Citation: WANG Wen-Guang, XU Xiao-Mu, LI Bin, REN Xiao, GUO Yu-Zhong, HUANG Rui-An. Preparation and Electrochemical Properties of Nano-Si by Magnesiothermic Reduction Reaction of Fumed Silica[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(12): 2219-2226. doi: 10.11862/CJIC.2018.265 shu

Preparation and Electrochemical Properties of Nano-Si by Magnesiothermic Reduction Reaction of Fumed Silica

WANG Wen-Guang ¹ ,
XU Xiao-Mu ² ,
LI Bin ³ ,
REN Xiao ¹ ,
GUO Yu-Zhong ^1,, ,
HUANG Rui-An ^4,,

1.
Faculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming 650093, China
2.
Kunshan Innovation Institute of Nanjing University, Suzhou, Jiangsu 215347, China
3.
Ganzhou Xinlong New Energy Material Co., Ltd., Ganzhou, Jiangxi 341000, China
4.
National Engineering Laboratory for Vacuum Metallurgy, Kunming University of Science and Technology, Kunming 650093, China

Corresponding author: GUO Yu-Zhong, yzguocn62@sina.com HUANG Rui-An, rahuang2002@163.com
Received Date: 18 July 2018
Revised Date: 12 September 2018

Figures(7)

Using fumed silica (FS) as Si precursor, the structure NPs-Si@SiO_x@C nanocomposite was prepared by magnesiothermic reduction reaction and coating the obtained NPs-Si with SiO_x and C, which was used as the lithium battery negative and tested for electrochemical performance. The results show that the magnesiothermic reduction reaction process was carried out in two steps. Firstly, SiO₂ reacted with Mg to form Mg₂Si intermediate phase, and then Mg₂Si continued to react with SiO₂ to form Si. And a high Si yield of magnesiothermic reduction reaction of fumed silica reached 87.9% according to the rule. The NPs-Si@SiO_x@C anode had a capacity platform of 1 300 mAh·g^-1 at a current density of 2.0 A·g^-1 in the electrochemical performance test. And the specific capacity is 964.2 mAh·g^-1 after 1 000 cycles with a capacity retention rate of 75%.
- nano-Si,
- high-performance anode material,
- magnesiothermic reduction,
- fumed silica,
- Mg₂Si intermediate phase
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