Citation: ZHAO Hong-Kun, DING Bo, WANG Xiu-Guang, JIA Fang, YANG En-Cui, ZHAO Xiao-Jun. Crystal Structures and Fluorescence Properties of Cu(Ⅱ)/Ni(Ⅱ) Complexes with 4-(1, 2, 4-Triazol-1-yl)phenol Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(9): 1739-1746. doi: 10.11862/CJIC.2018.219 shu

Crystal Structures and Fluorescence Properties of Cu(Ⅱ)/Ni(Ⅱ) Complexes with 4-(1, 2, 4-Triazol-1-yl)phenol Ligand

College of Chemistry, Key Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry, Ministry of Education, Tianjin Key Laboratory of Structure and Performance for Functional Molecules, Tianjin Normal University, Tianjin 300387, China

Corresponding author: YANG En-Cui, encui_yang@163.com ZHAO Xiao-Jun, xiaojun_zhao15@163.com
Received Date: 1 May 2018
Revised Date: 22 June 2018

Figures(4)

Two 4-(1, 2, 4-triazol-1-yl)phenol (hptrz)-based transition metal complexes, {[Ni(H₂O)₂(hptrz)₂(tp)]·2DMF}_n (1) and[Cu(hptrz)₂(SCN)₂]·2H₂O (2) (H₂tp=terephthalic acid), have been prepared and characterized by single-crystal and powder X-ray diffractions, elemental analysis, FT-IR spectra, thermogravimertric and luminescence spectra. X-ray diffraction analysis revealed that 1 is a one-dimensional linear chain with octahedral Ni(Ⅱ) ions extended by bis-unidentate tp^2- anions; whereas 2 exhibits a centrosymmetric mononuclear entity. The neutral hptrz ligand in the both complexes serves as terminal ligands to complete the metal coordination sphere and to help to assemble the low-dimensional aggregates into a high-dimensional supramolecular architecture by O-H…O hydrogen-bonding interactions. Additionally, the complexes display strong emissions in UV region originated from intraligand electronic transfer.
- 4-(1, 2, 4-triazol-1-yl)phenol,
- Cu(Ⅱ)/Ni(Ⅱ) complexes,
- crystal structure,
- luminescent property
1. [1]
  Rojas S, Carmona F J, Maldonado C R, et al. Inorg. Chem., 2016, 55:2650-2663 doi: 10.1021/acs.inorgchem.6b00045
2. [2]
  He H M, Sun F X, Ma S Q, et al. Inorg. Chem., 2016, 55:9071-9076 doi: 10.1021/acs.inorgchem.6b01592
3. [3]
  WU Xiao-Shuo, WANG Peng-Fei, LU Peng -Peng, et al. Chinese J. Inorg. Chem., 2016, 32(9):1667-1675
4. [4]
  ZHANG Mei-Na, ZHENG Xiao-Li, QU Xiang-Long, et al. Chinese J. Inorg. Chem., 2017, 33(7):1172-1180
5. [5]
  Bloch E D, Murray L J, Queen W L, et al. J. Am. Chem. Soc., 2011, 133:14814-14822 doi: 10.1021/ja205976v
6. [6]
  WANG Li, KANG Quan-Peng, HAO Jing, et al. Chinese J. Inorg. Chem., 2018, 34(3):525-533
7. [7]
  CHEN Jin-Wei, WEN Bing-Song, CAO Fang-Li, et al. Chinese J. Inorg. Chem., 2017, 33(12):2322-2328 doi: 10.11862/CJIC.2017.229
8. [8]
  Ding B, Yi L, Gao H L, et al. Inorg. Chem. Commun., 2005, 8:102-104 doi: 10.1016/j.inoche.2004.11.015
9. [9]
  Zhang J P, Chen X M. Chem. Commun., 2006, 16:1689-1699
10. [10]
  Zhai Q G, Lu C Z, Wu X Y, et al. Cryst. Growth Des., 2007, 7:2332-2342 doi: 10.1021/cg070593q
11. [11]
  Ouellette W, Hudson B S, Zubieta J. Inorg. Chem., 2007, 46:4887-4904 doi: 10.1021/ic062269a
12. [12]
  Haasnoot J G. Coord. Chem. Rev., 2000, 200-202:131-185 doi: 10.1016/S0010-8545(00)00266-6
13. [13]
  Klingale M H, Brooker S. Coord. Chem. Rev., 2003, 241:119-132 doi: 10.1016/S0010-8545(03)00049-3
14. [14]
  Beckman U, Brooker S. Coord. Chem. Rev., 2003, 245:17-19 doi: 10.1016/S0010-8545(03)00030-4
15. [15]
  Abramovitch R A, Beckert J M, Gibson H H, et al. J. Org. Chem., 2001, 66:1242-1251 doi: 10.1021/jo001382u
16. [16]
  Lavrenova L G, Ikorskii V N, Sheludyakova L A, et al. Russ. J. Coord. Chem., 2004, 30:413-418 doi: 10.1023/B:RUCO.0000030162.64191.66
17. [17]
  (a) Engelfriet D W, Verschoor G C, Den Brinker W. Acta Crystallogr. Sect. B: Struct. Sci., 1980, B35: 1554-1560
  (b)Yi L, Du J Y, Liu S, et al. J. Chem. Res., 2004, 1: 29-31
18. [18]
  Yang E C, Liu Z Y, Wang X G, et al. CrystEngComm, 2008, 10:1140-1143 doi: 10.1039/b804944k
19. [19]
  (a) Liu Z Y, Wang X G, Yang E C, et al. Z. Anorg. Allg. Chem., 2008, 634: 1807-1811
  (b)Yang E C, Liang Q Q, Wang X G, et al. Aust. J. Chem., 2008, 61: 813-820
20. [20]
  Yang E C, Jia F, Wang X G, et al. Bull. Korean Chem. Soc., 2008, 29:2195-2201 doi: 10.5012/bkcs.2008.29.11.2195
21. [21]
  (a) Feng W, Chang R N, Wang J Y, et al. J. Coord. Chem., 2010, 63: 250-262
  (b)Yang E C, Feng W, Wang J Y, et al. Inorg. Chim. Acta, 2010, 363: 308-316
  (c)Yang E C, Liu T Y, Wang Q, et al. Inorg. Chem. Commun., 2011, 14: 285-287
  (d)Yang E C, Yang Y L, Liu Z Y, et al. CrystEngComm, 2011, 13: 2667-2673
  (e)Jia F, Li J, Wang X G, et al. Acta Crystallogr. Sect. E: Struct. Rep. Online, 2007, E63: m31-m33
22. [22]
  SAINT Software Reference Manual, Bruker AXS, Madison, WI, 1998.
23. [23]
  Sheldrick G M. SADABS: Program for Empirical Absorption Correction of Area Detector Data, University of Göttingen, Germany, 1996.
24. [24]
  Sheldrick, G M. Acta Crystallogr. Sect. C:Cryst. Struct. Commun., 2015, C71:3-8
25. [25]
  Zhang H, Wang X M, Zhang K C, et al. Coord. Chem. Rev., 1999, 183:157-195 doi: 10.1016/S0010-8545(98)00270-7
26. [26]
  Deacon G B, Phillips R J. Coord. Chem. Rev., 1980, 33:227-250 doi: 10.1016/S0010-8545(00)80455-5
27. [27]
  Groeneveld L R, Vos G, Verschoor G C, et al. J. Chem. Soc. Chem. Commun., 1982:620-621
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