Citation: ZHAO Hong-Kun, DING Bo, WANG Xiu-Guang, JIA Fang, YANG En-Cui, ZHAO Xiao-Jun. Crystal Structures and Fluorescence Properties of Cu(Ⅱ)/Ni(Ⅱ) Complexes with 4-(1, 2, 4-Triazol-1-yl)phenol Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(9): 1739-1746. doi: 10.11862/CJIC.2018.219 shu

Crystal Structures and Fluorescence Properties of Cu(Ⅱ)/Ni(Ⅱ) Complexes with 4-(1, 2, 4-Triazol-1-yl)phenol Ligand

College of Chemistry, Key Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry, Ministry of Education, Tianjin Key Laboratory of Structure and Performance for Functional Molecules, Tianjin Normal University, Tianjin 300387, China

Corresponding author: YANG En-Cui, encui_yang@163.com ZHAO Xiao-Jun, xiaojun_zhao15@163.com
Received Date: 1 May 2018
Revised Date: 22 June 2018

Figures(4)

Two 4-(1, 2, 4-triazol-1-yl)phenol (hptrz)-based transition metal complexes, {[Ni(H₂O)₂(hptrz)₂(tp)]·2DMF}_n (1) and[Cu(hptrz)₂(SCN)₂]·2H₂O (2) (H₂tp=terephthalic acid), have been prepared and characterized by single-crystal and powder X-ray diffractions, elemental analysis, FT-IR spectra, thermogravimertric and luminescence spectra. X-ray diffraction analysis revealed that 1 is a one-dimensional linear chain with octahedral Ni(Ⅱ) ions extended by bis-unidentate tp^2- anions; whereas 2 exhibits a centrosymmetric mononuclear entity. The neutral hptrz ligand in the both complexes serves as terminal ligands to complete the metal coordination sphere and to help to assemble the low-dimensional aggregates into a high-dimensional supramolecular architecture by O-H…O hydrogen-bonding interactions. Additionally, the complexes display strong emissions in UV region originated from intraligand electronic transfer.
- 4-(1, 2, 4-triazol-1-yl)phenol,
- Cu(Ⅱ)/Ni(Ⅱ) complexes,
- crystal structure,
- luminescent property
1. [1]
  Rojas S, Carmona F J, Maldonado C R, et al. Inorg. Chem., 2016, 55:2650-2663 doi: 10.1021/acs.inorgchem.6b00045
2. [2]
  He H M, Sun F X, Ma S Q, et al. Inorg. Chem., 2016, 55:9071-9076 doi: 10.1021/acs.inorgchem.6b01592
3. [3]
  WU Xiao-Shuo, WANG Peng-Fei, LU Peng -Peng, et al. Chinese J. Inorg. Chem., 2016, 32(9):1667-1675
4. [4]
  ZHANG Mei-Na, ZHENG Xiao-Li, QU Xiang-Long, et al. Chinese J. Inorg. Chem., 2017, 33(7):1172-1180
5. [5]
  Bloch E D, Murray L J, Queen W L, et al. J. Am. Chem. Soc., 2011, 133:14814-14822 doi: 10.1021/ja205976v
6. [6]
  WANG Li, KANG Quan-Peng, HAO Jing, et al. Chinese J. Inorg. Chem., 2018, 34(3):525-533
7. [7]
  CHEN Jin-Wei, WEN Bing-Song, CAO Fang-Li, et al. Chinese J. Inorg. Chem., 2017, 33(12):2322-2328 doi: 10.11862/CJIC.2017.229
8. [8]
  Ding B, Yi L, Gao H L, et al. Inorg. Chem. Commun., 2005, 8:102-104 doi: 10.1016/j.inoche.2004.11.015
9. [9]
  Zhang J P, Chen X M. Chem. Commun., 2006, 16:1689-1699
10. [10]
  Zhai Q G, Lu C Z, Wu X Y, et al. Cryst. Growth Des., 2007, 7:2332-2342 doi: 10.1021/cg070593q
11. [11]
  Ouellette W, Hudson B S, Zubieta J. Inorg. Chem., 2007, 46:4887-4904 doi: 10.1021/ic062269a
12. [12]
  Haasnoot J G. Coord. Chem. Rev., 2000, 200-202:131-185 doi: 10.1016/S0010-8545(00)00266-6
13. [13]
  Klingale M H, Brooker S. Coord. Chem. Rev., 2003, 241:119-132 doi: 10.1016/S0010-8545(03)00049-3
14. [14]
  Beckman U, Brooker S. Coord. Chem. Rev., 2003, 245:17-19 doi: 10.1016/S0010-8545(03)00030-4
15. [15]
  Abramovitch R A, Beckert J M, Gibson H H, et al. J. Org. Chem., 2001, 66:1242-1251 doi: 10.1021/jo001382u
16. [16]
  Lavrenova L G, Ikorskii V N, Sheludyakova L A, et al. Russ. J. Coord. Chem., 2004, 30:413-418 doi: 10.1023/B:RUCO.0000030162.64191.66
17. [17]
  (a) Engelfriet D W, Verschoor G C, Den Brinker W. Acta Crystallogr. Sect. B: Struct. Sci., 1980, B35: 1554-1560
  (b)Yi L, Du J Y, Liu S, et al. J. Chem. Res., 2004, 1: 29-31
18. [18]
  Yang E C, Liu Z Y, Wang X G, et al. CrystEngComm, 2008, 10:1140-1143 doi: 10.1039/b804944k
19. [19]
  (a) Liu Z Y, Wang X G, Yang E C, et al. Z. Anorg. Allg. Chem., 2008, 634: 1807-1811
  (b)Yang E C, Liang Q Q, Wang X G, et al. Aust. J. Chem., 2008, 61: 813-820
20. [20]
  Yang E C, Jia F, Wang X G, et al. Bull. Korean Chem. Soc., 2008, 29:2195-2201 doi: 10.5012/bkcs.2008.29.11.2195
21. [21]
  (a) Feng W, Chang R N, Wang J Y, et al. J. Coord. Chem., 2010, 63: 250-262
  (b)Yang E C, Feng W, Wang J Y, et al. Inorg. Chim. Acta, 2010, 363: 308-316
  (c)Yang E C, Liu T Y, Wang Q, et al. Inorg. Chem. Commun., 2011, 14: 285-287
  (d)Yang E C, Yang Y L, Liu Z Y, et al. CrystEngComm, 2011, 13: 2667-2673
  (e)Jia F, Li J, Wang X G, et al. Acta Crystallogr. Sect. E: Struct. Rep. Online, 2007, E63: m31-m33
22. [22]
  SAINT Software Reference Manual, Bruker AXS, Madison, WI, 1998.
23. [23]
  Sheldrick G M. SADABS: Program for Empirical Absorption Correction of Area Detector Data, University of Göttingen, Germany, 1996.
24. [24]
  Sheldrick, G M. Acta Crystallogr. Sect. C:Cryst. Struct. Commun., 2015, C71:3-8
25. [25]
  Zhang H, Wang X M, Zhang K C, et al. Coord. Chem. Rev., 1999, 183:157-195 doi: 10.1016/S0010-8545(98)00270-7
26. [26]
  Deacon G B, Phillips R J. Coord. Chem. Rev., 1980, 33:227-250 doi: 10.1016/S0010-8545(00)80455-5
27. [27]
  Groeneveld L R, Vos G, Verschoor G C, et al. J. Chem. Soc. Chem. Commun., 1982:620-621
1. [1]
  Chao LIU , Jiang WU , Zhaolei JIN . Synthesis, crystal structures, and antibacterial activities of two zinc(Ⅱ) complexes bearing 5-phenyl-1H-pyrazole group. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1986-1994. doi: 10.11862/CJIC.20240153
2. [2]
  Gaofeng WANG , Shuwen SUN , Yanfei ZHAO , Lixin MENG , Bohui WEI . Structural diversity and luminescence properties of three zinc coordination polymers based on bis(4-(1H-imidazol-1-yl)phenyl)methanone. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 849-856. doi: 10.11862/CJIC.20230479
3. [3]
  Yao HUANG , Yingshu WU , Zhichun BAO , Yue HUANG , Shangfeng TANG , Ruixue LIU , Yancheng LIU , Hong LIANG . Copper complexes of anthrahydrazone bearing pyridyl side chain: Synthesis, crystal structure, anticancer activity, and DNA binding. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 213-224. doi: 10.11862/CJIC.20240359
4. [4]
  Jia JI , Zhaoyang GUO , Wenni LEI , Jiawei ZHENG , Haorong QIN , Jiahong YAN , Yinling HOU , Xiaoyan XIN , Wenmin WANG . Two dinuclear Gd(Ⅲ)-based complexes constructed by a multidentate diacylhydrazone ligand: Crystal structure, magnetocaloric effect, and biological activity. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 761-772. doi: 10.11862/CJIC.20240344
5. [5]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
6. [6]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
7. [7]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
8. [8]
  Xiaoling WANG , Hongwu ZHANG , Daofu LIU . Synthesis, structure, and magnetic property of a cobalt(Ⅱ) complex based on pyridyl-substituted imino nitroxide radical. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 407-412. doi: 10.11862/CJIC.20240214
9. [9]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
10. [10]
  Yinling HOU , Jia JI , Hong YU , Xiaoyun BIAN , Xiaofen GUAN , Jing QIU , Shuyi REN , Ming FANG . A rhombic Dy₄-based complex showing remarkable single-molecule magnet behavior. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 605-612. doi: 10.11862/CJIC.20240251
11. [11]
  Lulu DONG , Jie LIU , Hua YANG , Yupei FU , Hongli LIU , Xiaoli CHEN , Huali CUI , Lin LIU , Jijiang WANG . Synthesis, crystal structure, and fluorescence properties of Cd-based complex with pcu topology. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 809-820. doi: 10.11862/CJIC.20240171
12. [12]
  Xiumei LI , Linlin LI , Bo LIU , Yaru PAN . Syntheses, crystal structures, and characterizations of two cadmium(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 613-623. doi: 10.11862/CJIC.20240273
13. [13]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
14. [14]
  Yan XU , Suzhi LI , Yan LI , Lushun FENG , Wentao SUN , Xinxing LI . Structure variation of cadmium naphthalene-diphosphonates with the changing rigidity of N-donor auxiliary ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 395-406. doi: 10.11862/CJIC.20240226
15. [15]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
16. [16]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
17. [17]
  Shuyan ZHAO . Field-induced Co^Ⅱ single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231
18. [18]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079
19. [19]
  Zhijia Zhang , Shihao Sun , Yuefang Chen , Yanhao Wei , Mengmeng Zhang , Chunsheng Li , Yan Sun , Shaofei Zhang , Yong Jiang . Epitaxial growth of Cu_2-xSe on Cu (220) crystal plane as high property anode for sodium storage. Chinese Chemical Letters, 2024, 35(7): 108922-. doi: 10.1016/j.cclet.2023.108922
20. [20]
  Haiming Wu , Gaya N. Andrew , Rajini Anumula , Zhixun Luo . Corrigendum to 'How ligand coordination and superatomic-states accommodate the structure and property of a metal cluster: Cu₄ (dppy)₄ Cl₂ vs. Cu₂₁ (dppy)₁₀ with altered photoluminescence' [Chin. Chem. Lett. 35 (2024) 108340]. Chinese Chemical Letters, 2024, 35(12): 109912-. doi: 10.1016/j.cclet.2024.109912

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(1654)
HTML views(108)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142