Citation: LI Dong-Ping, WANG Qian, XIE Yi-Bu, ZHANG Jun, LIAN Qing-Yun, LI Yong-Xiu. Mononuclear Dy(Ⅲ) and Ho(Ⅲ) Complexes with Slow Magnetic Relaxation Behavior[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(8): 1547-1554. doi: 10.11862/CJIC.2018.170 shu

Mononuclear Dy(Ⅲ) and Ho(Ⅲ) Complexes with Slow Magnetic Relaxation Behavior

LI Dong-Ping ^1,, ,
WANG Qian ¹ ,
XIE Yi-Bu ¹ ,
ZHANG Jun ² ,
LIAN Qing-Yun ¹ ,
LI Yong-Xiu ^1,,

1.
Department of Chemistry, Nanchang University, Nanchang 330031, China
2.
Key Laboratory of Functional Molecule Design and Interface Process, Anhui Jianzhu University, Hefei 230022, China

Corresponding author: LI Dong-Ping, nculdp@126.com LI Yong-Xiu, yxli@ncu.edu.cn
Received Date: 8 March 2018
Revised Date: 3 May 2018

Figures(7)

Two new lanthanide complexes based on Schiff base ligand, namely[Dy(salen)₂]₃·3C₂H₉N₂·2CH₃OH (1) and[Ho(salen)₂]₃·3C₂H₉N₂·1.5CH₃OH (2), (H₂salen=N, N'-bis(3-methoxysalicylidene)ethylene-1, 2-diamine), have been synthesized and characterized. Single-crystal X-ray diffractions reveal that 1 and 2 crystallize in the same monoclinic space group C2, and have similar coordination environment around the metallic centers. Single molecule magnets (SMMs) behaviors have been observed in 1 and 2 with/without an applied magnetic field.
- Lanthanide complex,
- crystal structure,
- single-molecule magnet
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