Citation: LIU Guo-Cheng, YU Hui-Xuan, GAO Yue, TANG Shuang, FENG Cong. A 2-Fold Interpenetrated Cd(Ⅱ) Complex: Synthesis, Structure and Bifunctional Fluorescent Sensing Property[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(12): 2238-2244. doi: 10.11862/CJIC.2018.270 shu

A 2-Fold Interpenetrated Cd(Ⅱ) Complex: Synthesis, Structure and Bifunctional Fluorescent Sensing Property

Department of Chemistry, Bohai University, Jinzhou, Liaoning 121000, China

Corresponding author: LIU Guo-Cheng, lgch1004@sina.com
Received Date: 7 June 2018
Revised Date: 26 September 2018

Figures(11)

A new Cd(Ⅱ) coordination polymer {[Cd(BDC)(L)]·1.5H₂O}_n (1)[L=N, N'-bis (4-pyridin-3-yl)-5-hydroxyi-sophthalamide, H₂BDC=1, 4-benzenedicarboxylic acid) has been hydrothermally synthesized and structurally characterized by single crystal X-ray diffraction analysis. Complex 1 crystalizes in monoclinic, space group C2/c:a=2.171 45(8), b=1.605 34(6), c=1.678 04(6) nm, Z=8, V=5.116 8(3>) nm³, D_c=1.65 6 g·cm^-3, F(000)=2 568, μ=0.914 mm^-1, the final R=0.026 5 and wR=0.067 6. The crystal structure analysis indicates that the Cd(Ⅱ) cation is six-coordinated by two pyridyl N atoms from two L ligands, four O atoms from two BDC anions. The BDC anions connects adjacent Cd(Ⅱ) ions to form 1D chain, which is linked by pairs of L to generate two-dimensional 63 connected layer with a 2-fold parallel-interpenetrated structure. The phase purity, thermal stability, fluorescent property of 1 and fluorescence sensing properties of 1 for Fe³⁺ and dichloromethane have been studied investigated.
- cadmium (Ⅱ) complex,
- hydrothermal synthesis,
- crystal structure,
- fluorescence sensing
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