Citation: WANG Fei, TIAN Yi-Guang, ZHANG Qiao. Lattice Parameters and Luminescent Property of Single-Phase White Light-Emitting Ca_0.955-xAl₂Si₂O₈: 0.045Eu²⁺, xMn²⁺ Phosphors[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(1): 25-33. doi: 10.11862/CJIC.2019.003 shu

Lattice Parameters and Luminescent Property of Single-Phase White Light-Emitting Ca_0.955-xAl₂Si₂O₈: 0.045Eu²⁺, xMn²⁺ Phosphors

WANG Fei ^1,2,, ,
TIAN Yi-Guang ^3,, ,
ZHANG Qiao ³

1.
Experimental Center of Anhui Sanlian University, Hefei 230601, China
2.
College of Chemistry and Chemical Engineering, Anhui University, Hefei 230601, China
3.
College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, Zhejiang 325035, China

Corresponding author: WANG Fei, wangfchina@163.com TIAN Yi-Guang, gytian@wzu.edu.cn
Received Date: 7 August 2018
Revised Date: 23 October 2018

Figures(9)

A series of phosphors Ca_0.955-xAl₂Si₂O₈:0.045Eu²⁺, xMn²⁺ (x=0, 0.05, 0.10, 0.15, 0.20, 0.25, 0.30, 0.325, 0.35, 0.375, 0.40, 0.425) were prepared via solid-state reaction. As Mn²⁺ was substituted for Ca²⁺ into the crystal lattice, the effect on its lattice parameters and spectral properties were discussed. The results show that complete solid solutions were formed in the whole range for x while Mn²⁺ enterers CaAl₂Si₂O₈ lattice and substitutes for Ca²⁺. The samples belong to triclinic system, and P1 space group. The lattice parameters (a, b, c, γ) and unit cell volume of phosphors Ca_0.955-xAl₂Si₂O₈:0.045Eu²⁺, xMn²⁺ decreased linearly, and the lattice parameters (α, β) increased linearly as Mn²⁺ content increased in the phosphors. When Mn²⁺ substitutes for Ca²⁺ the most obvious change is in cell parameter a, the second is c, and the minimum is b. When excited by 357 nm, the Ca_0.955-xAl₂Si₂O₈:0.045Eu²⁺, xMn²⁺ phosphors exhibited two emission peaks centered at 433 and 567 nm, which are ascribed to 5d→4f and ⁴T₁(⁴G)→⁶A₁(⁶S) transition of Eu²⁺ and Mn²⁺, respectively. The results show that the existence of efficient energy transfer between Eu²⁺ and Mn²⁺ in phosphors Ca_0.955-xAl₂Si₂O₈:0.045Eu²⁺, xMn²⁺, the critical distance is calculated to be 0.947 1 nm. The energy transfer between Eu²⁺ and Mn²⁺ was due to the electric dipole-dipole interaction of the resonance transfer. Under the effective excitation of the ultraviolet chip, by changing the amount of Mn²⁺ doping, the color of the emitted light of the phosphors can be gradually shifted from blue light (0.158 2, 0.086) to near white light (0.295 3, 0.298 9). UV-excited single-phase white light-emitting phosphors for white LEDs were available.
- inorganic solid chemistry,
- CaAl₂Si₂O₈:Eu²⁺, Mn²⁺,
- lattice parameters,
- spectral characteristics,
- energy transfer
1. [1]
  Nakamura S, Mukai T, Senoh M. Appl. Phys. Lett., 1994, 64:1687-1689 doi: 10.1063/1.111832
2. [2]
  Ci Z, Que M, Shi Y, et al. Inorg. Chem., 2014, 53:2195-2199 doi: 10.1021/ic402859s
3. [3]
  Chen J, Zhang N, Guo C, et al. ACS Appl. Mater. Interfaces, 2016, 8:20856-20864 doi: 10.1021/acsami.6b06102
4. [4]
  Zhang X, Tsai Y T, Wu S M, et al. ACS Appl. Mater. Interfaces, 2016, 8:19612-19617
5. [5]
  Katrin H, Wolfgang S. Chem. Mater., 2017, 29:4590-4596 doi: 10.1021/acs.chemmater.7b01363
6. [6]
  Shang M M, Liang S S, Lian H Z, et al. Inorg. Chem., 2017, 56:6131-6140 doi: 10.1021/acs.inorgchem.7b00092
7. [7]
  Chubert E F S, Kim J K. Science, 2005, 308(5726):1274-1278 doi: 10.1126/science.1108712
8. [8]
  Ye S, Xiao F, Pan Y X, et al. Mater. Sci. Eng. R, 2010, 71:1-34 doi: 10.1016/j.mser.2010.07.001
9. [9]
  Wang Y H, Wang Z Y, Zhang P Y, et al. Mater. Lett., 2004, 58:3308-3311 doi: 10.1016/j.matlet.2004.06.024
10. [10]
  Li L, Pan Y, Wang W J, et al. J. Alloys Compd., 2018, 731(1):496-503
11. [11]
  Liu W R, Lei B. J. Nanosci. Nanotechnol., 2018, 18(1):374-380
12. [12]
  Fan J Y, Gou J, Chen Y L, et al. J. Alloys Compd., 2018, 731(1):796-804
13. [13]
  Liang S S, Dang P P, Li G G, et al. J. Mater. Chem. C, 2018, 6:6714-6725 doi: 10.1039/C8TC01825A
14. [14]
  Li X Q, Xie X Z, Wei H T, et al. Luminescence, 2017, 32(6):1025-1030 doi: 10.1002/bio.v32.6
15. [15]
  Kuo C H, Sheu J K, Chang S J, et al. Jpn. J. Appl. Phys., Part 1, 2003, 42(4B):2284-2287
16. [16]
  Kim J S, Kang J Y, Jeon P E, et al. Jpn. J. Appl. Phys. Part 1, 2004, 43(3):989-992 doi: 10.1143/JJAP.43.989
17. [17]
  WANG Fei, TIAN Yi-Guang, ZHANG Qiao, et al. Chinese J. Inorg. Chem., 2010, 26(12):2170-2174
18. [18]
  HAO Run-Rong, FANG Xi-Yi, NIU Shao -Chong. Inorganic Chemistry Books. Beijing:Science Press, 1998.
19. [19]
  Chiari G, Calleri M, Bruno E. Am. Mineral., 1975, 60(1):111-119
20. [20]
  LIU Hong-Kai. Progress in Physics, 1985, 5(2):206-207
21. [21]
  Dorenbos P. J. Lumin., 2003, 104(4):239-260 doi: 10.1016/S0022-2313(03)00078-4
22. [22]
  Zhang X M, Zeng H P, Su Q. J. Alloys Compd., 2007, 441(1/2):259-262
23. [23]
  Rack P D, Holloway P H. Mater. Sci. Eng. R, 1998, 21:171-219 doi: 10.1016/S0927-796X(97)00010-7
24. [24]
  Ohno K, Abe T. J. Electrochem. Soc., 1986, 133:638-643 doi: 10.1149/1.2108635
25. [25]
  Paulose P I, Jose G, Thomas V, et al. J. Phys. Chem. Solids, 2003, 64(5):841-846 doi: 10.1016/S0022-3697(02)00416-X
26. [26]
  XIONG Xiao-Bo, YUAN Xi-Ming, LIU Jin-Cun, et al. Acta Phys. Sin., 2015, 64(1):017801(6 Pages)
27. [27]
  Jiao H, Liao F H, Tian S J, et al. J. Electrochem. Soc., 2003, 150:H220-H224 doi: 10.1149/1.1601231
1. [1]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
2. [2]
  Yi Yang , Xin Zhou , Miaoli Gu , Bei Cheng , Zhen Wu , Jianjun Zhang . S型ZnO/CdIn₂S₄光催化剂制备H₂O₂偶联苄胺氧化的超快电子转移飞秒吸收光谱研究. Acta Physico-Chimica Sinica, 2025, 41(6): 100064-. doi: 10.1016/j.actphy.2025.100064
3. [3]
  Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn²⁺ doped quasi-two-dimensional perovskites (PEA)₂Pb_yMn_1-yBr₄. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473
4. [4]
  Liuchuang Zhao , Wenbo Chen , Leqian Hu . Discussion on Improvement of Teaching Contents about Common Evaluation Parameters in Analytical Chemistry. University Chemistry, 2024, 39(2): 379-391. doi: 10.3866/PKU.DXHX202308079
5. [5]
  Renshu Huang , Jinli Chen , Xingfa Chen , Tianqi Yu , Huyi Yu , Kaien Li , Bin Li , Shibin Yin . Synergized oxygen vacancies with Mn2O3@CeO2 heterojunction as high current density catalysts for Li–O2 batteries. Chinese Journal of Structural Chemistry, 2023, 42(11): 100171-100171. doi: 10.1016/j.cjsc.2023.100171
6. [6]
  Min WANG , Dehua XIN , Yaning SHI , Wenyao ZHU , Yuanqun ZHANG , Wei ZHANG . Construction and full-spectrum catalytic performance of multilevel Ag/Bi/nitrogen vacancy g-C₃N₄/Ti₃C₂T_x Schottky junction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1123-1134. doi: 10.11862/CJIC.20230477
7. [7]
  Hongzhi Zhang , Hong Li , Asif Ali Haider , Junpeng Li , Zhi Xie , Hongming Jiang , Conglin Liu , Rui Wang , Jing Zhu . An unexpected role of lanthanide substitution in thermally responsive phosphors NaLnTe2O7: Eu3+ (Ln = Y and Gd). Chinese Journal of Structural Chemistry, 2025, 44(2): 100509-100509. doi: 10.1016/j.cjsc.2024.100509
8. [8]
  Zizhuo Liang , Fuming Du , Ning Zhao , Xiangxin Guo . Revealing the reason for the unsuccessful fabrication of Li3Zr2Si2PO12 by solid state reaction. Chinese Journal of Structural Chemistry, 2023, 42(11): 100108-100108. doi: 10.1016/j.cjsc.2023.100108
9. [9]
  Tong Zhou , Xue Liu , Liang Zhao , Mingtao Qiao , Wanying Lei . Efficient Photocatalytic H₂O₂ Production and Cr(VI) Reduction over a Hierarchical Ti₃C₂/In₄SnS₈ Schottky Junction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309020-. doi: 10.3866/PKU.WHXB202309020
10. [10]
  Tianlong Zhang , Rongling Zhang , Hongsheng Tang , Yan Li , Hua Li . Online Monitoring and Mechanistic Analysis of 3,5-diamino-1,2,4-triazole (DAT) Synthesis via Raman Spectroscopy: A Recommendation for a Comprehensive Instrumental Analysis Experiment. University Chemistry, 2024, 39(6): 303-311. doi: 10.3866/PKU.DXHX202312006
11. [11]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
12. [12]
  Xinyu Yin , Haiyang Shi , Yu Wang , Xuefei Wang , Ping Wang , Huogen Yu . Spontaneously Improved Adsorption of H₂O and Its Intermediates on Electron-Deficient Mn^(3+δ)+ for Efficient Photocatalytic H₂O₂ Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312007-. doi: 10.3866/PKU.WHXB202312007
13. [13]
  Yan ZHAO , Jiaxu WANG , Zhonghu LI , Changli LIU , Xingsheng ZHAO , Hengwei ZHOU , Xiaokang JIANG . Gd³⁺-doped Sc₂W3O₁₂: Eu³⁺ red phosphor: Preparation and luminescence performance. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 461-468. doi: 10.11862/CJIC.20240316
14. [14]
  Xin XIONG , Qian CHEN , Quan XIE . First principles study of the photoelectric properties and magnetism of La and Yb doped AlN. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1519-1527. doi: 10.11862/CJIC.20240064
15. [15]
  Xueyu Lin , Ruiqi Wang , Wujie Dong , Fuqiang Huang . 高性能双金属氧化物负极的理性设计及储锂特性. Acta Physico-Chimica Sinica, 2025, 41(3): 2311005-. doi: 10.3866/PKU.WHXB202311005
16. [16]
  Xingyuan Lu , Yutao Yao , Junjing Gu , Peifeng Su . Energy Decomposition Analysis and Its Application in the Many-Body Effect of Water Clusters. University Chemistry, 2025, 40(3): 100-107. doi: 10.12461/PKU.DXHX202405074
17. [17]
  Liang MA , Honghua ZHANG , Weilu ZHENG , Aoqi YOU , Zhiyong OUYANG , Junjiang CAO . Construction of highly ordered ZIF-8/Au nanocomposite structure arrays and application of surface-enhanced Raman spectroscopy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1743-1754. doi: 10.11862/CJIC.20240075
18. [18]
  Yi Li , Zhaoxiang Cao , Peng Liu , Xia Wu , Dongju Zhang . Revealing the Coloration and Color Change Mechanisms of the Eriochrome Black T Indicator through Computational Chemistry and UV-Visible Absorption Spectroscopy. University Chemistry, 2025, 40(3): 132-139. doi: 10.12461/PKU.DXHX202405154
19. [19]
  Mingjiao Lu , Zhixing Wang , Gui Luo , Huajun Guo , Xinhai Li , Guochun Yan , Qihou Li , Xianglin Li , Ding Wang , Jiexi Wang . Boosting the performance of LiNi_0.90Co_0.06Mn_0.04O₂ electrode by uniform Li₃PO₄ coating via atomic layer deposition. Chinese Chemical Letters, 2024, 35(5): 108638-. doi: 10.1016/j.cclet.2023.108638
20. [20]
  Shuo Li , Xinran Liu , Yongjie Zheng , Jun Ma , Shijie You , Heshan Zheng . Effective peroxydisulfate activation by CQDs-MnFe₂O₄@ZIF-8 catalyst for complementary degradation of bisphenol A by free radicals and non-radical pathways. Chinese Chemical Letters, 2024, 35(5): 108971-. doi: 10.1016/j.cclet.2023.108971

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(911)
HTML views(172)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Lattice Parameters and Luminescent Property of Single-Phase White Light-Emitting Ca0.955-xAl2Si2O8: 0.045Eu2+, xMn2+ Phosphors

Metrics

通讯作者: 陈斌, bchen63@163.com

Lattice Parameters and Luminescent Property of Single-Phase White Light-Emitting Ca_0.955-xAl₂Si₂O₈: 0.045Eu²⁺, xMn²⁺ Phosphors