Citation: WANG Hong-Yan, ZHAO Yan-Peng, LÜ Wen-Miao, LU Ning-Yue, SHI Xiu-Feng, FAN Bin-Bin, LI Rui-Feng. Comparison on Catalytic Performance of 1, 10-Phenanthroline Cu(Ⅱ) Complexes Encapsulated in Zeolite-Y and Hierarchical Zeolite-Y[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(3): 483-489. doi: 10.11862/CJIC.2018.061 shu

Comparison on Catalytic Performance of 1, 10-Phenanthroline Cu(Ⅱ) Complexes Encapsulated in Zeolite-Y and Hierarchical Zeolite-Y

College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, China

Corresponding author: FAN Bin-Bin, fanbinbin@tyut.edu.cn
Received Date: 27 May 2017
Revised Date: 28 November 2017

Figures(7)

1, 10-phenanthroline Cu(Ⅱ) complexes (CuPhen) were successfully encapsulated in the cavities of conventional zeolite-Y and hierarchical zeolite-Y hosts obtained via post-treatment by the flexible ligand method. The physicochemical properties of the prepared hybrids were characterized by X-ray diffraction, TEM, Fourier transform infrared spectroscopy, Ultraviolet-visible spectroscopy and N₂ adsorption-desorption. A comparative study on the catalytic performances of the Cu complexes encapsulated in the different zeolite-Y hosts was carried out with different substrates. The results show that the hierarchical zeolite-Y exhibites superior host performance to the conventional zeolite-Y, and Cu complexes encapsulated in hierarchical zeolite-Y has higher catalytic activities in various cycloalkane oxidation reactions than those in the conventional zeolite-Y using H₂O₂ as the oxidant. In addition, Cu complexes encapsulated in the hierarchical zeolite-Y exhibites the same stability and reusability as those in the conventional zeolite-Y.
- hierarchical Y zeolites,
- metal complexes,
- encapsulation,
- catalytic oxidation
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