Citation: ZHANG Hui-Juan, ZHANG Dong-Jie, ZHANG Cong-Yun, LIU Ya-Qing. 3D Silver Dendritic Thin Film: Controllable Growth and Application in Surface Enhanced Raman Spectroscopy[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(3): 597-604. doi: 10.11862/CJIC.2018.085 shu

3D Silver Dendritic Thin Film: Controllable Growth and Application in Surface Enhanced Raman Spectroscopy

Shanxi Province Key Laboratory of Functional Nanocomposites, School of Materials Science and Engineering, North University of China, Taiyuan 030051, China

Corresponding author: ZHANG Cong-Yun, z.congyun@nuc.edu.c LIU Ya-Qing, lyq@nuc.edu.cn
Received Date: 28 November 2017
Revised Date: 10 January 2018

Figures(6)

A novel surface enhanced Raman spectroscopy (SERS) substrate was fabricated via a simple galvanic displacement reaction, where large scale of silver dendritic were uniformly and symmetrically formed on anodic aluminum oxide (AAO) membrane. The morphology, distribution and density of these silver dendritic films could be tuned easily just by controlling the reaction time as well as the concentration of AgNO₃. Such active SERS substrate exhibits extremely high sensitivity, excellent reproducibility and good stability. Raman signal sensitivity for rhodamine 6G (R6G) was tested as low as 1×10^-11 mol·L^-1. Additionally, the as-synthesized robust substrate displays good stability under an ambient condition for several months. This 3D eco-friendly AAO membrane based substrate provides not only high density of SERS hot spots, but also a very large area for capturing target analytes. It has potential applications for the detection of trace organic contaminants in the environment.
- silver dendritic films,
- SERS,
- galvanic displacement reaction
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