Citation: KANG Xi-Yang, YANG Qing-Xiang, WANG Li-Jie, SONG Hai-Mei, ZHANG Yan, DONG Meng-Guo, CHEN Zhi-Jun. GO/Fe₃O₄/Organic Amine Composites: Preparation and Adsorption on Crystal Violet Dyes[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(8): 1463-1469. doi: 10.11862/CJIC.2018.172 shu

GO/Fe₃O₄/Organic Amine Composites: Preparation and Adsorption on Crystal Violet Dyes

Zhengzhou University of Light Industry, Zhengzhou 450000, China

Corresponding author: CHEN Zhi-Jun, chenzj@zzuli.edu.cn
Received Date: 8 March 2018
Revised Date: 17 April 2018

Figures(8)

Graphene oxide prepared by modified Hummers was modified by ethylenediamine, ethylenediamine and butanediamine/hexamethylenediamine miscibility. Fe₃O₄ was prepared by hydrothermal, and GO/Fe₃O₄/organic amine ternary complex system was prepared by physical mixing. The prepared samples were characterized by TEM, SEM, FT-IR, TG, XRD, VSM and XPS, the performance of ternary composite particles on the crystal violet dye adsorption was tested, and the adsorption properties of the ternary composite particles on the crystal violet dyes were studied. The results show that the prepared Fe₃O₄ have an average particle size of about 200 nm and a uniform particle size distribution; the graphene in the composite is a typical sheet-like structure; the doping of graphene and organic amine does not affect the spinel of Fe₃O₄ structure; the composite is superparamagnetic with M_s of 53.0 emu·g^-1. The results of adsorption showed that the maximum adsorption capacity of the ternary composite on the crystal violet dye increases with the increase of concentration, while the removal rate of crystal violet dye adsorption increases with the concentration of crystal violet dye decrease, and tend to a certain value. The best adsorption capacity of GO/Fe₃O₄ composites with 5:1 miscibility of ethylenediamine and hexamethylenediamine is:mass concentration of the crystal violet=400 mg·L^-1, maximum adsorption=164.3 mg·L^-1.
- graphene oxide,
- Fe₃O₄,
- organic amines,
- dye adsorption
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GO/Fe3O4/Organic Amine Composites: Preparation and Adsorption on Crystal Violet Dyes

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GO/Fe₃O₄/Organic Amine Composites: Preparation and Adsorption on Crystal Violet Dyes