Citation: HE Wei-Wei, Feng Si-Yang, QU Zhi-Rong, TANG Hui, WANG Zuo-Xiang. Syntheses, Crystal Structures and Properties of Cu(Ⅱ), Ni(Ⅱ) and Cd(Ⅱ) Complexes Based on 4-Methyl-3-phenyl-5-(2-pyridyl)-1, 2, 4-triazole[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(1): 155-164. doi: 10.11862/CJIC.2019.010 shu

Syntheses, Crystal Structures and Properties of Cu(Ⅱ), Ni(Ⅱ) and Cd(Ⅱ) Complexes Based on 4-Methyl-3-phenyl-5-(2-pyridyl)-1, 2, 4-triazole

1.
Key Laboratory of Organosilicon Chemistry and Materials Technology of Ministry of Education, Hangzhou Normal University, Hangzhou 311121, China
2.
School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China

Corresponding author: QU Zhi-Rong, quzr@hznu.edu.cn WANG Zuo-Xiang, wangzx0908@aliyun.com
Received Date: 15 September 2018
Revised Date: 24 October 2018

Figures(9)

Complexes of[CuL₂Cl]Cl·H₂O (1), [NiL₂(H₂O)₂](NO₃)₂ (2), [CuL₂(H₂O)₂](ClO₄)₂ (3) and[CdL₂(NO₃)₂]·CH₃CN (4) were synthesized by the reactions of 4-methyl-3-phenyl-5-(2-pyridyl)-1, 2, 4-triazole (L) with CuCl₂·2H₂O, Ni(NO₃)₂·6H₂O, Cu(ClO₄)₂·6H₂O and Cd(NO₃)₂·4H₂O, respectively. Their structures were determined by single crystal X-ray diffraction, and characterized by IR, UV-Vis, fluorescence and TGA. Complex 1 belongs to orthorhombic system with space group Fddd, and the central Cu1(Ⅱ) ion has a distorted tetragonal pyramid geometry[CuN₄Cl]. The complexes of 2, 3 and 4 all belong to monoclinic system with space groups P2₁/_n, P2₁/_n and P2₁/c, respectively. All the central metal ions of 2, 3 and 4 have distorted octahedral configuration[NiN₄O₂], [CuN₄O₂], [CdN₄O₂].
- 4-methyl-3-phenyl-5-(2-pyridyl)-1, 2, 4-triazole,
- complexes,
- syntheses,
- crystal structures,
- fluorescence
1. [1]
  Bloch E D, Murry L J, Queen W L, et al. J. Am. Chem. Soc., 2011, 133:14814-14822 doi: 10.1021/ja205976v
2. [2]
  Rojas S, Carmona F J, Maldonado C R, et al. Inorg. Chem., 2016, 55:2650-2663 doi: 10.1021/acs.inorgchem.6b00045
3. [3]
  王莉, 康全鹏, 郝静, 等.无机化学学报, 2018, 34(3):525-533
4. [4]
  Kumar R, Vats L, Bua S, et al. Eur. J. Med. Chem., 2018, 155:545-551 doi: 10.1016/j.ejmech.2018.06.021
5. [5]
  Bokor E, Efthimios K, Theodora G A S, et al. J. Med. Chem., 2017, 60:9251-9262 doi: 10.1021/acs.jmedchem.7b01056
6. [6]
  Dixit P P, Dixit P P, Thore S N. Eur. J. Med. Chem., 2016, 107:38-47 doi: 10.1016/j.ejmech.2015.10.054
7. [7]
  El-Sherief H A M, Youssif B G M, Bukhari S N A, et al. Eur. J. Med. Chem., 2018, 156:774-789 doi: 10.1016/j.ejmech.2018.07.024
8. [8]
  Polucci P, Magnaghi P, Angiolini M, et al. J. Med. Chem., 2013, 56:437-450 doi: 10.1021/jm3013213
9. [9]
  潘里, 陈有为, 刘卓, 等.有机化学, 2013, 33:542-550 doi: 10.6023/cjoc201211018
10. [10]
  Hugenberg V, Breyholz H J, Riemannet B, et al. J. Med. Chem., 2012, 55:4714-472 doi: 10.1021/jm300199g
11. [11]
  Shukia R, Mohan T P, Vishalakshi B, et al. J. Mol. Struct., 2017, 1134:426-434 doi: 10.1016/j.molstruc.2017.01.011
12. [12]
  Tian Y L, Jin J, Wang X J, et al. Eur. J. Med. Chem., 2014, 85:1-15 doi: 10.1016/j.ejmech.2014.07.081
13. [13]
  Insua I, Alvarado M, Masaguer C F, et al. Bioorg. Med. Chem. Lett., 2013, 23:5586-5591 doi: 10.1016/j.bmcl.2013.08.047
14. [14]
  Zhang J H, Dharavath S, Mitchell L A, et al. J. Am. Chem. Soc., 2016, 138:7500-7503 doi: 10.1021/jacs.6b03819
15. [15]
  Umeyama D, Horike S, Inukai U, et al. J. Am. Chem. Soc., 2012, 134:12780-12785 doi: 10.1021/ja304693r
16. [16]
  Jiang Y H, Liu Q L, Luo Y H, et al. J. Mol. Struct., 2017, 1149:136-141 doi: 10.1016/j.molstruc.2017.07.103
17. [17]
  Shang K X, Qiu J P, Zhang Q, et al. Inorg. Chem. Commun., 2017, 84:89-92 doi: 10.1016/j.inoche.2017.07.012
18. [18]
  Han X T, Yue M M, Liu G Y, et al. Polyhedron, 2012, 44:204-209 doi: 10.1016/j.poly.2012.07.012
19. [19]
  Hernandez G J, Ovejaket N, Ferrer S, et al. Inorg. Chem., 2013, 52:2289-2291 doi: 10.1021/ic3027946
20. [20]
  Wang J W, Li Y J, Chen C, et al. New J. Chem., 2017, 41:13846-13854 doi: 10.1039/C7NJ03445H
21. [21]
  Gural'skiy I A, Reshetnikov V A, Omelchenko I V, et al. J. Mol. Struct., 2017, 1127:164-168 doi: 10.1016/j.molstruc.2016.07.094
22. [22]
  Shi Z Z, Qin L, Zheng H G. Inorg. Chem. Commun., 2017, 79:21-24 doi: 10.1016/j.inoche.2017.03.017
23. [23]
  Bahemmat S, Ghassemzadeh M, Afsharpour M, et al. Polyhedron, 2015, 89:196-202 doi: 10.1016/j.poly.2014.12.050
24. [24]
  Sun Y H, Lemaur V, Beltrán J I, et al. Inorg. Chem., 2016, 55:5845-5852 doi: 10.1021/acs.inorgchem.6b00101
25. [25]
  Wang Y F, Li Z, Sun Y C, et al. Inorg. Chem. Commun., 2014, 44:25-28 doi: 10.1016/j.inoche.2014.02.043
26. [26]
  卢伟, 谢大景, 王作祥, 等.无机化学学报, 2010, 26(4):717-720
27. [27]
  Wang Y, Chen R, Jia W, et al. Inorg. Chem., 2018, 57:2381-2385 doi: 10.1021/acs.inorgchem.7b03047
28. [28]
  Muller J M, Galley S S, Albrecht S T E, et al. Inorg. Chem., 2016, 55:11454-11461 doi: 10.1021/acs.inorgchem.6b02005
29. [29]
  Sheldrick G M. SHELXTL Version 5.10, Structure Deter-mination Software Programs, Bruker Analytical X-ray Systems Inc., Wisconsin, USA, 1997.
30. [30]
  Zhu D R, Xu Y, Mei Y, et al. J. Mol. Struct., 2001, 559:119-125 doi: 10.1016/S0022-2860(00)00728-6
1. [1]
  Shuwen SUN , Gaofeng WANG . Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 613-620. doi: 10.11862/CJIC.20230368
2. [2]
  Long TANG , Yaxin BIAN , Luyuan CHEN , Xiangyang HOU , Xiao WANG , Jijiang WANG . Syntheses, structures, and properties of three coordination polymers based on 5-ethylpyridine-2,3-dicarboxylic acid and N-containing ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1975-1985. doi: 10.11862/CJIC.20240180
3. [3]
  Xiaofen GUAN , Yating LIU , Jia LI , Yiwen HU , Haiyuan DING , Yuanjing SHI , Zhiqiang WANG , Wenmin WANG . Synthesis, crystal structure, and DNA-binding of binuclear lanthanide complexes based on a multidentate Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2486-2496. doi: 10.11862/CJIC.20240122
4. [4]
  Dongdong YANG , Jianhua XUE , Yuanyu YANG , Meixia WU , Yujia BAI , Zongxuan WANG , Qi MA . Design and synthesis of two coordination polymers for the rapid detection of ciprofloxacin based on triphenylpolycarboxylic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2466-2474. doi: 10.11862/CJIC.20240266
5. [5]
  Xiaxia LIU , Xiaofang MA , Luxia GUO , Xianda HAN , Sisi FENG . Structure and magnetic properties of Mn(Ⅱ) coordination polymers regulated by N-auxiliary ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 587-596. doi: 10.11862/CJIC.20240269
6. [6]
  Chao LIU , Jiang WU , Zhaolei JIN . Synthesis, crystal structures, and antibacterial activities of two zinc(Ⅱ) complexes bearing 5-phenyl-1H-pyrazole group. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1986-1994. doi: 10.11862/CJIC.20240153
7. [7]
  Weizhong LING , Xiangyun CHEN , Wenjing LIU , Yingkai HUANG , Yu LI . Syntheses, crystal structures, and catalytic properties of three zinc(Ⅱ), cobalt(Ⅱ) and nickel(Ⅱ) coordination polymers constructed from 5-(4-carboxyphenoxy)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1803-1810. doi: 10.11862/CJIC.20240068
8. [8]
  Zhenghua ZHAO , Qin ZHANG , Yufeng LIU , Zifa SHI , Jinzhong GU . Syntheses, crystal structures, catalytic and anti-wear properties of nickel(Ⅱ) and zinc(Ⅱ) coordination polymers based on 5-(2-carboxyphenyl)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 621-628. doi: 10.11862/CJIC.20230342
9. [9]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
10. [10]
  Xiumei LI , Linlin LI , Bo LIU , Yaru PAN . Syntheses, crystal structures, and characterizations of two cadmium(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 613-623. doi: 10.11862/CJIC.20240273
11. [11]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
12. [12]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
13. [13]
  Yao HUANG , Yingshu WU , Zhichun BAO , Yue HUANG , Shangfeng TANG , Ruixue LIU , Yancheng LIU , Hong LIANG . Copper complexes of anthrahydrazone bearing pyridyl side chain: Synthesis, crystal structure, anticancer activity, and DNA binding. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 213-224. doi: 10.11862/CJIC.20240359
14. [14]
  Anqiu LIU , Long LIN , Dezhi ZHANG , Junyu LEI , Kefeng WANG , Wei ZHANG , Junpeng ZHUANG , Haijun HAO . Synthesis, structures, and catalytic activity of aluminum and zinc complexes chelated by 2-((2,6-dimethylphenyl)amino)ethanolate. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 791-798. doi: 10.11862/CJIC.20230424
15. [15]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
16. [16]
  Huirong LIU , Hao XU , Dunru ZHU , Junyong ZHANG , Chunhua GONG , Jingli XIE . Syntheses, structures, photochromic and photocatalytic properties of two viologen-polyoxometalate hybrid materials. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1368-1376. doi: 10.11862/CJIC.20240066
17. [17]
  Xinyi Cao , Yucheng Jin , Hailong Wang , Xu Ding , Xiaolin Liu , Baoqiu Yu , Xiaoning Zhan , Jianzhuang Jiang . A tetraaldehyde-derived porous organic cage and covalent organic frameworks: Syntheses, structures, and iodine vapor capture. Chinese Chemical Letters, 2024, 35(9): 109201-. doi: 10.1016/j.cclet.2023.109201
18. [18]
  Yadan SUN , Xinfeng LI , Qiang LIU , Oshio Hiroki , Yinshan MENG . Structures and magnetism of dinuclear Co complexes based on imine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2212-2220. doi: 10.11862/CJIC.20240131
19. [19]
  Xiao SANG , Qi LIU , Jianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158
20. [20]
  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(347)
HTML views(58)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142