Citation: YUAN Hui-Ping, JIANG Li-Jun. Effect of Surface Treatment with Different Alkaline Solutions on Rare Earth-Magnesium-Nickel Based Hydrogen Storage Alloy[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(12): 2271-2279. doi: 10.11862/CJIC.2018.259 shu

Effect of Surface Treatment with Different Alkaline Solutions on Rare Earth-Magnesium-Nickel Based Hydrogen Storage Alloy

YUAN Hui-Ping ^, ,
JIANG Li-Jun

GRIMAT Engineering Institute Co., Ltd., Beijing 101407, China

Corresponding author: YUAN Hui-Ping, huiping.yuan1@gmail.com
Received Date: 27 July 2018
Revised Date: 5 September 2018

Figures(6)

The rare earth-Mg-Ni (RE-Mg-Ni) based hydrogen storage alloy was treated in the same concentration of 6 mol·L^-1 LiOH, NaOH, and KOH aqueous solutions. The effects of different alkaline solutions and the treating times on the morphologies and compositions of the alloy surfaces and the electrochemical characters of the alloy electrodes have been investigated. The alloy electrode treated in 6 mol·L^-1 NaOH for 10 min shows the best electrochemical properties. LiOH solution could remove Mg element and diminish the oxygen species on the alloy surface effectively. The alloy surface layer formed in LiOH solution was more unfavorable for H adsorption and desorption but had good resistance for further corrosion. The alloy electrode treated with 6 mol·L^-1 LiOH had the best cyclic durability. With the increase of the treating time, the reduction of the discharge capacity was the largest for the alloy electrode treated with 6 mol·L^-1 NaOH solution because of the dissolution of a large amount of rare earth (RE) and Al elements, and the loose surface layer containing mainly rare earth hydroxides.
- nickel metal hydride battery,
- hydrogen storage alloy,
- surface treatment,
- rare earth-magnesium-nickel based
1. [1]
  Iwase K, Terashita N, Mori K, et al. Int. J. Hydrogen Energy, 2016, 41:1074-1079 doi: 10.1016/j.ijhydene.2015.11.052
2. [2]
  Wu C, Zhang L, Liu J J, et al. J. Alloys Compd., 2017, 693:573-581 doi: 10.1016/j.jallcom.2016.09.206
3. [3]
  ZHANG Xin-Bo, ZHAO Min-Shou. Chem. J. Chinese. University, 2003, 24:1680-1682
4. [4]
  Liu Z P, Yang S Q, Li Y, et al. J. Rare Earths, 2015, 33:397-402 doi: 10.1016/S1002-0721(14)60432-4
5. [5]
  Zhang Y H, Zhang W, Yuan Z. Int. J. Hydrogen Energy, 2017, 42:14227-14245 doi: 10.1016/j.ijhydene.2017.04.198
6. [6]
  Zhang X B, Sun D Z, Yin W Y, et al. ChemPhysChem, 2005, 6:520-525 doi: 10.1002/(ISSN)1439-7641
7. [7]
  Zhang X B, Sun D Z, Yin W Y, et al. Electrochim. Acta, 2005, 50:1957-1964 doi: 10.1016/j.electacta.2004.09.016
8. [8]
  Zhou W H, Tang Z Y, Zhu D, et al. J. Alloys Compd., 2017, 692:364-374 doi: 10.1016/j.jallcom.2016.08.292
9. [9]
  Karwowska M, Jaron T, Fijalkowski K J, et al. J. Power Sources, 2014, 263:304-309 doi: 10.1016/j.jpowsour.2014.04.050
10. [10]
  Zhang P L, Wang X L, TU J P, et al. J. Rare Earths, 2009, 27:510-513 doi: 10.1016/S1002-0721(08)60279-3
11. [11]
  Chen W X, Tang Z Y, Guo H T, et al. J. Power Sources, 1998, 74:34-39 doi: 10.1016/S0378-7753(98)00007-X
12. [12]
  Chen W X. J. Power Sources, 2001, 92:102-107 doi: 10.1016/S0378-7753(00)00509-7
13. [13]
  Kim H K, Yang D C, Jang I S, et al. Int. J. Hydrogen Energy, 2009, 34:9570-9575 doi: 10.1016/j.ijhydene.2009.09.097
14. [14]
  Santos D M F, Sequeira C A C, Lobo R F M. Int. J. Hydrogen Energy, 2010, 35:9901-9909 doi: 10.1016/j.ijhydene.2009.11.015
15. [15]
  Zhou Y, Dag N. J. Alloys Compd., 2016, 664:59-64 doi: 10.1016/j.jallcom.2015.12.170
16. [16]
  Zhou N, Ma Y D, Ding Y, et al. Battery, 2013, 43:88-90
17. [17]
  Xiao L L, Wang Y J, Liu Y, et al. Int. J. Hydrogen Energy, 2008, 33:3925-3929 doi: 10.1016/j.ijhydene.2008.01.045
18. [18]
  ZENG Shu-Ping, LUO Yong-Chun, LI Xin-Yu, et al. Journal of the Chinese Society of Rare Earths, 2014, 32:701-709
19. [19]
  Young K, Huang B, Regmi R K, et al. J. Alloys Compd., 2010, 506:831-840 doi: 10.1016/j.jallcom.2010.07.086
20. [20]
  Young K, Chao B, Liu Y, et al. J. Alloys Compd., 2014, 606:97-104 doi: 10.1016/j.jallcom.2014.04.033
21. [21]
  Yuan H P, Yang K, Jiang L J, et al. Int. J. Hydrogen Energy, 2015, 40:4623-4629 doi: 10.1016/j.ijhydene.2015.01.167
22. [22]
  Su G, He Y H, Liu K Y. Int. J. Hydrogen Energy, 2012, 37:12384-12392 doi: 10.1016/j.ijhydene.2012.05.149
23. [23]
  Lin C H, Lin K M, Chou H T, et al. J. Alloys Compd., 2003, 358:281-287 doi: 10.1016/S0925-8388(03)00030-6
24. [24]
  Ikoma M, Komori K, Kaida S, et al. J. Alloys Compd., 1999, 284:92-98 doi: 10.1016/S0925-8388(98)00740-3
25. [25]
  Liu J J, Han S M, Li Y, et al. J. Alloys Compd., 2015, 619:778-787 doi: 10.1016/j.jallcom.2014.09.041
26. [26]
  Balogun M S, Wang Z M, Chen H X, et al. Int J. Hydrogen Energy, 2013, 38:10926-10931 doi: 10.1016/j.ijhydene.2013.02.139
27. [27]
  Liu Y F, Pan H G, Gao M X, et al. Int J. Hydrogen Energy, 2008, 33:124-133 doi: 10.1016/j.ijhydene.2007.09.016
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