Citation: BAI Feng-Ying, WANG Xue-Min, QU Chang-Qing, WANG Yu, XING Yong-Heng. Syntheses, Structures and Antibacterial Activity of Lead Complexes with Nitrogen Heterocyclic Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(4): 639-646. doi: 10.11862/CJIC.2018.095 shu

Syntheses, Structures and Antibacterial Activity of Lead Complexes with Nitrogen Heterocyclic Ligand

1.
College of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, Liaoning 116029, China
2.
College of Life Science, Liaoning Normal University, Dalian, Liaoning 116081, China

Corresponding author: BAI Feng-Ying, baifengying2003@163.com
Received Date: 21 September 2017
Revised Date: 20 January 2018

Figures(10)

Two lead complexes, [Pb(phen)(NO₃)(H₂O)]NO₃ (1) and[Pb(phen)₂(NO₃)]NO₃ (2) (phen=1, 10-phenanthro-line) were synthesized via a solution synthesis method at room temperature. They were characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction. In complex 1, the central metal Pb(Ⅱ) is tetra-coordinated to form a distorted tetrahedral geometry. In complex 2, the central metal Pb(Ⅱ) is hexa-coordinated to form a distorted octahedral geometry. By extensive intermolecular hydrogen bonds, complex 1 is connected into 1D chain supramolecular structure, while complex 2 is assembled into 3D supramolecular network. Complexes 1 and 2 have a strong inhibitory effect on Escherichia coli and Golden staph. The higher the concentration, the stronger the inhibitory effect. And the activity of complex 2 is superior to that of complex 1.
- lead complexes,
- 1, 10-phenanthroline,
- solution synthesis,
- crystal structure,
- antifungal activity
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1.
沈阳化工大学材料科学与工程学院沈阳 110142