Citation: HUANG Chao, ZHAI Ju, LUO Xuan, CHEN Yao, CHEN Dong-Mei, ZHU Bi-Xue. Syntheses and Crystal Structures of Hg(Ⅱ) and Cd(Ⅱ) Complexes Derived from a Bis(pyridylurea) Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(6): 1028-1034. doi: 10.11862/CJIC.2018.112 shu

Syntheses and Crystal Structures of Hg(Ⅱ) and Cd(Ⅱ) Complexes Derived from a Bis(pyridylurea) Ligand

Key laboratory of Macrocycle and Supramolecular Chemistry, Guizhou University, Guiyang 550025, China

Corresponding author: ZHU Bi-Xue, bxzhu@gzu.edu.cn
Received Date: 13 December 2017
Revised Date: 23 January 2018

Figures(6)

A bis(pyridylurea) ligand(L) was synthesized from the reaction of bis(2-aminophenyl) ether with 4-isocyanatopyridine. HgCl₂ and Cd(ClO₄)₂ reacted with L to give two coordination polymers {[Hg(L)Cl₂]·2DMF}_n (1) and {[Cd(L)₂(H₂O)₂](ClO₄)₂·4DMF·2H₂O·2CH₃OH}_n (2), respectively. The ligand was characterized by ¹H NMR, MS, FTIR, and elemental analysis. The structures of the ligand and two complexes were analyzed via single crystal X-ray diffraction, and the structural analysis indicated that both complexes show a one-dimensional chain structure. Their thermal stabilities and vapor adsorptions for MeOH were further investigated.CCDC: 1588599, L; 1588600, 1; 1588601, 2
- urea,
- complex,
- crystal structure,
- one dimension chain,
- absorption
1. [1]
  Wang X J, Huang T H, Tang L H, et al. CrystEngComm, 2010, 12:4356-4364 doi: 10.1039/c0ce00110d
2. [2]
  Jones C D, Tan J C, Lloyd G O. Chem. Commun., 2012, 48:2110-2112 doi: 10.1039/c2cc16691g
3. [3]
  Li S G, Wu B, Hao Y J, et al. CrystEngComm, 2010, 12:2001-2004 doi: 10.1039/b922566h
4. [4]
  Paul M, Adarsh N N, Dastidar P. Cryst. Growth Des., 2012, 12:4135-4143 doi: 10.1021/cg300649e
5. [5]
  Liang J J, Wu B, Jia C D, et al. CrystEngComm, 2009, 11:975-977 doi: 10.1039/b820640f
6. [6]
  Zhang R, Zhang Y L, Wang J M, et al. Chin. J. Chem., 2013, 31:679-683 doi: 10.1002/cjoc.201300342
7. [7]
  Adarsh N N, Dastidar P. Cryst. Growth Des., 2010, 10:483-487 doi: 10.1021/cg901159r
8. [8]
  Zhang R, Zhao Y X, Wang J M, et al. Cryst. Growth Des., 2014, 14:544-551 doi: 10.1021/cg401345z
9. [9]
  Hao Y J, Wu B, Li S G, et al. CrystEngComm, 2011, 13:6285-6292 doi: 10.1039/c1ce05662j
10. [10]
  Hao Y J, Wu B, Li S G, et al. CrystEngComm, 2011, 13:215-222 doi: 10.1039/C0CE00200C
11. [11]
  Khavasi H R, Fard M A. Cryst. Growth Des., 2010, 10:1892-1896 doi: 10.1021/cg100265d
12. [12]
  Burchell T J, Eisler D J, Puddephatt R J. Chem. Commun., 2004:944-945
13. [13]
  Yin Z M, Zhang Y H, He J Q, et al. Chem. Commun., 2007:2599-2601
14. [14]
  Zhang Q L, Huang Y L, Xu H, et al. J. Coord. Chem., 2017, 70(1):156-167 doi: 10.1080/00958972.2016.1250260
15. [15]
  DONG Yi-Tian, TU Bo, XU Hong, et al. Chinese J. Inorg. Chem., 2017, 33(4):651-658 doi: 10.11862/CJIC.2017.088
16. [16]
  Naranthatta M C, Das D, Tripathy D, et al. Cryst. Growth Des., 2012, 12:6012-6022 doi: 10.1021/cg301085t
17. [17]
  Wilshire J F K. Aust. J. Chem., 1988, 41(6):995-1001 doi: 10.1071/CH9880995
18. [18]
  Hernández-Balderas U, Andrade-López N, Alvarado-Rodríg-uez J G, et al. Polyhedron, 2015, 90:165-174 doi: 10.1016/j.poly.2015.02.004
19. [19]
  Sheldrick G M. SHELXL-97, Program for X-ray Crystal Structure Solution and Refinement, University of Göttingen, Germany, 1997.
1. [1]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
2. [2]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
3. [3]
  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192
4. [4]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
5. [5]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
6. [6]
  Hui Wang , Abdelkader Labidi , Menghan Ren , Feroz Shaik , Chuanyi Wang . 微观结构调控的g-C₃N₄在光催化NO转化中的最新进展：吸附/活化位点的关键作用. Acta Physico-Chimica Sinica, 2025, 41(5): 100039-. doi: 10.1016/j.actphy.2024.100039
7. [7]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
8. [8]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
9. [9]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
10. [10]
  Zuozhong Liang , Lingling Wei , Yiwen Cao , Yunhan Wei , Haimei Shi , Haoquan Zheng , Shengli Gao . Exploring the Development of Undergraduate Scientific Research Ability in Basic Course Instruction: A Case Study of Alkali and Alkaline Earth Metal Complexes in Inorganic Chemistry. University Chemistry, 2024, 39(7): 247-263. doi: 10.3866/PKU.DXHX202310103
11. [11]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
12. [12]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
13. [13]
  Weina Wang , Fengyi Liu , Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029
14. [14]
  Junqiao Zhuo , Xinchen Huang , Qi Wang . Symbol Representation of the Packing-Filling Model of the Crystal Structure and Its Application. University Chemistry, 2024, 39(3): 70-77. doi: 10.3866/PKU.DXHX202311100
15. [15]
  Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060
16. [16]
  Wenyan Dan , Weijie Li , Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, 2024, 39(3): 63-69. doi: 10.3866/PKU.DXHX202302060
17. [17]
  Linjie ZHU , Xufeng LIU . Electrocatalytic hydrogen evolution performance of tetra-iron complexes with bridging diphosphine ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 321-328. doi: 10.11862/CJIC.20240207
18. [18]
  Yongzhi LI , Han ZHANG , Gangding WANG , Yanwei SUI , Lei HOU , Yaoyu WANG . A two-dimensional metal-organic framework for the determination of nitrofurantoin and nitrofurazone in aqueous solution. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 245-253. doi: 10.11862/CJIC.20240307
19. [19]
  Jinfeng Chu , Lan Jin , Yu-Fei Song . Exploration and Practice of Flipped Classroom in Inorganic Chemistry Experiment: a Case Study on the Preparation of Inorganic Crystalline Compounds. University Chemistry, 2024, 39(2): 248-254. doi: 10.3866/PKU.DXHX202308016
20. [20]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(419)
HTML views(89)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142