Citation: YU Ji, WEI Hai-Yan, Li LI, YANG Zhen-Yu, CAI Jian-Xin. Preparation and Lithium Storage Properties of Grid-like SnO₂ Fibers[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(10): 1792-1798. doi: 10.11862/CJIC.2018.232 shu

Preparation and Lithium Storage Properties of Grid-like SnO₂ Fibers

College of Chemistry, Nanchang University, Nanchang 330031, China

Corresponding author: YU Ji, yuji@ncu.edu.cn
Received Date: 16 April 2018
Revised Date: 19 July 2018

Figures(6)

SnO₂ fibers and SnO₂-C fibers were synthesized through electrospun technology and calcined under air or Ar atmosphere. Samples were characterized by different methods. The results showed that SnO₂ fibers and SnO₂-C fibers have a grid-like structure, which can effectively alleviate the disadvantages caused by the huge volume change of SnO₂ during charging-discharging process. SnO₂-C fibers showed a better electrochemical performance than SnO₂ nanoparticles, but worse than that of SnO₂ fibers. SnO₂ fibers could discharged a much high capacity and had a good rate performance and long cycle life at the same time. After working at the current density of 0.4, 0.8, 1.6, 2.4 A·g^-1 and 4 A·g^-1 for 10 cycles, SnO₂ fibers could still discharge a capacity of 1 372, 832, 685, 642 and 599 mAh·g^-1. And when the current density went back to 0.4 A·g^-1, its capacity could arrive 1 113 mAh·g^-1 again. Furthermore, the SnO₂ fibers could also release a high discharge capacity of 613 mAh·g^-1 and almost 100% coulomb efficiency after 200 cycles at the current density of 1.6 A·g^-1, showing an excellent electrochemistry performance.
- lithium-ion battery,
- SnO₂ fibers,
- SnO₂-C fibers,
- anode material,
- electrospinning
1. [1]
  Liu H, Liu B H, Li Z P. Solid State Ionics, 2016, 294:6-14 doi: 10.1016/j.ssi.2016.06.008
2. [2]
  Wang H K, Lu X, Jiri T, et al. Electrochim. Acta, 2016, 211:636-643 doi: 10.1016/j.electacta.2016.06.089
3. [3]
  Zhou H, Li Z Y, Qiu Y P, et al. J. Alloys Compd., 2016, 670:35-40 doi: 10.1016/j.jallcom.2016.02.032
4. [4]
  Ni J F, Li L, Lu J. ACS Energy Lett., 2018, 3(5):1137-1144 doi: 10.1021/acsenergylett.8b00312
5. [5]
  Ni J F, Bi X X, Jiang Y, et al. Nano Energy, 2017, 34:356-366 doi: 10.1016/j.nanoen.2017.02.041
6. [6]
  Li Z, Tan Y Y, Huang X X, et al. Ceram. Int., 2016, 42(16):18887-18893 doi: 10.1016/j.ceramint.2016.09.036
7. [7]
  Li J, Guo J Q, Zhang X, et al. Ionics, 2016, 22(12):2307-2313 doi: 10.1007/s11581-016-1764-4
8. [8]
  Chen S, Xin Y L, Zhou Y Y, et al. J. Mater. Chem. A, 2014, 2(37):15582-15589 doi: 10.1039/C4TA03218G
9. [9]
  Yang Y, Ren S Z, Song X D, et al. Electrochim. Acta, 2016, 209:350-359 doi: 10.1016/j.electacta.2016.05.105
10. [10]
  Yuan J J, Chen C H, Hao Y, et al. J. Alloys Compd., 2017, 691:34-39 doi: 10.1016/j.jallcom.2016.08.229
11. [11]
  Wang C, Du G H, Kenny S, et al. J. Phys. Chem. C, 2012, 116(6):4000-4011 doi: 10.1021/jp300136p
12. [12]
  Ding S J, Luan D, Boey F Y C, et al. Chem. Commun., 2011, 47(25):7155-7157 doi: 10.1039/c1cc11968k
13. [13]
  Mao R, Guo H, Tian D X, et al. Mater. Res. Bull., 2013, 48(4):1518-1522 doi: 10.1016/j.materresbull.2012.12.056
14. [14]
  Guo H, Mao R, Yang X J, et al. J. Power Sources, 2012, 219:280-284 doi: 10.1016/j.jpowsour.2012.07.063
15. [15]
  Qu J, Yang Y A, Shi X M, et al. J. Alloys Compd., 2016, 686:122-129 doi: 10.1016/j.jallcom.2016.06.007
16. [16]
  Ma L A, Wei Z H, Guo T L. J. Mater. Sci.-Mater. Electron., 2016, 27(9):9044-9051 doi: 10.1007/s10854-016-4937-z
17. [17]
  Liu Y, Palmieri A, He J K, et al. Sci. Rep., 2016, 6:25860-25867 doi: 10.1038/srep25860
18. [18]
  Luo L, Xu W Z, Xia Z K, et al. Ceram. Int., 2016, 42(9):10826-10832 doi: 10.1016/j.ceramint.2016.03.211
19. [19]
  Cheng S, Shen D Z, Zhu X S, et al. Eur. Polym. J., 2009, 45(10):2767-2778 doi: 10.1016/j.eurpolymj.2009.06.021
20. [20]
  Dirican M, Yanilmaz M, Fu K, et al. J. Power Sources, 2014, 264:240-247 doi: 10.1016/j.jpowsour.2014.04.102
21. [21]
  Song H C, Wang H X, Lin Z X, et al. Nano Energy, 2016, 19:511-521 doi: 10.1016/j.nanoen.2015.10.031
22. [22]
  Cai M Y, Sun X G, Chen W, et al. J. Mater. Sci., 2018, 53(1):749-758 doi: 10.1007/s10853-017-1524-5
23. [23]
  Koo B R, Oh S T, Ahn H J. Mater. Lett., 2016, 178:288-291 doi: 10.1016/j.matlet.2016.05.016
24. [24]
  Liu D D, Kong Z, Liu X H, et al. ACS Appl. Mater. Interfaces, 2018, 10(3):2515-2525 doi: 10.1021/acsami.7b15916
25. [25]
  Guo H, Mao R, Yang X J, et al. J. Power Sources, 2012, 219:280-284 doi: 10.1016/j.jpowsour.2012.07.063
26. [26]
  Chen J S, Lou X W D. Small, 2013, 9(11):1877-1893 doi: 10.1002/smll.v9.11
27. [27]
  JI Wen-Xu, WU Di, YANG Rong, et al.Chinese J. Inorg. Chem., 2015, 31(4):659-665
28. [28]
  PENG Peng, WEN Zhao-Yin, LIU Yu, et al. Chinese J. Inorg. Chem., 2014, 30(6):1293-1298
29. [29]
  Ni J, Zhang L, Fu S, et al. Carbon, 2015, 92:15-25 doi: 10.1016/j.carbon.2015.02.047
30. [30]
  LI Jian, CUI Yong-Fu, CUI Jin-Long, et al. Chinese J. Inorg. Chem., 2018, 34(1):33-42
1. [1]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
2. [2]
  Xueyu Lin , Ruiqi Wang , Wujie Dong , Fuqiang Huang . 高性能双金属氧化物负极的理性设计及储锂特性. Acta Physico-Chimica Sinica, 2025, 41(3): 2311005-. doi: 10.3866/PKU.WHXB202311005
3. [3]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
4. [4]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
5. [5]
  Yifeng Xu , Jiquan Liu , Bin Cui , Yan Li , Gang Xie , Ying Yang . “Xiao Li’s School Adventures: The Working Principles and Safety Risks of Lithium-ion Batteries”. University Chemistry, 2024, 39(9): 259-265. doi: 10.12461/PKU.DXHX202404009
6. [6]
  Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, 2024, 40(10): 2309028-. doi: 10.3866/PKU.WHXB202309028
7. [7]
  Aoyu Huang , Jun Xu , Yu Huang , Gui Chu , Mao Wang , Lili Wang , Yongqi Sun , Zhen Jiang , Xiaobo Zhu . Tailoring Electrode-Electrolyte Interfaces via a Simple Slurry Additive for Stable High-Voltage Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100037-. doi: 10.3866/PKU.WHXB202408007
8. [8]
  Yuting ZHANG , Zunyi LIU , Ning LI , Dongqiang ZHANG , Shiling ZHAO , Yu ZHAO . Nickel vanadate anode material with high specific surface area through improved co-precipitation method: Preparation and electrochemical properties. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2163-2174. doi: 10.11862/CJIC.20240204
9. [9]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
10. [10]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
11. [11]
  Zhuo WANG , Xiaotong LI , Zhipeng HU , Junqiao PAN . Three-dimensional porous carbon decorated with nano bismuth particles: Preparation and sodium storage properties. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 267-274. doi: 10.11862/CJIC.20240223
12. [12]
  Bowen Yang , Rui Wang , Benjian Xin , Lili Liu , Zhiqiang Niu . C-SnO₂/MWCNTs Composite with Stable Conductive Network for Lithium-based Semi-Solid Flow Batteries. Acta Physico-Chimica Sinica, 2025, 41(2): 100015-. doi: 10.3866/PKU.WHXB202310024
13. [13]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
14. [14]
  Jiaxuan Zuo , Kun Zhang , Jing Wang , Xifei Li . 锂离子电池Ni-Co-Mn基正极材料前驱体的形核调控及机制. Acta Physico-Chimica Sinica, 2025, 41(1): 2404042-. doi: 10.3866/PKU.WHXB202404042
15. [15]
  Zhenming Xu , Mingbo Zheng , Zhenhui Liu , Duo Chen , Qingsheng Liu . Experimental Design of Project-Driven Teaching in Computational Materials Science: First-Principles Calculations of the LiFePO₄ Cathode Material for Lithium-Ion Batteries. University Chemistry, 2024, 39(4): 140-148. doi: 10.3866/PKU.DXHX202307022
16. [16]
  Hengyi ZHU , Liyun JU , Haoyue ZHANG , Jiaxin DU , Yutong XIE , Li SONG , Yachao JIN , Mingdao ZHANG . Efficient regeneration of waste LiNi_0.5Co_0.2Mn_0.3O₂ cathode toward high-performance Li-ion battery. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 625-638. doi: 10.11862/CJIC.20240358
17. [17]
  Yuejiao An , Wenxuan Liu , Yanfeng Zhang , Jianjun Zhang , Zhansheng Lu . Revealing Photoinduced Charge Transfer Mechanism of SnO₂/BiOBr S-Scheme Heterostructure for CO₂ Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(12): 2407021-. doi: 10.3866/PKU.WHXB202407021
18. [18]
  Xingang Kong , Yabei Su , Cuijuan Xing , Weijie Cheng , Jianfeng Huang , Lifeng Zhang , Haibo Ouyang , Qi Feng . Facile synthesis of porous TiO₂/SnO₂ nanocomposite as lithium ion battery anode with enhanced cycling stability via nanoconfinement effect. Chinese Chemical Letters, 2024, 35(11): 109428-. doi: 10.1016/j.cclet.2023.109428
19. [19]
  Yu Guo , Zhiwei Huang , Yuqing Hu , Junzhe Li , Jie Xu . 钠离子电池中铁基异质结构负极材料的最新研究进展. Acta Physico-Chimica Sinica, 2025, 41(3): 2311015-. doi: 10.3866/PKU.WHXB202311015
20. [20]
  Yifen He , Chao Qu , Na Ren , Dawei Liang . Enhanced degradation of refractory organics in ORR-EO system with a blue TiO₂ nanotube array modified Ti-based Ni-Sb co-doped SnO₂ anode. Chinese Chemical Letters, 2024, 35(8): 109262-. doi: 10.1016/j.cclet.2023.109262

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(378)
HTML views(58)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Lithium Storage Properties of Grid-like SnO2 Fibers

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation and Lithium Storage Properties of Grid-like SnO₂ Fibers