Citation: YU Min, XUAN Fang, LIU Guang-Xiang. Syntheses, Crystal Structures and Photoluminescent Properties of Two Zinc(Ⅱ) Coordination Polymers Derived from 4, 4'-((1H-Imidazol-1-yl) methylene) dibenzoic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(1): 133-140. doi: 10.11862/CJIC.2019.018 shu

Syntheses, Crystal Structures and Photoluminescent Properties of Two Zinc(Ⅱ) Coordination Polymers Derived from 4, 4'-((1H-Imidazol-1-yl) methylene) dibenzoic Acid

Nanjing Key Laboratory of Advanced Functional Materials, School of Environmental Science, Nanjing Xiaozhuang University, Nanjing 211171, China

Corresponding author: LIU Guang-Xiang, njuliugx@126.com
Received Date: 30 July 2018
Revised Date: 30 October 2018

Figures(10)

Two zinc(Ⅱ) coordination polymers, [Zn(HIMB)₂]_n (1) and {[Zn(IMB)]·1.5H₂O}_n (2), (H₂IMB=4, 4'-((1H-imidazol-1-yl) methylene) dibenzoic acid), have been synthesized and characterized by IR spectroscopy, elemental analyses, thermogravimetric analysis (TGA), powder X-ray diffraction (PXRD), and single-crystal X-ray diffraction. Complex 1 crystallizes in orthorhombic, space group C222₁ with a=0.935 2(3) nm, b=2.583 3(8) nm, c=1.396 4(4) nm, V=3.373 6(18) nm³, M_r=707.98, D_c=1.394 g·cm^-3, F(000)=1 456, μ=0.786 mm^-1 and Z=4. The final R₁=0.048 6 and wR₂=0.120 1 for 2 794 observed reflections when I>2σ(I). Complex 2 belongs to tetragonal, space group I4₁/acd with a=1.853 5(2) nm, b=1.853 5(2) nm, c=4.309 7(5) nm, V=14.806 (4) nm³, M_r=412.69, D_c=1.481 g·cm^-3, F(000)=6 752, μ=0.136 0 mm^-1 and Z=32. The final R₁=0.043 7 and wR₂=0.117 1 for 3 615 observed reflections when I>2σ(I). Structural analyses reveal that complex 1 shows a 2D→2D polycatenane of 2-fold interpenetrated sql layer, whereas complex 2 possesses a 3D 2-fold interpenetrated (3, 6)-connected net with the point symbol of (6¹¹.8⁴)(6³)₂. The results show that the solvent plays a significant role in the structure of the final products.
- zinc (Ⅱ) coordination polymer,
- bifunctional ligand,
- crystal structure,
- luminescence
1. [1]
  Lyu H L, Zhang Q, Wang Y, et al. Dalton Trans., 2018, 47:4424-4427 doi: 10.1039/C8DT00512E
2. [2]
  Wang H, Lustig W P, Li J. Chem. Soc. Rev., 2018, 47:4729-4756 doi: 10.1039/C7CS00885F
3. [3]
  Dutta S, Jana A K, Natarajan S, et al. Chem. Eur. J., 2017, 23:8932-8940 doi: 10.1002/chem.v23.37
4. [4]
  Cheng M, Lai C, Liu Y, et al. Coord. Chem. Rev., 2018, 368:80-92 doi: 10.1016/j.ccr.2018.04.012
5. [5]
  Mingabudinaova L R, Vinogradov W, Milichko V A, et al. Chem. Soc. Rev., 2016, 45:5408-5431 doi: 10.1039/C6CS00395H
6. [6]
  Wang G Y, Yang L L, Li Y, et al. Dalton Trans., 2013, 42:12865-12868 doi: 10.1039/c3dt51450a
7. [7]
  Huang R W, Wei Y S, Dong X Y, et al. Nat. Chem., 2017, 9:689-697 doi: 10.1038/nchem.2718
8. [8]
  Kotzabasaki M, Froudakis G E. Inorg. Chem. Front., 2018, 5:1255-1272 doi: 10.1039/C7QI00645D
9. [9]
  Guo X M, Guo H D, Zou H Y, et al. CrystEngComm, 2013, 15:9112-9120
10. [10]
  Zhao F H, Jing S, Che Y X, et al. CrystEngComm, 2012, 14:4478-4485 doi: 10.1039/c2ce25272d
11. [11]
  Shen L, Gray D, Masel R I, et al. CrystEngComm, 2012, 14:5145-5147 doi: 10.1039/c2ce25780g
12. [12]
  Guo H D, Guo X M, Zou H Y, et al. CrystEngComm, 2014, 16:7459-7468 doi: 10.1039/C4CE00664J
13. [13]
  Ding J G, Yin C, Zheng L Y, et al. RSC Adv., 2014, 4:24594-24600 doi: 10.1039/c4ra02291b
14. [14]
  Hu F L, Wang S L, Wu B, et al. CrystEngComm, 2014, 16:6354-6363 doi: 10.1039/c3ce42545b
15. [15]
  Pan M, Su C Y. CrystEngComm, 2014, 16:7847-7859 doi: 10.1039/C4CE00616J
16. [16]
  LI Tian-Tian, ZHENG Sheng-Rui. Chinese J. Inorg. Chem., 2018, 34(8):1566-1572
17. [17]
  Ye R P, Zhang X, Zhang L, et al. Cryst. Growth Des., 2016, 16:4012-4020 doi: 10.1021/acs.cgd.6b00548
18. [18]
  Lin Z J, Yang Z, Liu T F, et al. Inorg. Chem., 2012, 51:1813-1820 doi: 10.1021/ic202082w
19. [19]
  Lin Z J, Huang Y B, Liu T F, et al. Inorg. Chem., 2013, 52:3127-3132 doi: 10.1021/ic302583a
20. [20]
  Yang J X, Zhang X, Cheng J K, et al. Cryst. Growth Des., 2012, 12:333-345 doi: 10.1021/cg201143f
21. [21]
  Zhu Z, Xu C G, Wang M, et al. Cryst. Growth Des., 2017, 17:5533-5543 doi: 10.1021/acs.cgd.7b01070
22. [22]
  Meng X M, Cui L S, Wang X P, et al. CrystEngComm, 2017, 19:6630-6643 doi: 10.1039/C7CE01229B
23. [23]
  Yan T, Du L, Sun L, et al. RSC Adv., 2017, 7:50150-50155 doi: 10.1039/C7RA07997D
24. [24]
  Wu W P, Liu P, Liang Y T, et al. J. Solid State Chem., 2015, 228:124-130
25. [25]
  Ma A Q, Wu J, Han Y T, et al. Dalton Trans., 2018, 47:9627-9633 doi: 10.1039/C8DT01923A
26. [26]
  Tian D, Li Y, Chen R Y, et al. J. Mater. Chem. A, 2014, 2:1465-1470 doi: 10.1039/C3TA13983B
27. [27]
  Sheldrick G M. SADABS. Program for Empirical Absorption Correction of Area Detector Data, University of Göttingen, Germany, 1996.
28. [28]
  Sheldrick G M. SHELXS-2016, Program for Crystal Structure Solution, University of Göttingen, Germany, 2016.
29. [29]
  Sheldrick G M. SHELXL-2016, Program for the Refinement of Crystal Structure, University of Göttingen, Germany, 2016
30. [30]
  Wang T, Zhu R R, Zhang X F, et al. RSC Adv., 2018, 8:7428-7437 doi: 10.1039/C7RA12874F
31. [31]
  Song J F, Luo J J, Jia Y Y, et al. RSC Adv., 2017, 7:36575-36584 doi: 10.1039/C7RA05049F
32. [32]
  Jing X M, Xiao L W, Wei L, et al. Inorg. Chem. Commun., 2016, 71:78-81 doi: 10.1016/j.inoche.2016.06.032
33. [33]
  Wu Y L, Yang G P, Zhao Y Q, et al. Dalton Trans., 2015, 44:3271-3277 doi: 10.1039/C4DT03415E
34. [34]
  Nakamoto K. Infrared and Raman Spectra of Inorganic and Coordinated Compounds. 5th Ed. New York: Wiley & Sons, 1997.
35. [35]
  Liu Y, Liu W, Xu C, et al. New J. Chem., 2018, 42:3885-3891
36. [36]
  Arici M, Yesilel O Z, Tas M, et al. Cryst. Growth Des., 2016, 16:5448-5459 doi: 10.1021/acs.cgd.6b00912
37. [37]
  Li H Q, Ding Z Y, Pan Y, et al. Inorg. Chem. Front., 2016, 3:1363-1375 doi: 10.1039/C6QI00267F
38. [38]
  Li H J, He Y L, Li Q Q, et al. RSC Adv., 2017, 7:50035-50039 doi: 10.1039/C7RA08427G
39. [39]
  Wen L L, Lu Z D, Lin J G, et al. Cryst. Growth Des., 2007, 7:93-99
40. [40]
  Liu H J, Tao X T, Yang J X, et al. Cryst. Growth Des., 2008, 8:259-264 doi: 10.1021/cg070276j
41. [41]
  WANG Da-Wei, WANG Tao, YAN Tong, et al. Chinese J. Inorg. Chem., 2017, 33(8):1443-1449
42. [42]
  de Angelis F, Fantacci S, Sgamellotti A, et al. Inorg. Chem., 2006, 45:10576-10584 doi: 10.1021/ic061147f
1. [1]
  Jia JI , Zhaoyang GUO , Wenni LEI , Jiawei ZHENG , Haorong QIN , Jiahong YAN , Yinling HOU , Xiaoyan XIN , Wenmin WANG . Two dinuclear Gd(Ⅲ)-based complexes constructed by a multidentate diacylhydrazone ligand: Crystal structure, magnetocaloric effect, and biological activity. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 761-772. doi: 10.11862/CJIC.20240344
2. [2]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
3. [3]
  Xiumei LI , Linlin LI , Bo LIU , Yaru PAN . Syntheses, crystal structures, and characterizations of two cadmium(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 613-623. doi: 10.11862/CJIC.20240273
4. [4]
  Chao LIU , Jiang WU , Zhaolei JIN . Synthesis, crystal structures, and antibacterial activities of two zinc(Ⅱ) complexes bearing 5-phenyl-1H-pyrazole group. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1986-1994. doi: 10.11862/CJIC.20240153
5. [5]
  Ting WANG , Peipei ZHANG , Shuqin LIU , Ruihong WANG , Jianjun ZHANG . A Bi-CP-based solid-state thin-film sensor: Preparation and luminescence sensing for bioamine vapors. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1615-1621. doi: 10.11862/CJIC.20240134
6. [6]
  Yao HUANG , Yingshu WU , Zhichun BAO , Yue HUANG , Shangfeng TANG , Ruixue LIU , Yancheng LIU , Hong LIANG . Copper complexes of anthrahydrazone bearing pyridyl side chain: Synthesis, crystal structure, anticancer activity, and DNA binding. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 213-224. doi: 10.11862/CJIC.20240359
7. [7]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
8. [8]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
9. [9]
  Lulu DONG , Jie LIU , Hua YANG , Yupei FU , Hongli LIU , Xiaoli CHEN , Huali CUI , Lin LIU , Jijiang WANG . Synthesis, crystal structure, and fluorescence properties of Cd-based complex with pcu topology. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 809-820. doi: 10.11862/CJIC.20240171
10. [10]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
11. [11]
  Xiaoling WANG , Hongwu ZHANG , Daofu LIU . Synthesis, structure, and magnetic property of a cobalt(Ⅱ) complex based on pyridyl-substituted imino nitroxide radical. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 407-412. doi: 10.11862/CJIC.20240214
12. [12]
  Yan XU , Suzhi LI , Yan LI , Lushun FENG , Wentao SUN , Xinxing LI . Structure variation of cadmium naphthalene-diphosphonates with the changing rigidity of N-donor auxiliary ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 395-406. doi: 10.11862/CJIC.20240226
13. [13]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
14. [14]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
15. [15]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
16. [16]
  Shuyan ZHAO . Field-induced Co^Ⅱ single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231
17. [17]
  Yinling HOU , Jia JI , Hong YU , Xiaoyun BIAN , Xiaofen GUAN , Jing QIU , Shuyi REN , Ming FANG . A rhombic Dy₄-based complex showing remarkable single-molecule magnet behavior. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 605-612. doi: 10.11862/CJIC.20240251
18. [18]
  Xiaofen GUAN , Yating LIU , Jia LI , Yiwen HU , Haiyuan DING , Yuanjing SHI , Zhiqiang WANG , Wenmin WANG . Synthesis, crystal structure, and DNA-binding of binuclear lanthanide complexes based on a multidentate Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2486-2496. doi: 10.11862/CJIC.20240122
19. [19]
  Gaofeng WANG , Shuwen SUN , Yanfei ZHAO , Lixin MENG , Bohui WEI . Structural diversity and luminescence properties of three zinc coordination polymers based on bis(4-(1H-imidazol-1-yl)phenyl)methanone. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 849-856. doi: 10.11862/CJIC.20230479
20. [20]
  Yang Li , Yihan Chen , Jiaxin Luo , Qihuan Li , Yiwu Quan , Yixiang Cheng . Enhanced circularly polarized luminescence emission promoted by achiral dichroic oligomers of F8BT in cholesteric liquid crystal. Chinese Chemical Letters, 2024, 35(11): 109864-. doi: 10.1016/j.cclet.2024.109864

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(429)
HTML views(84)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142