Citation: LIU Ji-Wei, GUAN Shu-Xia, GU Chang-Sheng. Syntheses, Crystal Structures and Properties of Mn(Ⅱ) and Cu(Ⅱ) Complexes with 3, 3'-Thiodipropionic Acid Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(11): 2081-2087. doi: 10.11862/CJIC.2018.254 shu

Syntheses, Crystal Structures and Properties of Mn(Ⅱ) and Cu(Ⅱ) Complexes with 3, 3'-Thiodipropionic Acid Ligand

1.
College of Chemistry and Chemical Technology, Northeast Petroleum University, Heilongjiang Provincal Key Laboratory of Oil and Chemical Technology, Daqing, Heilongjiang 163318, China
2.
Department of Applied Chemistry, Guangdong Ocean University, Zhanjiang, Guangdong 524088, China

Corresponding author: LIU Ji-Wei, liujiwei0706@163.com
Received Date: 5 June 2018
Revised Date: 23 August 2018

Figures(9)

A Mn(Ⅱ) coordination polymer, {[Mn(DPA)(4, 4'-bipy)]·H₂O}_n (1) was prepared with 3, 3'-thiodipropionic acid (DPA), 4, 4'-bipyridine (4, 4'-bipy) and Mn(NO₃)₂·4H₂O by hydrothermal method, and a Cu(Ⅱ) coordination polymer, {[Cu(DPA)(bpp)(H₂O)]·H₂O}_n (2) was hydrothermal synthesized by using 3, 3'-thiodipropionic acid (DPA), 1, 3-bis(4-pyridyl)propane (bpp) and Cu(NO₃)₂·3H₂O. The coordination polymers were characterized by elemental analysis, thermal analysis, IR, XRD and X-ray single crystal diffraction. Complexes 1 and 2 have two-dimensional layer structures, Furthermore, there are hydrogen bonds and π-π stacking interactions contributing three-dimensional supramolecular structures of 1 and 2, respectively.
- 3, 3'-thiodipropionic acid,
- 1, 3-bis(4-pyridyl)propane,
- 4, 4'-bipyridine,
- crystal structure
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沈阳化工大学材料科学与工程学院沈阳 110142