Citation: HE Wei-Wei, Feng Si-Yang, QU Zhi-Rong, TANG Hui, WANG Zuo-Xiang. Syntheses, Crystal Structures and Properties of Cu(Ⅱ), Ni(Ⅱ) and Cd(Ⅱ) Complexes Based on 4-Methyl-3-phenyl-5-(2-pyridyl)-1, 2, 4-triazole[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(1): 155-164. doi: 10.11862/CJIC.2019.010 shu

Syntheses, Crystal Structures and Properties of Cu(Ⅱ), Ni(Ⅱ) and Cd(Ⅱ) Complexes Based on 4-Methyl-3-phenyl-5-(2-pyridyl)-1, 2, 4-triazole

1.
Key Laboratory of Organosilicon Chemistry and Materials Technology of Ministry of Education, Hangzhou Normal University, Hangzhou 311121, China
2.
School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China

Corresponding author: QU Zhi-Rong, quzr@hznu.edu.cn WANG Zuo-Xiang, wangzx0908@aliyun.com
Received Date: 15 September 2018
Revised Date: 24 October 2018

Figures(9)

Complexes of[CuL₂Cl]Cl·H₂O (1), [NiL₂(H₂O)₂](NO₃)₂ (2), [CuL₂(H₂O)₂](ClO₄)₂ (3) and[CdL₂(NO₃)₂]·CH₃CN (4) were synthesized by the reactions of 4-methyl-3-phenyl-5-(2-pyridyl)-1, 2, 4-triazole (L) with CuCl₂·2H₂O, Ni(NO₃)₂·6H₂O, Cu(ClO₄)₂·6H₂O and Cd(NO₃)₂·4H₂O, respectively. Their structures were determined by single crystal X-ray diffraction, and characterized by IR, UV-Vis, fluorescence and TGA. Complex 1 belongs to orthorhombic system with space group Fddd, and the central Cu1(Ⅱ) ion has a distorted tetragonal pyramid geometry[CuN₄Cl]. The complexes of 2, 3 and 4 all belong to monoclinic system with space groups P2₁/_n, P2₁/_n and P2₁/c, respectively. All the central metal ions of 2, 3 and 4 have distorted octahedral configuration[NiN₄O₂], [CuN₄O₂], [CdN₄O₂].
- 4-methyl-3-phenyl-5-(2-pyridyl)-1, 2, 4-triazole,
- complexes,
- syntheses,
- crystal structures,
- fluorescence
1. [1]
  Bloch E D, Murry L J, Queen W L, et al. J. Am. Chem. Soc., 2011, 133:14814-14822 doi: 10.1021/ja205976v
2. [2]
  Rojas S, Carmona F J, Maldonado C R, et al. Inorg. Chem., 2016, 55:2650-2663 doi: 10.1021/acs.inorgchem.6b00045
3. [3]
  王莉, 康全鹏, 郝静, 等.无机化学学报, 2018, 34(3):525-533
4. [4]
  Kumar R, Vats L, Bua S, et al. Eur. J. Med. Chem., 2018, 155:545-551 doi: 10.1016/j.ejmech.2018.06.021
5. [5]
  Bokor E, Efthimios K, Theodora G A S, et al. J. Med. Chem., 2017, 60:9251-9262 doi: 10.1021/acs.jmedchem.7b01056
6. [6]
  Dixit P P, Dixit P P, Thore S N. Eur. J. Med. Chem., 2016, 107:38-47 doi: 10.1016/j.ejmech.2015.10.054
7. [7]
  El-Sherief H A M, Youssif B G M, Bukhari S N A, et al. Eur. J. Med. Chem., 2018, 156:774-789 doi: 10.1016/j.ejmech.2018.07.024
8. [8]
  Polucci P, Magnaghi P, Angiolini M, et al. J. Med. Chem., 2013, 56:437-450 doi: 10.1021/jm3013213
9. [9]
  潘里, 陈有为, 刘卓, 等.有机化学, 2013, 33:542-550 doi: 10.6023/cjoc201211018
10. [10]
  Hugenberg V, Breyholz H J, Riemannet B, et al. J. Med. Chem., 2012, 55:4714-472 doi: 10.1021/jm300199g
11. [11]
  Shukia R, Mohan T P, Vishalakshi B, et al. J. Mol. Struct., 2017, 1134:426-434 doi: 10.1016/j.molstruc.2017.01.011
12. [12]
  Tian Y L, Jin J, Wang X J, et al. Eur. J. Med. Chem., 2014, 85:1-15 doi: 10.1016/j.ejmech.2014.07.081
13. [13]
  Insua I, Alvarado M, Masaguer C F, et al. Bioorg. Med. Chem. Lett., 2013, 23:5586-5591 doi: 10.1016/j.bmcl.2013.08.047
14. [14]
  Zhang J H, Dharavath S, Mitchell L A, et al. J. Am. Chem. Soc., 2016, 138:7500-7503 doi: 10.1021/jacs.6b03819
15. [15]
  Umeyama D, Horike S, Inukai U, et al. J. Am. Chem. Soc., 2012, 134:12780-12785 doi: 10.1021/ja304693r
16. [16]
  Jiang Y H, Liu Q L, Luo Y H, et al. J. Mol. Struct., 2017, 1149:136-141 doi: 10.1016/j.molstruc.2017.07.103
17. [17]
  Shang K X, Qiu J P, Zhang Q, et al. Inorg. Chem. Commun., 2017, 84:89-92 doi: 10.1016/j.inoche.2017.07.012
18. [18]
  Han X T, Yue M M, Liu G Y, et al. Polyhedron, 2012, 44:204-209 doi: 10.1016/j.poly.2012.07.012
19. [19]
  Hernandez G J, Ovejaket N, Ferrer S, et al. Inorg. Chem., 2013, 52:2289-2291 doi: 10.1021/ic3027946
20. [20]
  Wang J W, Li Y J, Chen C, et al. New J. Chem., 2017, 41:13846-13854 doi: 10.1039/C7NJ03445H
21. [21]
  Gural'skiy I A, Reshetnikov V A, Omelchenko I V, et al. J. Mol. Struct., 2017, 1127:164-168 doi: 10.1016/j.molstruc.2016.07.094
22. [22]
  Shi Z Z, Qin L, Zheng H G. Inorg. Chem. Commun., 2017, 79:21-24 doi: 10.1016/j.inoche.2017.03.017
23. [23]
  Bahemmat S, Ghassemzadeh M, Afsharpour M, et al. Polyhedron, 2015, 89:196-202 doi: 10.1016/j.poly.2014.12.050
24. [24]
  Sun Y H, Lemaur V, Beltrán J I, et al. Inorg. Chem., 2016, 55:5845-5852 doi: 10.1021/acs.inorgchem.6b00101
25. [25]
  Wang Y F, Li Z, Sun Y C, et al. Inorg. Chem. Commun., 2014, 44:25-28 doi: 10.1016/j.inoche.2014.02.043
26. [26]
  卢伟, 谢大景, 王作祥, 等.无机化学学报, 2010, 26(4):717-720
27. [27]
  Wang Y, Chen R, Jia W, et al. Inorg. Chem., 2018, 57:2381-2385 doi: 10.1021/acs.inorgchem.7b03047
28. [28]
  Muller J M, Galley S S, Albrecht S T E, et al. Inorg. Chem., 2016, 55:11454-11461 doi: 10.1021/acs.inorgchem.6b02005
29. [29]
  Sheldrick G M. SHELXTL Version 5.10, Structure Deter-mination Software Programs, Bruker Analytical X-ray Systems Inc., Wisconsin, USA, 1997.
30. [30]
  Zhu D R, Xu Y, Mei Y, et al. J. Mol. Struct., 2001, 559:119-125 doi: 10.1016/S0022-2860(00)00728-6
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沈阳化工大学材料科学与工程学院沈阳 110142