Citation: YU You-Zhu, GUO Yu-Hua, NIU Yong-Sheng, WU Xian-Li, FANG Ya-Ting, ZHUANG Na-Jie, ZHANG Jun-Wei, LIANG Hao, WANG Fang. Syntheses, Crystal Structures and Luminescence Properties of Two La(Ⅲ) Complexes Assembled by 3, 5-Dinitrosalicylic Acid and 1, 10-Phenanthroline[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(11): 2108-2114. doi: 10.11862/CJIC.2018.248 shu

Syntheses, Crystal Structures and Luminescence Properties of Two La(Ⅲ) Complexes Assembled by 3, 5-Dinitrosalicylic Acid and 1, 10-Phenanthroline

1.
College of Chemistry and Environmental Engineering, Anyang Institute of Technology, Anyang, Henan 455000, China
2.
College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, China

Corresponding author: YU You-Zhu, 119yyz@163.com
Received Date: 19 July 2018
Revised Date: 13 August 2018

Figures(7)

Two new complexes based on 3, 5-dinitrosalicylic acid (H₂dns) and 1, 10-phenanthroline (phen), namely[La₂(dns)₂(Hdns)₂(phen)₄] (1) and[La₄(dns)₆(phen)₆] (2) have been synthesized and characterized by IR, elemental analyses, thermogravimetric analyses and X-ray diffraction technique. Single-crystal X-ray diffraction analyses revealed that two complexes all crystallize in the triclinic system and space group P1. For complexes 1, H₂dns ligands adopt tridentate and didentate coordination modes to link La(Ⅲ) ions into dinuclear structure. However H₂dns ligands adopt tridentate coordination mode to link La(Ⅲ) ions into tetranuclear structure. TG and fluorescence analysis show the thermal stability of 2 is higher than that of 1, and 1 and 2 have same maximum emission band of the fluorescence at 467 nm.
- La(Ⅲ) complexes,
- 3, 5-dinitrosalicylic acid,
- crystal structures,
- luminescent properties
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1.
沈阳化工大学材料科学与工程学院沈阳 110142