Citation: PU Ying-Hui, DU Dong-Feng, YU Shi-Fan, XING Wei. Synthesis and Supercapacitor Performance of Conductive Polymer@Nickel and Aluminum Double Metal Hydroxide Composites[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(11): 1983-1990. doi: 10.11862/CJIC.2018.224 shu

Synthesis and Supercapacitor Performance of Conductive Polymer@Nickel and Aluminum Double Metal Hydroxide Composites

College of Science, China University of Petroleum(East China), Qingdao, Shandong 266580, China

Corresponding author: DU Dong-Feng, dudongfeng0512@126.com XING Wei, xingwei@upc.edu.cn
Received Date: 13 June 2018
Revised Date: 2 August 2018

Figures(11)

The composite materials of conductive polymer@nickel and aluminum double metal hydroxide were prepared using the simple and mild hydrothermal conditions, constructing the nano-channels for high-speed transmission of electrons and electrolyte. The morphologies and microstructures of the composites were characterized by scanning electron microscope (SEM) and X-ray diffraction (XRD). The results of electrochemical performance showed that the conductive polymer could provide some pseudocapacitance for the composite material, promote the rapid transfer of charge, and improve significantly the capacitive performance of CP@NiAl-LDH. The polypyrrole@LDH had the best performance of capacitance, the specific capacity could reach 3 010.3 F·g^-1 at the current density of 1 A·g^-1, and the specific capacitance remained 73.1% when the current density increased to 20 A·g^-1, exhibiting excellent rate performance. Furthermore, it also displayed excellent cycling stability with a specific capacity retention rate of 88.8% after 10 000 times of charge-discharge cycles at the current density of 10 A·g^-1. These were mainly ascribed to the synergetic enhancement effect among NiAl-LDH and conductive polymer.
- hybrid materials,
- conductive polymer,
- layered double hydroxide,
- supercapacitor
1. [1]
  Shao Y L, Elkady M F, Wang L J, et al. Chem. Soc. Rev., 2015, 44(11):3639-3665 doi: 10.1039/C4CS00316K
2. [2]
  Wang G P, Zhang L, Zhang J J. Cheminform, 2012, 41(2):797-828
3. [3]
  Chiam S L, Lim H N, Hafiz S M, et al. Sci. Rep., 2018, 8(1):3093-3099 doi: 10.1038/s41598-018-21572-x
4. [4]
  Yu Z N, Tetard L, Zhai L, et al. Energy Environ. Sci., 2105, 8(3):702-730
5. [5]
  Huang M, Li F, Dong F, et al. J. Mater. Chem. A, 2015, 3(43):21380-21423 doi: 10.1039/C5TA05523G
6. [6]
  KANG Gui-Ying, CHEN Yong, LI Juan-Juan, et al. J. Inorg. Mater., 2016, 31(11):1230-1236
7. [7]
  Meng W, Chen W, Zhao L, et al. Nano Energy, 2014, 8(9):133-140
8. [8]
  Li L, Peng S, Chen H Y, et al. Nano Energy, 2016, 19:307-317 doi: 10.1016/j.nanoen.2015.11.026
9. [9]
  Wang F F, Wang T, Sun S G, et al. Sci. Rep., 2018, 8(1):8908-8917 doi: 10.1038/s41598-018-27171-0
10. [10]
  WANG Hai-Yan, SHI Gao-Quan. Acta Phys.-Chim Sin., 2018(1):22-35
11. [11]
  Wimalasiri Y, Fan R, Zhao X S, et al. Electrochim. Acta, 2014, 134(21):127-135
12. [12]
  Snook G A, Kao P, Best A S. J. Power Sources, 2011, 196(1):1-12 doi: 10.1016/j.jpowsour.2010.06.084
13. [13]
  Tang H, Wang J, Yin H, et al. Adv. Mater., 2015, 27(6):1117-1123 doi: 10.1002/adma.201404622
14. [14]
15. [15]
  Ma K Y, Cheng J P, Liu F, et al. J. Alloys Compd., 2016, 679:277-284 doi: 10.1016/j.jallcom.2016.04.059
16. [16]
  Warsi M F, Shakir I., Shahid M, et al. Electrochim. Acta, 2014, 135(22):513-518
17. [17]
  DUAN Hong-Zhen, CHENG Xia, LUO Ming-Yu, et al. Chinese J. Inorg. Chem., 2017, 33(12):2208-2214 doi: 10.11862/CJIC.2017.267
18. [18]
  Yuan C Z, Gao B, Shen L F, et al. Nanoscale, 2011, 3(2):529-545
19. [19]
  Mai L Q, Minhas-khan A, Tian X C, et al. Nat. Commun., 2013, 4(1):2923-2929 doi: 10.1038/ncomms3923
20. [20]
  Li M, Cheng J P, Fang J H, et al. Electrochim. Acta, 2014, 134(21):309-318
21. [21]
  YANG Jin-Lin, LIN Jin-Xin, GUO Shao-Yi. Chinese J. Inorg. Chem., 2017, 33(2):255-261
22. [22]
  Wang H L, Robonson J T, Diankov G. J. Am. Chem. Soc., 2010, 132(10):3270-3271 doi: 10.1021/ja100329d
23. [23]
  Liu X X, Zhou A W, Pan T, et al. J. Mater. Chem. A, 2016, 4(21):8421-8427 doi: 10.1039/C6TA02164F
24. [24]
  Li X C, Shen J J, Sun W, et al. J. Mater. Chem. A, 2015, 3(25):13244-13253 doi: 10.1039/C5TA01292A
25. [25]
  Du D F, Wu X Z, Li S, et al. J. Mater. Chem. A, 2017, 5(19):8964-8971 doi: 10.1039/C7TA00624A
1. [1]
  Huayan Liu , Yifei Chen , Mengzhao Yang , Jiajun Gu . Strategies for enhancing capacity and rate performance of two-dimensional material-based supercapacitors. Acta Physico-Chimica Sinica, 2025, 41(6): 100063-. doi: 10.1016/j.actphy.2025.100063
2. [2]
  Yihan Xue , Xue Han , Jie Zhang , Xiaoru Wen . NCQDs修饰FeOOH基复合材料的制备及其电容脱盐性能. Acta Physico-Chimica Sinica, 2025, 41(7): 100072-. doi: 10.1016/j.actphy.2025.100072
3. [3]
  Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404
4. [4]
  Xiangyu CAO , Jiaying ZHANG , Yun FENG , Linkun SHEN , Xiuling ZHANG , Juanzhi YAN . Synthesis and electrochemical properties of bimetallic-doped porous carbon cathode material. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 509-520. doi: 10.11862/CJIC.20240270
5. [5]
  Yanhui XUE , Shaofei CHAO , Man XU , Qiong WU , Fufa WU , Sufyan Javed Muhammad . Construction of high energy density hexagonal hole MXene aqueous supercapacitor by vacancy defect control strategy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1640-1652. doi: 10.11862/CJIC.20240183
6. [6]
  Jin CHANG . Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)₂. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1697-1707. doi: 10.11862/CJIC.20240108
7. [7]
  Yaping ZHANG , Tongchen WU , Yun ZHENG , Bizhou LIN . Z-scheme heterojunction β-Bi₂O₃ pillared CoAl layered double hydroxide nanohybrid: Fabrication and photocatalytic degradation property. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 531-539. doi: 10.11862/CJIC.20240256
8. [8]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
9. [9]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
10. [10]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
11. [11]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
12. [12]
  Qiqi Li , Su Zhang , Yuting Jiang , Linna Zhu , Nannan Guo , Jing Zhang , Yutong Li , Tong Wei , Zhuangjun Fan . 前驱体机械压实制备高密度活性炭及其致密电容储能性能. Acta Physico-Chimica Sinica, 2025, 41(3): 2406009-. doi: 10.3866/PKU.WHXB202406009
13. [13]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
14. [14]
  Guanghui SUI , Yanyan CHENG . Application of rice husk-based activated carbon-loaded MgO composite for symmetric supercapacitors. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 521-530. doi: 10.11862/CJIC.20240221
15. [15]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
16. [16]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
17. [17]
  Jiatong Hu , Qiyi Wang , Ruiwen Tang , Jiajing Feng . Photocatalytic Journey of Perylene Diimides in a Competitive Arena. University Chemistry, 2025, 40(5): 328-333. doi: 10.12461/PKU.DXHX202407015
18. [18]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170
19. [19]
  Kuaibing Wang , Honglin Zhang , Wenjie Lu , Weihua Zhang . Experimental Design and Practice for Recycling and Nickel Content Detection from Waste Nickel-Metal Hydride Batteries. University Chemistry, 2024, 39(11): 335-341. doi: 10.12461/PKU.DXHX202403084
20. [20]
  Huirong BAO , Jun YANG , Xiaomiao FENG . Preparation and electrochemical properties of NiCoP/polypyrrole/carbon cloth by electrodeposition. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1083-1093. doi: 10.11862/CJIC.20250008

Get Citation

PDF

XML

Metrics

PDF Downloads(11)
Abstract views(1955)
HTML views(377)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142