Citation: CHEN Dan-Dan, LI Guang-She, FAN Jian-Ming, LI Bao-Yun, ZHANG Dan, FENG Tao, LI Guo-Hua, LI Li-Ping. Differentiating the Integrated Structure from Lithium Rich Layer Oxide by ex situ Raman Spectroscopy: an Effective Method to Predict the Activation of Li₂MnO₃[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(4): 703-711. doi: 10.11862/CJIC.2018.093 shu

Differentiating the Integrated Structure from Lithium Rich Layer Oxide by ex situ Raman Spectroscopy: an Effective Method to Predict the Activation of Li₂MnO₃

1.
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012, China
2.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: LI Li-Ping, lipingli@jlu.edu.cn
Received Date: 14 November 2017
Revised Date: 25 January 2018

Figures(6)

The Li_1.2Mn_0.6Ni_0.2O₂ cathode was prepared by five synthesis routes:sol-gel, high temperature solid, coprecipitation, hydrothermal and solvothermal method. The analysis of Raman spectrum shows that the co-precipitation sample is solid solution structure, while the other four samples are composite structures formed at different scales. The results of electrochemical tests for as-prepared samples show obviously different performance, especially the capacity from the activation of Li₂MnO₃ during the first charging process (> 4.5 V). The co-precipitation sample with solid solution structure shows the highest capacity from the activation of Li₂MnO₃. Therefore, we can establish the connection between electrochemical performance and two-phase integration modes. Different integration modes affect the activation capacity of Li₂MnO₃, leading to different electrochemical properties.
- lithium ion battery,
- Li-rich cathode material,
- Raman spectrosopy,
- activation degree
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Differentiating the Integrated Structure from Lithium Rich Layer Oxide by ex situ Raman Spectroscopy: an Effective Method to Predict the Activation of Li2MnO3

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通讯作者: 陈斌, bchen63@163.com

Differentiating the Integrated Structure from Lithium Rich Layer Oxide by ex situ Raman Spectroscopy: an Effective Method to Predict the Activation of Li₂MnO₃