Citation: LI Song, GAN Xian-Xue, TANG Liang-Fu. Syntheses and Catalytic Properties of Metal Carbonyl Derivatives with Hydroxymethyl Functionalized Pyrazoles[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(8): 1573-1580. doi: 10.11862/CJIC.2018.183 shu

Syntheses and Catalytic Properties of Metal Carbonyl Derivatives with Hydroxymethyl Functionalized Pyrazoles

1.
State Key Laboratory of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071, China
2.
College of Chemistry and Chemical Engineering, Yibin University, Yibin, Sichuan 644007, China

Corresponding author: TANG Liang-Fu, lftang@nankai.edu.cn
Received Date: 10 April 2018
Revised Date: 22 April 2018

Figures(9)

Reaction of tungsten or molybdenum carbonyl with 3(5)-hydroxymethyl-5(3)-methylpyrazole (L¹), 4-hydroxymethylpyrazole (L²) and bis(3-hydroxymethyl-5-methylpyrazol-1-yl)methane (L³) yielded complexes LW(CO)₅ (L=L¹ or L²) and L³M(CO)₄ (M=Mo or W), respectively. These complexes have been fully characterized by NMR, IR and X-ray crystal structural analyses, indicating that they form 1D or 2D organometallic supramolecular architectures through O-H…O, N-H…O and O-H…OC-M hydrogen bonding interactions, and these structures are significantly affected by the relative position of the hydroxymethyl group on the pyrazole ring. In addition, these complexes show moderate catalytic activity for the cyclotrimerization reaction of phenylacetylene.
- N ligand,
- pyrazole,
- hydrogen bond,
- metal carbonyl complex,
- catalysis
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沈阳化工大学材料科学与工程学院沈阳 110142