Citation: MEI Xue-Lan, DU Min-Jie, HU Peng, LI Zong-Qun. Syntheses, Structures and Magnetic Properties of Two Binuclear Lanthanide Complexes Bridged by Nitronyl Nitroxide Radical Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(2): 323-328. doi: 10.11862/CJIC.2019.034 shu

Syntheses, Structures and Magnetic Properties of Two Binuclear Lanthanide Complexes Bridged by Nitronyl Nitroxide Radical Ligands

MEI Xue-Lan ^1,, ,
DU Min-Jie ² ,
HU Peng ³ ,
LI Zong-Qun ¹

1.
College of Materials Science and Chemical Engineering, Bengbu University, Bengbu, Anhui 233030, China
2.
Military Representative Bureau of Nanjing of the PLA Army, Hefei 230041, China
3.
College of Environment and Chemical Engineering, Zhaoqing University, Zhaoqing, Guangdong 526061, China

Corresponding author: MEI Xue-Lan, daluhuashu@126.com
Received Date: 30 August 2018
Revised Date: 26 November 2018

Figures(5)

The reaction of Ln(acac)₃·3H₂O with NIT-PhOH radical yielded two new Ln-radical complexes[Ln₂(acac)₄(NIT-PhO)₂] (Ln=Tb (1), Y (2); acac=acetylacetonato, NIT-PhOH=2-(2'-hydroxyphenyl)-4, 4, 5, 5-tetramethylimidazo-line-1-oxyl-3-oxide). Two complexes are isostructural and have binuclear structure in which two lanthanide ions are bridged by two radical ligands through their phenoxo-O atoms. DC magnetic susceptibility studies indicated that there exists weak antiferromagnetic interaction in complex 2.
- lanthanide complexes,
- crystal structure,
- magnetic properties,
- radical
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