Citation: YAO Yu-Han, YUAN Zhen-Tao, ZHANG Yan-Nan, YU Xiao-Hua, RONG Ju, MENG Kun, ZHAN Zhao-Lin. Surface Modification and Electrochemical Lithium Storage Performance of TiO₂-Anatase Nanotube Arrays with CuO[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(4): 662-668. doi: 10.11862/CJIC.2018.079 shu

Surface Modification and Electrochemical Lithium Storage Performance of TiO₂-Anatase Nanotube Arrays with CuO

YAO Yu-Han ^1,2 ,
YUAN Zhen-Tao ² ,
ZHANG Yan-Nan ² ,
YU Xiao-Hua ^1,2,, ,
RONG Ju ^2,3 ,
MENG Kun ² ,
ZHAN Zhao-Lin ²

1.
National Engineering Research Center of Solid Waste Resource, Kunming University of Science and Technology, Kunming 650093, China
2.
Faculty of Materials Science & Engineering, Kunming University of Science and Technology, Kunming 650093, China
3.
Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China

Corresponding author: YU Xiao-Hua, xiaohua_y@163.com
Received Date: 1 November 2017
Revised Date: 9 January 2018

Figures(8)

Anodic oxidation and hydrothermal method were jointly used to prepare CuO/TiO₂ negative material which was synthesized from ethylene glycol, ammonium fluoride, hydrochloric acid, cupric chloride and sodium nitrate. Morphology, element distribution, valence state, microcosmic phase composition of the samples were investigated by scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy dispersive spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD). Furthermore, the electrochemical lithium insertion properties of CuO/TiO₂ were tested by the use of battery charge and discharge testing system and electrochemical workstation. The results show that there are particulates arrange the surface of the anatase TiO₂ nanotube. The nanometer size was 4 nm×10 nm. The as prepared CuO/TiO₂ displays plummy electric properties of initial discharge and charge capacities of 550 and 490 mAh·g^-1 at the rate of 0.3C. respectively. After 50 cycles the reserve capacities is 320 mAh·g^-1.
- surface modification,
- TiO₂-anatase nanotube array,
- CuO,
- electrochemical performance,
- microscopic structure
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Surface Modification and Electrochemical Lithium Storage Performance of TiO₂-Anatase Nanotube Arrays with CuO