Citation: LIU Ling, LI Rui-Yi, LAI Ting, LI Zai-Jun, GU Zhi-Guo. His-CDs@NaTbF₄: Synthesis and Application in Detection of Histidine and Cancer Cell Imaging[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(7): 1240-1248. doi: 10.11862/CJIC.2018.154 shu

His-CDs@NaTbF₄: Synthesis and Application in Detection of Histidine and Cancer Cell Imaging

School of Chemical and Material engineering, Jiangnan University, Wuxi, Jiangsu 214122, China

Corresponding author: LI Zai-Jun, zaijunli@jiangnan.edu.cn
Received Date: 23 January 2018
Revised Date: 5 April 2018

Figures(9)

Histidine-functionalized carbon dots(His-CDs) were used as a stabilizer for hydrothermal synthesis of His-CDs@NaTbF₄. The formed NaTbF₄ is a hexagonal crystal, its surface is covalently coated by carbon dots, and the crystal size is only in the range of 4~6 nm. The small size and rich of hydrophilic groups make the composite easy to disperse in water. The resulted dispersion is of excellent stability. As the absorption spectra of His-CDs and the fluorescence emission spectrum of NaTbF₄ exist a great overlap as well a short distance between His-CDs and NaTbF₄, their combination brings a remarkable fluorescence resonance energy transfer. The increase in the fluorescence intensity of the His-CDs@NaTbF₄ is more than 7 times that of sole carbon dots. The coordination of Cu²⁺ with carbon dots on NaTbF₄ surface results in an obvious fluorescence quenching process. However, the quenched fluorescence can be well recovered by adding histidine. Based on the above behaviors, one "On-Off" type fluorescence scheme was established for the detection of histidine. When the histidine concentration is in the range of 1.0×10^-6~2.0×10^-4 mol·L^-1, the peak fluorescence intensity linearly increases with the increase of histidine. The analytical method gives a detection limit of 3.8×10^-7 mol·L^-1, and it has been successfully applied in determination of histidine in human urine and Hela cell imaging.
- carbon nanomaterials,
- NaTbF₄,
- optical response,
- fluorescence resonance energy transfer,
- Cu²⁺
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His-CDs@NaTbF4: Synthesis and Application in Detection of Histidine and Cancer Cell Imaging

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His-CDs@NaTbF₄: Synthesis and Application in Detection of Histidine and Cancer Cell Imaging