Citation: CHEN Xin, XU Li, SHEN Zhi-Long, LIU Shuang-Yu, LI Hui, WANG Bo, XIE Jian, JIANG Yin-Zhu, LIU Hai-Zhen, SHENG Peng, ZHAO Guang-Yao. Preparation and Electrochemical Performance of the Nanostructure Mn-Based Prussian White[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(7): 1327-1332. doi: 10.11862/CJIC.2018.177 shu

Preparation and Electrochemical Performance of the Nanostructure Mn-Based Prussian White

CHEN Xin ¹ ,
XU Li ¹ ,
SHEN Zhi-Long ² ,
LIU Shuang-Yu ¹ ,
LI Hui ¹ ,
WANG Bo ¹ ,
XIE Jian ^2,, ,
JIANG Yin-Zhu ² ,
LIU Hai-Zhen ¹ ,
SHENG Peng ¹ ,
ZHAO Guang-Yao ¹

1.
State Key Laboratory of Advanced Transmission Technology, Global Energy Interconnection Research Institute Co. Ltd., Beijing 102211, China
2.
School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China

Corresponding author: XIE Jian, xiejian1977@zju.edu.cn
Received Date: 23 March 2018
Revised Date: 25 May 2018

Figures(6)

Rhombohedral phase Mn-based Prussian white materials were synthesized by high-temperature coprecipitation method and the effect of synthesis temperature on the microstructure and electrochemical performance of the products was investigated. It is found that the crystallinity, particle size and Na-insertion capacity increase obviously with the increasing synthesis temperature. At a synthesis temperature of 90℃, the first charge and discharge capacities of the product reach 142 and 139 mAh·g^-1 at 15 mA·g^-1. After 300 cycles at 30 mA·g^-1 and 600 cycles at 50 mA·g^-1, the discharge capacities are kept at 111 and 89 mAh·g^-1, respectively.
- sodium-ion batteries,
- cathode materials,
- Prussian white,
- electrochemical performance
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