Citation: LI Yun-Xia, XIA Yan, LÜ Ling-Zhi, FENG Yun-Long. Two Lead(Ⅱ)-Organic Coordination Polymers Based on N-Acetic-5-oxygen-nicotinic Acid: Syntheses, Structures and Fluorescence Properties[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(3): 539-544. doi: 10.11862/CJIC.2018.058 shu

Two Lead(Ⅱ)-Organic Coordination Polymers Based on N-Acetic-5-oxygen-nicotinic Acid: Syntheses, Structures and Fluorescence Properties

1.
College of Pharmaceutics and Material Engineering, Jinhua Polytechnic, Jinhua, Zhejiang 321007, China
2.
Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004, China

Corresponding author: LI Yun-Xia, lyxjinhua@163.com
Received Date: 13 September 2017
Revised Date: 30 November 2017

Figures(8)

Two new lead coordination polymers, namely, [Pb₄(μ₃-O)₂L₂]_n (1), [Pb₃(μ₄-O)₂L]_n (2) (H₂L=N-acetic-5-oxygen-nicotinic acid) have been prepared by the reaction of Pb(NO₃)₂ with H₂L and characterized by elemental analysis, IR and single crystal X-ray diffraction. Polymer 1 crystallizes in the monoclinic C2/c space group, and features[Pb₄(μ₃-O)₂]_n rigid inorganic chains, which are further linked by L^2- ligands to form a 3D framework. Polymer 2 crystallizes in the orthorhombic P2₁2₁2₁ space group, and displays a 3D framework with[Pb₃(μ₄-O)₂]_n inorganic chains. The thermodynamic stability and fluorescence properties of 2 were investigated.
- coordination polymer,
- N-acetic-5-oxygen-nicotinic acid,
- crystal structure,
- fluorescence property
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沈阳化工大学材料科学与工程学院沈阳 110142