Citation: LEI Xue, CHEN Yun-Zhou, LI Yuan-Xiang, JIA Li-Hui, CHEN Yun-Feng. Two Mono- and Binuclear Zn(Ⅱ) Coordination Complexes Containing 4-Pyridyl-NH-1, 2, 3-triazole Ligand: Syntheses, Structures and Photoluminescence Properties[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(3): 545-550. doi: 10.11862/CJIC.2018.060 shu

Two Mono- and Binuclear Zn(Ⅱ) Coordination Complexes Containing 4-Pyridyl-NH-1, 2, 3-triazole Ligand: Syntheses, Structures and Photoluminescence Properties

School of Chemistry and Environmental Engineering, Wuhan Institute of Technology, Wuhan 430073, China

Corresponding author: JIA Li-Hui, jialihui715@wit.edu.cn CHEN Yun-Feng, yfchen@wit.edu.cn
Received Date: 18 September 2017
Revised Date: 22 November 2017

Figures(5)

Two Zn(Ⅱ) coordination complexes, [Zn₂(L)₂Cl₄] (1) and[Zn(L)₂Cl₂]·2H₂O (2) (L=4-pyridiyl-NH-1, 2, 3-triazole) are synthesized by reaction of ZnCl₂·2H₂O with rigid ligand L. Single crystal diffraction reveals that 1 and 2 crystallizes in space groups, P1 and P2₁/n, respectively. In the structures of 1 and 2, supramolecular interactions play important role in forming 3D structures. Photoluminescent properties of 1 and 2 in solid state and dilute methanolic solutions have been investigated in detail.
- hydrothermal synthesis,
- coordination chemistry,
- crystal structure,
- photoluminescence properties
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