Citation: ZHAO Hai-Yan, LI Na, YANG Xiao-Dong. Two Binuclear Cu(Ⅱ) Complexes of Reduced Schiff Base Ligand Containing Benzimidazole Ring:Syntheses, Structures and Electrochemical Properties[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(9): 1725-1732. doi: 10.11862/CJIC.2018.218 shu

Two Binuclear Cu(Ⅱ) Complexes of Reduced Schiff Base Ligand Containing Benzimidazole Ring:Syntheses, Structures and Electrochemical Properties

College of Science, Hebei University of Science and Technology, Shijiazhuang 050018, China

Corresponding author: ZHAO Hai-Yan, hbhaiyanzh@163.com
Received Date: 12 April 2018
Revised Date: 22 June 2018

Figures(5)

Two binuclear copper(Ⅱ) complexes of the reduced Schiff base, namely, HL=2-(((2-(2-benzimidazyl) ethyl)aimino)methyl)phenol (HL) have been synthesized and characterized by C, H and N microanalyses, spectroscopic (FT-IR, UV-Vis) as well as electrochemical techniques and single-crystal X-ray diffraction. The crystal structures of[CuL(CH₃OH)]₂(BF₄)₂ (1) and[CuL(NO₃)₂]₂ (2) show that the Cu(Ⅱ) atoms are bridged by two phenolato oxygen atoms in the dimers. The geometries around Cu(Ⅱ) atoms are distorted square pyramid with the Addison parameters (τ) of 0.31 and 0.35 for 1 and 2, respectively. Furthermore, the complex units in 1 and 2 are linked into 1D and 3D supramolecular networks by H-bonding in the solid state, respectively. The electrochemical studies of 1 and 2 show two quasi-reversible one electron reduction processes.
- binuclear copper complexes,
- reduced Schiff base ligand,
- crystal structure,
- redox properties
1. [1]
  Koohzad S, Golchoubian H, Jaglii Z. Inorg. Chim. Acta, 2018, 473:60-69 doi: 10.1016/j.ica.2017.12.026
2. [2]
  Chai D F, Wang M, Zhang C J, et al. Inorg. Chem. Commun., 2017, 83:16-19 doi: 10.1016/j.inoche.2017.05.028
3. [3]
  Pattanayak P, Pratihar J L, Patra D, et al. Polyhedron, 2013, 59:23-28 doi: 10.1016/j.poly.2013.04.034
4. [4]
  Hazra S, Karmakar A, da Silva M F C G, et al. Inorg. Chem. Commun., 2014, 46:113-117 doi: 10.1016/j.inoche.2014.05.025
5. [5]
  Chai L Q, Li Y X, Chen L C, et al. Inorg. Chim. Acta, 2016, 444:193-201 doi: 10.1016/j.ica.2016.01.038
6. [6]
  YANG Yong-Sheng, CHEN Bo-Yong, JU Hai-Yan, et al. Chinese J. Inorg. Chem., 2017, 33(12):2338-2344 doi: 10.11862/CJIC.2017.262
7. [7]
  LIN Long, LI Xian-Hong, ZHANG Bo, et al. Chinese J. Inorg. Chem., 2017, 33(1):143-148
8. [8]
  YANG Hong, GUO Li-Jun. Chinese J. Inorg. Chem., 2017, 33(6):1059-1064
9. [9]
  Ferreira B J M L, BrandO P, Meiriles M, et al. J. Inorg. Biochem., 2016, 161:9-17 doi: 10.1016/j.jinorgbio.2016.04.026
10. [10]
  Ghosh A K, Ali A, Singh Y, et al. Inorg. Chim. Acta, 2018, 474:156-163 doi: 10.1016/j.ica.2018.02.004
11. [11]
  Arthi P, Haleel A, Srinivasan P, et al. Spectrochim. Acta A, 2014, 129:400-414 doi: 10.1016/j.saa.2014.03.058
12. [12]
  You X L, Wei Z H. Inorg. Chim. Acta, 2014, 423:332-339 doi: 10.1016/j.ica.2014.08.051
13. [13]
  Sadhukhan D, Ray A, Butcher R J, et al. Inorg. Chim. Acta, 2011, 376:245-254 doi: 10.1016/j.ica.2011.06.024
14. [14]
  Biswas A, Drew M G B, Ribas J, et al. Inorg. Chim. Acta, 2011, 379:28-33 doi: 10.1016/j.ica.2011.09.026
15. [15]
  Biswas A, Drew M G B, Ghosh A. Polyhedron, 2010, 29:1029-1034 doi: 10.1016/j.poly.2009.12.006
16. [16]
  Cescon L A, Day A R. J. Org. Chem., 1962, 27:581-586 doi: 10.1021/jo01049a056
17. [17]
  Sheldrick G M. SADABS, Program for Empirical Absorption Correction of Area Detector Data, University of Göttingen, Germany, 1996.
18. [18]
  Sheldrick G M. SHELXL-97, Program for X-ray Crystal Structure Solution, Göttingen University, Germany, 1997.
19. [19]
  Maurya M R, Kumar A, Ebel M, et al. Inorg. Chem., 2006, 45:5924-5937 doi: 10.1021/ic0604922
20. [20]
  Nath M, Saini P K, Kumar A. Appl. Organometal. Chem., 2009, 23:434-445 doi: 10.1002/aoc.v23:11
21. [21]
  Zianna A, Psomas G, Hatzidimitriou A, et al. J. Inorg. Biochem., 2013, 127:116-126 doi: 10.1016/j.jinorgbio.2013.07.031
22. [22]
  Muppidi V K, Das M S, Raghavaiah P, et al. Inorg. Chem. Commun., 2007, 10:234-238 doi: 10.1016/j.inoche.2006.10.011
23. [23]
  Creaven B S, Devereux M, Karcz D, et al. J. Inorg. Biochem., 2009, 103:196-1203
24. [24]
  Bronisz R. Inorg. Chim. Acta, 2004, 357:396-404 doi: 10.1016/j.ica.2003.05.002
25. [25]
  Youngme S, van Albada G A, Chaichit N, et al. Inorg. Chim. Acta, 2003, 353:119-128 doi: 10.1016/S0020-1693(03)00207-X
26. [26]
  Keypour H, Shayesteh M, Rezaeivala M, et al. Spectrochim. Acta A, 2013, 101:59-66 doi: 10.1016/j.saa.2012.09.048
27. [27]
  Yang J, Ma J F, Liu Y C, et al. J. Mol. Struct., 2003, 646:55-60 doi: 10.1016/S0022-2860(02)00591-4
28. [28]
  McLachlan G A, Fallon G D, Martin R L, et al. Inorg. Chem., 1995, 34:254-261 doi: 10.1021/ic00105a041
29. [29]
  Gupta S, Pal S, Barik A K, et al. Polyhedron, 2008, 27:2519-2528 doi: 10.1016/j.poly.2008.05.009
30. [30]
  Sreenivasulu B, Zhao F, Gao S, et al. Eur. J. Inorg. Chem., 2006:2656-2670
31. [31]
  Amudha P, Akilan P, Kandaswam M. Polyhedron, 1999, 18:1355-1362 doi: 10.1016/S0277-5387(98)00401-X
32. [32]
  Thirumavalavan M, Akilan P, Amudha P, et al. Polyhedron, 2004, 23:519-527 doi: 10.1016/j.poly.2003.09.032
33. [33]
  Sreedaran S, Bharathi K S, Rahiman A K, et al. Polyhedron, 2008, 27:2931-2938 doi: 10.1016/j.poly.2008.06.025
34. [34]
  Sundaravadivel E, Kandaswamy M, Varghese B. Polyhedron, 2013, 61:33-44 doi: 10.1016/j.poly.2013.04.057
35. [35]
  Patel R N, Patel D K, Sondhiya V P, et al. Inorg. Chim. Acta, 2013, 405:209-217 doi: 10.1016/j.ica.2013.05.024
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