Citation: JIANG Zheng-Jing, YIN Jing-Zhou, LI Rong-Qing, ZHANG Zai-Chao, LU Lu-De. Syntheses, Structures and Luminescent Properties of Two Zinc(Ⅱ) Coordination Polymers Constructed by Acetate and Pyridyl-Containing Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(4): 719-727. doi: 10.11862/CJIC.2018.086 shu

Syntheses, Structures and Luminescent Properties of Two Zinc(Ⅱ) Coordination Polymers Constructed by Acetate and Pyridyl-Containing Ligands

1.
Jiangsu Key Laboratory for the Chemistry of Low-Dimensional Materials, Huaiyin Normal University, Huai'an, Jiangsu 223300, China
2.
Key Laboratory for Soft Chemistry and Functional Materials of Ministry of Education, Nanjing University of Science and Technology, Nanjing 210094, China

Corresponding author: JIANG Zheng-Jing, jiangzj@hytc.edu.cn
Received Date: 19 June 2017
Revised Date: 23 January 2018

Figures(6)

Two coordination polymers, [Zn(CH₃COO)₂(INH)]_n (INH=isonicotinic acid hydrazid; isoniazid) (1) and[Zn(CH₃COO)₂(2-APy)]_n (2-APy=2-aminopyridine) (2) have been synthesized in DMF solution and structurally characterized by elemental analysis, IR spectra, single-crystal and powder X-ray diffractions. Structural analyses reveal that polymer 1 exhibits a 2-dimensional (2D) infinite layer framework, and the resulting 2D structure is interconnected by hydrogen-bond interactions to lead to a 3D supramolecular architecture. It crystallizes in the monoclinic system, space group P2₁/c, with cell parameters a=0.914 44(17) nm, b=0.161 86(3) nm, c=0.871 75(16) nm, β=96.181(3)°, V=1.282 8(4) nm³, Z=4. Polymer 2 is an infinite 1D zig-zag chain. Polymer 2 crystallizes in the triclinic system, space group P1, with cell parameters a=0.747 0(4) nm, b=0.814 5(5) nm, c=1.895 7(11) nm, α=88.276(8)°, β=86.202(8)°, γ=84.334(8)°, V=1.144 9(11) nm³, Z=2. The solid-state luminescent properties of two polymers have also been investigated at room temperature.
- zinc,
- coordination polymer,
- crystal structure,
- luminescent property
1. [1]
  Liu K, Shi W, Cheng P. Coord. Chem. Rev., 2015, 289-290:74-122 doi: 10.1016/j.ccr.2014.10.004
2. [2]
  Zhou H C, Kitagawa S. Chem. Soc. Rev., 2014, 43:5415-5418 doi: 10.1039/C4CS90059F
3. [3]
  O'Keeffe M, Yaghi O M. Chem. Rev., 2012, 112:675-702 doi: 10.1021/cr200205j
4. [4]
  Kumar U, Thomas J, Thirupathi N. Inorg. Chem., 2010, 49:62-72 doi: 10.1021/ic901100z
5. [5]
  Zhang X, Hou L, Liu B, et al. Cryst. Growth Des., 2013, 13:3177-3187 doi: 10.1021/cg400579w
6. [6]
  Feng X, Ma L F, Liu L, et al. Cryst. Growth Des., 2013, 13:4469-4479 doi: 10.1021/cg4009587
7. [7]
  LI Hong-Jin, GAO Zhu-Qing, GU Jin-Zhong. Chinese J. Inorg. Chem., 2014, 30(11):2615-2620
8. [8]
  Huang Y M, Zheng X F, Duan J G, et al. Dalton Trans., 2014, 43:6811-6818 doi: 10.1039/c4dt00230j
9. [9]
  Kesanli B, Cui Y, Smith M R, et al. Angew. Chem. Int. Ed., 2005, 44:72-75 doi: 10.1002/(ISSN)1521-3773
10. [10]
  Zhang H M, Fu W F, Gan X, et al. Dalton Trans., 2008:6817-6824
11. [11]
  Xie Y B, Gan L, Saudo E C, et al. CrystEngComm, 2015, 17:4136-4142 doi: 10.1039/C5CE00531K
12. [12]
  Hong D Y, Hwang Y K, Serre C, et al. Adv. Funct. Mater., 2009, 19:1537-1552 doi: 10.1002/adfm.v19:10
13. [13]
  Karmakar A, Rubio G M D M, Silva M F C G, et al. Cryst. Growth Des., 2015, 15:4185-4197 doi: 10.1021/acs.cgd.5b00948
14. [14]
  Horcajada P, Chalati T, Serre C, et al. Nat. Mater., 2010, 9:172-178 doi: 10.1038/nmat2608
15. [15]
  Kumar U, Thomas J, Nagarajan R, et al. Inorg. Chim. Acta, 2011, 372:191-199 doi: 10.1016/j.ica.2011.01.083
16. [16]
  Lan Y Q, Jiang H L, Li S L, et al. Inorg. Chem., 2012, 51:7484-7491 doi: 10.1021/ic202635a
17. [17]
  Zhao D, Timmons D J, Yuan D, et al. Acc. Chem. Res., 2011, 44:123-133 doi: 10.1021/ar100112y
18. [18]
  Hou L, Li D, Shi W J, et al. Inorg. Chem., 2005, 44:7825-7832 doi: 10.1021/ic050558d
19. [19]
  Chen S S, Sheng L Q, Zhao Y, et al. Cryst. Growth Des., 2016, 16:229-241 doi: 10.1021/acs.cgd.5b01133
20. [20]
  Lee T W, Lau J P K, Wong W T, et al. Polyhedron, 2004, 23:999-1002 doi: 10.1016/j.poly.2003.12.020
21. [21]
  Freitas M C R, António J M S, Ziolli R L, et al. Polyhedron, 2011, 30:1922-1926 doi: 10.1016/j.poly.2011.04.027
22. [22]
  Jiang Z J, Zhao P S, Li R Q, et al. J. Chem. Crystallogr., 2013, 43:463-470 doi: 10.1007/s10870-013-0442-x
23. [23]
  JIANG Zheng-Jing, LU Lu-De, WU Xiao-Dong, et al. Chinese J. Inorg. Chem., 2009, 25(4):746-750
24. [24]
  Sheldrick G M. SADABS, Program for Empirical Absorption Correction of Area Detector Data, University of Göttingen, Germany, 1996.
25. [25]
  Sheldrick G M. SHELXS-97, Program for X-ray Crystal Structure Solution, University of Göttingen, Germany, 1996.
26. [26]
  Sheldrick G M. SHELXL-97, Program for the Refinement of Crystal Structure, University of Göttingen, Germany, 1996.
27. [27]
  Kreno L E, Leong K, Farha O K, et al. Chem. Rev., 2012, 112:1105-1125 doi: 10.1021/cr200324t
28. [28]
  Su Z, Fan J, Chen M, et al. Cryst. Growth Des., 2011, 11:1159-1169 doi: 10.1021/cg101365v
29. [29]
  Wan X Y, Jiang F L, Chen L, et al. CrystEngComm, 2015, 17:3829-3837 doi: 10.1039/C5CE00420A
30. [30]
  Wu G, Wang X F, Okamura T, et al. Inorg. Chem., 2006, 45:8523-8532 doi: 10.1021/ic060493u
1. [1]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
2. [2]
  Xiumei LI , Linlin LI , Bo LIU , Yaru PAN . Syntheses, crystal structures, and characterizations of two cadmium(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 613-623. doi: 10.11862/CJIC.20240273
3. [3]
  Gaofeng WANG , Shuwen SUN , Yanfei ZHAO , Lixin MENG , Bohui WEI . Structural diversity and luminescence properties of three zinc coordination polymers based on bis(4-(1H-imidazol-1-yl)phenyl)methanone. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 849-856. doi: 10.11862/CJIC.20230479
4. [4]
  Zhenghua ZHAO , Qin ZHANG , Yufeng LIU , Zifa SHI , Jinzhong GU . Syntheses, crystal structures, catalytic and anti-wear properties of nickel(Ⅱ) and zinc(Ⅱ) coordination polymers based on 5-(2-carboxyphenyl)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 621-628. doi: 10.11862/CJIC.20230342
5. [5]
  Weizhong LING , Xiangyun CHEN , Wenjing LIU , Yingkai HUANG , Yu LI . Syntheses, crystal structures, and catalytic properties of three zinc(Ⅱ), cobalt(Ⅱ) and nickel(Ⅱ) coordination polymers constructed from 5-(4-carboxyphenoxy)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1803-1810. doi: 10.11862/CJIC.20240068
6. [6]
  Chao LIU , Jiang WU , Zhaolei JIN . Synthesis, crystal structures, and antibacterial activities of two zinc(Ⅱ) complexes bearing 5-phenyl-1H-pyrazole group. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1986-1994. doi: 10.11862/CJIC.20240153
7. [7]
  Xiaoling WANG , Hongwu ZHANG , Daofu LIU . Synthesis, structure, and magnetic property of a cobalt(Ⅱ) complex based on pyridyl-substituted imino nitroxide radical. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 407-412. doi: 10.11862/CJIC.20240214
8. [8]
  Anqiu LIU , Long LIN , Dezhi ZHANG , Junyu LEI , Kefeng WANG , Wei ZHANG , Junpeng ZHUANG , Haijun HAO . Synthesis, structures, and catalytic activity of aluminum and zinc complexes chelated by 2-((2,6-dimethylphenyl)amino)ethanolate. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 791-798. doi: 10.11862/CJIC.20230424
9. [9]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004
10. [10]
  Jing REN , Ruikui YAN , Xiaoli CHEN , Huali CUI , Hua YANG , Jijiang WANG . Synthesis and fluorescence sensing of a highly sensitive and multi-response cadmium coordination polymer. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 574-586. doi: 10.11862/CJIC.20240287
11. [11]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
12. [12]
  Yao HUANG , Yingshu WU , Zhichun BAO , Yue HUANG , Shangfeng TANG , Ruixue LIU , Yancheng LIU , Hong LIANG . Copper complexes of anthrahydrazone bearing pyridyl side chain: Synthesis, crystal structure, anticancer activity, and DNA binding. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 213-224. doi: 10.11862/CJIC.20240359
13. [13]
  Jia JI , Zhaoyang GUO , Wenni LEI , Jiawei ZHENG , Haorong QIN , Jiahong YAN , Yinling HOU , Xiaoyan XIN , Wenmin WANG . Two dinuclear Gd(Ⅲ)-based complexes constructed by a multidentate diacylhydrazone ligand: Crystal structure, magnetocaloric effect, and biological activity. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 761-772. doi: 10.11862/CJIC.20240344
14. [14]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
15. [15]
  Lulu DONG , Jie LIU , Hua YANG , Yupei FU , Hongli LIU , Xiaoli CHEN , Huali CUI , Lin LIU , Jijiang WANG . Synthesis, crystal structure, and fluorescence properties of Cd-based complex with pcu topology. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 809-820. doi: 10.11862/CJIC.20240171
16. [16]
  Zhenzhong MEI , Hongyu WANG , Xiuqi KANG , Yongliang SHAO , Jinzhong GU . Syntheses and catalytic performances of three coordination polymers with tetracarboxylate ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1795-1802. doi: 10.11862/CJIC.20240081
17. [17]
  Shuwen SUN , Gaofeng WANG . Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 613-620. doi: 10.11862/CJIC.20230368
18. [18]
  Dongdong YANG , Jianhua XUE , Yuanyu YANG , Meixia WU , Yujia BAI , Zongxuan WANG , Qi MA . Design and synthesis of two coordination polymers for the rapid detection of ciprofloxacin based on triphenylpolycarboxylic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2466-2474. doi: 10.11862/CJIC.20240266
19. [19]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
20. [20]
  Yan XU , Suzhi LI , Yan LI , Lushun FENG , Wentao SUN , Xinxing LI . Structure variation of cadmium naphthalene-diphosphonates with the changing rigidity of N-donor auxiliary ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 395-406. doi: 10.11862/CJIC.20240226

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(380)
HTML views(66)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142