Citation: ZHANG Hai-Xia, HAN Wang-Kang, ZHANG Feng-Li, HE Wei, GE Fang-Yuan, WANG Ya-Qin, YAN Xiao-Dong, GU Zhi-Guo. Halide Triggered Spin State Switching of Iron(Ⅱ) Tetrahedral Cages[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(11): 2063-2072. doi: 10.11862/CJIC.2018.233 shu

Halide Triggered Spin State Switching of Iron(Ⅱ) Tetrahedral Cages

1.
Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi, Jiangsu 214122, China
2.
International Joint Research Center for Photoresponsive Molecules and Materials, School of Chemical and Material Engineering, Jiangnan University, Wuxi, Jiangsu 214122, China

Corresponding author: GU Zhi-Guo, zhiguogu@jiangnan.edu.cn
Received Date: 22 June 2018
Revised Date: 18 July 2018

Figures(6)

Three iron(Ⅱ) tetrahedral cages 1~3 with solid state spin-crossover properties were rational constructed.Single crystal X-ray diffraction analysis confirmed the edge-capped capsule, which were assembled from six imidazole Schiff-base ligands and four iron(Ⅱ) ions.The metal centers occupy the vertices and each linker situates at the edges of the tetrahedron.The inner cavities of these cages are surrounded by imidazole groups, while the periphery is decorated by substituted phenyl rings.One of the counter anions is encapsulated at the central cavities and shows strong anion binding interactions with the cages.Interestingly, the iron(Ⅱ) cages in solution can change their spin states from low-spin (LS) to high-spin (HS) upon addition of halide, since tremendous change of solution color and absorption intensity of characteristic broad absorption MLCT bands when addition of halide (Cl^- and Br^-) to the CH₃CN solution of the cages.
- metal-organic cage,
- spin-crossover,
- halide,
- host-guest,
- spin state switching
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