Citation: GU Meng-Meng, CAI Wei-Quan, MA Tian. Preparation of Amino Modified Fe₃O₄@SiO₂ Composite by One-Pot Co-condensation Method with Enhanced Adsorption Performance Towards Cr(Ⅵ)[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(7): 1293-1302. doi: 10.11862/CJIC.2018.161 shu

Preparation of Amino Modified Fe₃O₄@SiO₂ Composite by One-Pot Co-condensation Method with Enhanced Adsorption Performance Towards Cr(Ⅵ)

GU Meng-Meng ¹ ,
CAI Wei-Quan ^1,2,, ,
MA Tian ¹

1.
School of Chemistry, Chemical Engineering and Life Sciences, Wuhan University of Technology, Wuhan 430070, China
2.
School of Chemistry and Chemical Engineering, Guangzhou University, Guangzhou 510006, China

Corresponding author: CAI Wei-Quan, cccaiwq@gzhu.edu.cn
Received Date: 29 January 2018
Revised Date: 17 April 2018

Figures(9)

A one-pot co-condensation method was used to prepare three kinds of silane coupling agents containing different amounts of N atom modified and SiO₂ coated magnetic adsorbents Fe₃O₄@SiO₂-xN (x=1, 2, 3). Here, 1N, 2N, and 3N represent 3-aminopropyltrimethoxysilane, N-β(aminoethyl)-γ-aminopropyltrimethoxysilane and 2-[2-(3-Trimethoxysilylpropylamino)ethylamino]ethylamine, respectively. Their physicochemical properties were comparatively characterized by XRD, SEM, N₂ adsorption-desorption, elemental analysis, FT-IR and ζ potential. The results showed that the modified composites present good spherical morphologies and higher isoelectric points, and their nitrogen contents show the trend of Fe₃O₄@SiO₂-1N < Fe₃O₄@SiO₂-2N < Fe₃O₄@SiO₂-3N. The static adsorption experiments towards Cr(Ⅵ) showed that the corresponding maximum adsorption capacity decreases with increasing nitrogen content, namely Fe₃O₄@SiO₂-1N (79.74 mg·g^-1) > Fe₃O₄@SiO₂-2N (63.05 mg·g^-1) > Fe₃O₄@SiO₂-3N (55.37 mg ·g^-1), and the mechanism on this trend was also analyzed. The adsorption experiments on simulated wastewater showed that the Fe₃O₄@SiO₂-1N can adsorb some kinds of heavy metal ions simultaneously, and can achieve magnetic separation within 30 s.
- one-pot co-condensation,
- amino modification,
- adsorption performance,
- hexavalent chromium,
- magnetic separation
1. [1]
  Ge J R, Deng K J, Cai W Q, et al. J. Colloid Interface Sci., 2013, 401:34-39 doi: 10.1016/j.jcis.2013.03.028
2. [2]
  Cai W Q, Tan L J, Yu J G, et al. Chem. Eng. J., 2014, 239:207-215 doi: 10.1016/j.cej.2013.11.011
3. [3]
  Yuan Q, Chi Y, Yu N, et al. Mater. Res. Bull., 2014, 49:279-284 doi: 10.1016/j.materresbull.2013.08.063
4. [4]
  WANG Jia-Hong, YIN Xiao-Long, JI Yan-Fen, et al. Chinese J. Inorg. Chem., 2015, 31(6):1185-1193
5. [5]
  Yoshitake H, Yokoi T, Tatsumi T. Chem. Lett., 2002:586-587
6. [6]
  Yoshitake H, Yokoi T, Tatsumi T. Chem. Mater., 2002, 14:4603-4610 doi: 10.1021/cm0202355
7. [7]
  Bois L, Bonhommé A, Ribes A, et al. Colloids Surfaces A Physicochem. Eng. Asp., 2003, 221:221-230 doi: 10.1016/S0927-7757(03)00138-9
8. [8]
  XU Zhen-Yao, Li Xin. Materials Review, 2015, 29(25):34-37
9. [9]
  LI Jian-Jun, BAO Xu, WU Xian-Feng, et al. Chinese J. Inorg. Chem., 2017, 33(3):383-388 doi: 10.11862/CJIC.2017.052
10. [10]
  Chung J, Chun J Y, Lee J, et al. J. Hazard. Mater., 2012, 239-240:183-191 doi: 10.1016/j.jhazmat.2012.08.063
11. [11]
  XUE Juan-Qin, XU Shang-Yuan, ZHU Qian-Wen, et al. Chinese J. Inorg. Chem., 2016, 32(9):1503-1511
12. [12]
  Deng H, Li X L, Peng Q, et al. J. Angew. Chemie-Int. Ed., 2005, 44:2782-2785 doi: 10.1002/(ISSN)1521-3773
13. [13]
  Luo L, Cai W Q, Zhou J B, et al. J. Hazard. Mater., 2016, 318:452-459 doi: 10.1016/j.jhazmat.2016.07.019
14. [14]
  Gui C X, Li J Q, Lv L L, et al. RSC Adv., 2015, 5:20440-20445 doi: 10.1039/C5RA02596F
15. [15]
  ZHAI Shang-Rui, LI Ming-Hui, KOU Zi-Nong, et al. Chinese J. Inorg. Chem., 2011, 27(7):1271-1276
16. [16]
  Yoshitake H, Yokoi T, Tatsumi T. Bull. Chem. Soc. Jpn., 2003, 76:847-852 doi: 10.1246/bcsj.76.847
17. [17]
  Zhang L X, Yu C C, Zhao W R, et al. J. Non-Cryst. Solids., 2007, 353:4055-4061 doi: 10.1016/j.jnoncrysol.2007.06.018
18. [18]
  Li J N, Wang L N, Qi T, et al. Microporous Mesoporous Mater., 2008, 110:442-450 doi: 10.1016/j.micromeso.2007.06.033
19. [19]
  Jin X, Cai W Q, Cai Z J. RSC Adv., 2017, 7:53076-53086 doi: 10.1039/C7RA10933D
20. [20]
  Xu C, Lu X L, Dai H L. Nanoscale Res. Lett., 2017, 12:234 doi: 10.1186/s11671-017-1986-z
21. [21]
  Roto R, Yusran Y, Kuncaka A. Appl. Surf. Sci., 2016, 377:30-36 doi: 10.1016/j.apsusc.2016.03.099
22. [22]
  Rafigh S M, Heydarinasab A. ACS Sustain. Chem. Eng., 2017, 5(11):10379-10386 doi: 10.1021/acssuschemeng.7b02388
23. [23]
  Zhao D L, Chen L L, Xu M W C, et al. ACS Sustain. Chem. Eng., 2017, 5(11):10290-10297 doi: 10.1021/acssuschemeng.7b02316
24. [24]
  Li X S, Fan Y H, Zhang S W, et al. Water Sci. Technol., 2017, 75:1399-1409 doi: 10.2166/wst.2017.009
25. [25]
  Hassan S, Yasin T, Imran Z, et al. J. Inorg. Organomet. Polym. Mater., 2016, 26:208-218 doi: 10.1007/s10904-015-0309-z
26. [26]
  Huang X, Hou X, Song F, et al. Environ. Sci. Technol., 2016, 50(4):1964-1972 doi: 10.1021/acs.est.5b05111
27. [27]
  Zhang J M, Zhai S R, Li S, et al. Chem. Eng. J., 2013, 215-216:461-471 doi: 10.1016/j.cej.2012.11.043
28. [28]
  Chen J H, Li G P, Liu Q L, et al. Chem. Eng. J., 2010, 165:465-473 doi: 10.1016/j.cej.2010.09.034
29. [29]
  WANG Jun, CAI Wei-Quan, WU Xuan-Jun. Chinese J. Inorg. Chem., 2014, 30(11):2564-2570
30. [30]
  Wang P, Du M L, Zhu H, et al. J. Hazard. Mater., 2015, 286:533-544 doi: 10.1016/j.jhazmat.2014.12.034
31. [31]
  ZHAO Fan, CHEN Xiu-Mei, ZHANG Wen-Gang. Bull Chin Ceramic Soc., 2017, 36(12):4302-4307
1. [1]
  Youlin SI , Shuquan SUN , Junsong YANG , Zijun BIE , Yan CHEN , Li LUO . Synthesis and adsorption properties of Zn(Ⅱ) metal-organic framework based on 3, 3', 5, 5'-tetraimidazolyl biphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1755-1762. doi: 10.11862/CJIC.20240061
2. [2]
  Kexin Yan , Zhaoqi Ye , Lingtao Kong , He Li , Xue Yang , Yahong Zhang , Hongbin Zhang , Yi Tang . Seed-Induced Synthesis of Disc-Cluster Zeolite L Mesocrystals with Ultrashort c-Axis: Morphology Control, Decoupled Mechanism, and Enhanced Adsorption. Acta Physico-Chimica Sinica, 2024, 40(9): 2308019-0. doi: 10.3866/PKU.WHXB202308019
3. [3]
  Ziyang Long , Quanzheng Li , Chengliang Zhang , Haifeng Shi . BiVO₄/WO_3-x S-scheme heterojunctions with amplified internal electric field for boosting photothermal-catalytic activity. Acta Physico-Chimica Sinica, 2025, 41(10): 100122-0. doi: 10.1016/j.actphy.2025.100122
4. [4]
  Xiaosong PU , Hangkai WU , Taohong LI , Huijuan LI , Shouqing LIU , Yuanbo HUANG , Xuemei LI . Adsorption performance and removal mechanism of Cd(Ⅱ) in water by magnesium modified carbon foam. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1537-1548. doi: 10.11862/CJIC.20240030
5. [5]
  Shasha Ma , Zujin Yang , Jianyong Zhang . Facile Synthesis of FeBTC Metal-Organic Gel and Its Adsorption of Cr₂O₇²⁻: A Physical Chemistry Innovation Experiment. University Chemistry, 2024, 39(8): 314-323. doi: 10.3866/PKU.DXHX202401008
6. [6]
  Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060
7. [7]
  Zhen Yao , Bing Lin , Youping Tian , Tao Li , Wenhui Zhang , Xiongwei Liu , Wude Yang . Visible-Light-Mediated One-Pot Synthesis of Secondary Amines and Mechanistic Exploration. University Chemistry, 2024, 39(5): 201-208. doi: 10.3866/PKU.DXHX202311033
8. [8]
  Runjie Li , Hang Liu , Xisheng Wang , Wanqun Zhang , Wanqun Hu , Kaiping Yang , Qiang Zhou , Si Liu , Pingping Zhu , Wei Shao . 氨基酸的衍生及手性气相色谱分离创新实验. University Chemistry, 2025, 40(6): 286-295. doi: 10.12461/PKU.DXHX202407059
9. [9]
  Linhan Tian , Changsheng Lu . Discussion on Sextuple Bonding in Diatomic Motifs of Chromium Family Elements. University Chemistry, 2024, 39(8): 395-402. doi: 10.3866/PKU.DXHX202401056
10. [10]
  Yanyan Zhao , Zhen Wu , Yong Zhang , Bicheng Zhu , Jianjun Zhang . Enhancing photocatalytic H₂O₂ production via dual optimization of charge separation and O₂ adsorption in Au-decorated S-vacancy-rich CdIn₂S₄. Acta Physico-Chimica Sinica, 2025, 41(11): 100142-0. doi: 10.1016/j.actphy.2025.100142
11. [11]
  Yang ZHOU , Lili YAN , Wenjuan ZHANG , Pinhua RAO . Thermal regeneration of biogas residue biochar and the ammonia nitrogen adsorption properties. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1574-1588. doi: 10.11862/CJIC.20250032
12. [12]
  Yukun Chang , Haoqin Huang , Baolei Wang . Preparation of Trans-Cinnamic Acid via “One-Pot” Protocol of Aldol Condensation-Hydrolysis Reaction: Recommending an Improved Organic Synthesis Experiment. University Chemistry, 2024, 39(4): 322-328. doi: 10.3866/PKU.DXHX202309095
13. [13]
  Renxiao Liang , Zhe Zhong , Zhangling Jin , Lijuan Shi , Yixia Jia . A Palladium/Chiral Phosphoric Acid Relay Catalysis for the One-Pot Three-Step Synthesis of Chiral Tetrahydroquinoline. University Chemistry, 2024, 39(5): 209-217. doi: 10.3866/PKU.DXHX202311024
14. [14]
  Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
15. [15]
  Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO₂ by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385
16. [16]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
17. [17]
  Yinuo Wang , Siran Wang , Yilong Zhao , Dazhen Xu . Selective Synthesis of Diarylmethyl Anilines and Triarylmethanes via Multicomponent Reactions: Introduce a Comprehensive Experiment of Organic Chemistry. University Chemistry, 2024, 39(8): 324-330. doi: 10.3866/PKU.DXHX202401063
18. [18]
  Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050
19. [19]
  Ruihu Wang , Aidang Lu . 新型铬(VI)检测试纸的制备及应用——介绍一个应用化学综合实验. University Chemistry, 2025, 40(8): 284-290. doi: 10.12461/PKU.DXHX202410102
20. [20]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(1653)
HTML views(308)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of Amino Modified Fe3O4@SiO2 Composite by One-Pot Co-condensation Method with Enhanced Adsorption Performance Towards Cr(Ⅵ)

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation of Amino Modified Fe₃O₄@SiO₂ Composite by One-Pot Co-condensation Method with Enhanced Adsorption Performance Towards Cr(Ⅵ)