Citation: GUO Hu, LI Ling-Hui, WANG Tao, FAN Xiao-Li, SONG Li, GONG Hao, XIA Wei, JIANG Cheng, GAO Bin, HE Jian-Ping. Preparation and Catalytic Activity for Oxygen Reduction Reaction of Tungsten Nitirde-Tungsten/Nitrogen Doped Ordered Mesoporous Carbon[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(11): 2032-2040. doi: 10.11862/CJIC.2018.263 shu

Preparation and Catalytic Activity for Oxygen Reduction Reaction of Tungsten Nitirde-Tungsten/Nitrogen Doped Ordered Mesoporous Carbon

Jiangsu Key Laboratory of Materials and Technology for Energy Conversion, College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China

Corresponding author: HE Jian-Ping, jianph@nuaa.edu.cn
Received Date: 18 July 2018
Revised Date: 17 September 2018

Figures(8)

Tungsten nitride-Tungsten/nitrogen doped ordered mesoporous carbon (WN/W-NOMC), as a non-precious-metal cathode catalyst for oxygen reduction reaction (ORR), was successfully synthesized through a soft-template method.The amount of nitrogen was adjusted by urea, and when the content of nitrogen was 7%(w/w), the obtained composite had highly ordered mesoporous structure, and its specific surface area reached to 835 m²·g^-1.Transmission electron microscope (TEM) shows that the catalytic particles were uniform supported on NOMC.ORR test was conducted in O₂-staturated 0.1 mol·L^-1 KOH solution, the oneset potential is 0.87 V (vs RHE) and the limiting current density is 4.49 mA·cm^-2.The transfer number of electron was 3.4, which was close to commercial 20%(w/w) Pt/C (3.8), indicated that WN-NOMC exhibited an approximate 4e^- transfer pathway during the ORR process.Though the catalytic activity is less than Pt/C, the excellent methanol tolerance and long-time electrochemical stability make WN-W/NOMC to be a potential electrode catalyst for ORR.
- tungsten nitride,
- electrocatalysis,
- ordered mesoporous carbon,
- oxygen reduction reaction,
- fuel cells
1. [1]
  Chen Z W, Higgins D, Yu A P, et al. Energy Environ. Sci., 2011, 4(9):3167-3192 doi: 10.1039/c0ee00558d
2. [2]
  Wang X X, Cullen D A, Pan Y T, et al. Adv. Mater., 2018, 30(11):1706758 doi: 10.1002/adma.201706758
3. [3]
  Zhang C, Wang Y C, An B, et al. Adv. Mater., 2017, 29(4):1604556 doi: 10.1002/adma.v29.4
4. [4]
  Sui S, Wang X Y, Zhou X T, et al. J. Mater. Chem. A, 2017, 5(5):1808-1825 doi: 10.1039/C6TA08580F
5. [5]
  Xue H R, Tang J, Gong H, et al. ACS Appl. Mater. Interfaces, 2016, 8(32):20766-20771 doi: 10.1021/acsami.6b05856
6. [6]
  Kulkarni A, Siahrostami S, Patel A, et al. Chem. Rev., 2018, 118(5):2302-2312 doi: 10.1021/acs.chemrev.7b00488
7. [7]
  Xue H R, Wu S C, Tang J, et al. ACS Appl. Mater. Interfaces, 2016, 8(13):8427-8435 doi: 10.1021/acsami.5b10856
8. [8]
  Xue H R, Wang T, Gong H, et al. Catalysts, 2017, 7(6):189(9 Pages)
9. [9]
  Guo D H, Shibuya R, Akiba C, et al. Science, 2016, 351(6271):361-365 doi: 10.1126/science.aad0832
10. [10]
  Song L, Wang T, Ma Y O, et al. Chem. Eur. J., 2017, 23(14):3398-3405 doi: 10.1002/chem.201605026
11. [11]
  Xue H R, Wang T, Zhao J Q, et al. Carbon, 2016, 104:10-19 doi: 10.1016/j.carbon.2016.03.026
12. [12]
  Yin P Q, Yao T, Wu Y A, et al. Angew. Chem. Int. Ed., 2016, 55(36):10800-10805 doi: 10.1002/anie.201604802
13. [13]
  Wang Y J, Zhao N, Fang B, et al. Chem. Rev., 2015, 115(9):3433-3467 doi: 10.1021/cr500519c
14. [14]
  Song L, Wang T, Wang Y L, et al. ACS Appl. Mater. Interfaces, 2017, 9(4):3713-3722 doi: 10.1021/acsami.6b14754
15. [15]
  WANG Qi-Chen, WANG Jing, LEI Yong-Peng, et al. Chinese J. Inorg. Chem., 2018, 34(5):807-822
16. [16]
  Li G R, Song J, Pan G L, et al. Energy Environ. Sci., 2011, 4(5):1680-1683 doi: 10.1039/c1ee01105g
17. [17]
  Zhong H X, Zhang H M, Liang Y M, et al. J. Power Sources, 2007, 164(2):572-577 doi: 10.1016/j.jpowsour.2006.11.080
18. [18]
  Dong Y Z, Li J H. Chem. Commun., 2015, 51(3):572-575 doi: 10.1039/C4CC07137A
19. [19]
  Zhou Y, Xue H R, Wang T, et al. Chem. Asian J., 2017, 12(1):60-66 doi: 10.1002/asia.v12.1
20. [20]
  WANG Yan-En, CAO Shuang, LIU Shu-Jing, et al. Chinese J. Inorg. Chem., 2015, 31(1):23-28
21. [21]
  SU Jing, WANG Yan-Hui, DONG Liang, et al. Chinese J. Inorg. Chem., 2018, 34(1):1-10
22. [22]
  LI Ying-Ying, HUANG Li-Zhen, CAI Xiao -Wei, et al. Chinese J. Inorg. Chem., 2018, 34(8):1437-1447
23. [23]
  LIU Guang, TAO Rui, ZHAO Yong, et al. Chinese J. Inorg. Chem., 2018, 34(8):1494-1500
24. [24]
  CHEN Ya-Ling, SONG Li, GUO Hu, et al. Chinese J. Inorg. Chem., 2016, 32(4):633-640
25. [25]
  PAN Xu-Chen, TANG Jing, XUE Hai-Rong, et al. Chinese J. Inorg. Chem., 2015, 31(2):282-290
26. [26]
  Gong H, Xue H R, Wang T, et al. ACS Appl. Mater. Interfaces, 2016, 8(28):18060-18068 doi: 10.1021/acsami.6b04810
27. [27]
  Guo H, Wen D H, Wang T, et al. J. Porous Mater., 2018, https://doi.org/10.1007/s10934-018-0614-3
28. [28]
  Wan K, Long G F, Liu M Y, et al. Appl. Catal., B, 2015, 165:566-571 doi: 10.1016/j.apcatb.2014.10.054
29. [29]
  Wang D W, Su D. Energy Environ. Sci., 2014, 7(2):576-591 doi: 10.1039/c3ee43463j
30. [30]
  Shui J L, Wang M, Du F, et al. Sci. Adv., 2015, 1(1):e1400129 doi: 10.1126/sciadv.1400129
31. [31]
  Wei W, Liang H W, Parvez K, et al. Angew. Chem. Int. Ed., 2014, 126(6):1596-1600 doi: 10.1002/ange.201307319
32. [32]
  Sun Y Y, Sinev I, Ju W, et al. ACS Catal., 2018, 8(4):2844-2856 doi: 10.1021/acscatal.7b03464
33. [33]
  Tang J, Liu J, Li C L, et al. Angew. Chem. Int. Ed., 2015, 54(2):588-593
34. [34]
  Wang T, Tang J, Fan X L, et al. Nanoscale, 2014, 6(10):5359-5371 doi: 10.1039/C4NR00396A
35. [35]
  Xia Y, Mokaya R. Chem. Mater., 2005, 17(6):1553-1560 doi: 10.1021/cm048057y
36. [36]
  Moncoffre N, Hollinger G, Jaffrezic H, et al. Nucl. Instrum. Methods, 1985, 7-8(1):177-183
37. [37]
  Marton D, Boyd K J, Al-bayati A H, et al. Phys. Rev. Lett., 1994, 73(1):118-121 doi: 10.1103/PhysRevLett.73.118
38. [38]
  Ballutaud D, Simon N, Girard H, et al. Diamond Relat. Mater., 2006, 15(4):716-719
39. [39]
  Li X L, Wen Y, Wang S, et al. China Pet. Process. Petrochem. Technol., 2014, 16(3):84-91
40. [40]
  Shao Y Y, Sui J H, Yin G P, et al. Appl. Catal., B, 2008, 79(1):89-99 doi: 10.1016/j.apcatb.2007.09.047
41. [41]
  Jukk K, Kongi N, Matisen L, et al. Electrochim. Acta, 2014, 137:206-212 doi: 10.1016/j.electacta.2014.06.020
42. [42]
  Cao H L, Zhou X F, Qin Z H, et al. Carbon, 2013, 56:218-223 doi: 10.1016/j.carbon.2013.01.005
43. [43]
  Hulicova-Jurcakova D, Seredych M, Lu G Q, et al. Adv. Funct. Mater., 2009, 19(3):438-447 doi: 10.1002/adfm.v19:3
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