metal ions Mⁿ⁺ (Mⁿ⁺=Co²⁺, Cu²⁺, Fe³⁺, Al³⁺, Ce⁴⁺) were prepared by hydrothermal method, which was referred to as MMn for catalytic oxidation of chlorobenzene. The catalysts were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), N₂ absorption-desorption, X-ray photoelectron spectroscopy (XPS) and temperature-programmed reduction (H₂-TPR). The results showed that the catalytic efficiency of chlorobenzene under the same reaction conditions was:AlMn > FeMn > CeMn > CuMn > δ-MnO₂ > CoMn. The higher specific surface area, the lower reducible temperature and more surface active oxygen O_sur of Al-doped δ-MnO₂ catalyst are important factors for higher catalytic activity.
- catalysis,
- metals,
- oxides,
- decomposition,
- dope,
- chlorobenzene
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Preparation by Hydrothermal Method and Property of Catalytic Oxidation of Gaseous Chlorobenzene for Metal Ion Doped MnO2

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Preparation by Hydrothermal Method and Property of Catalytic Oxidation of Gaseous Chlorobenzene for Metal Ion Doped MnO₂