Citation: ZHANG Zai-Chao, TANG Guo-Dong, TANG Ting-Ting, Lance F. Culnane, ZHANG Yu, SONG Ying-Lin, LI Rong-Qing, XIA Min. Hydrothermal Synthesis of Mn(Ⅱ) Complex Based on Imidazole Ligand: Structure, Theoretical Calculation and Third-Order Nonlinear Optical Properties[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(2): 367-374. doi: 10.11862/CJIC.2018.054 shu

Hydrothermal Synthesis of Mn(Ⅱ) Complex Based on Imidazole Ligand: Structure, Theoretical Calculation and Third-Order Nonlinear Optical Properties

1.
Jiangsu Key Laboratory for Chemistry of Low-Dimensional Materials, School of Chemistry and Chemical Engineering, Huaiyin Normal University, Huai'an, Jiangsu 223300, China
2.
Department of Chemistry and Biochemistry, University of Colorado, Boulder, CO 80309, USA
3.
School of Physical Science and Technology, Suzhou University, Suzhou, Jiangsu 215006, China

Corresponding author: TANG Guo-Dong, hysytanggd@hotmail.com SONG Ying-Lin, ylsong@suda.edu.cn
Received Date: 7 July 2017
Revised Date: 23 December 2017

Figures(5)

The complex Mn[(IPB)₂Cl₂]·4H₂O (IPB=4-(1H-imidazo[4, 5-f] [1, 10]phenanthrolin-2-yl) benzaldehyde) was synthesized and characterized by elemental analysis, IR, UV-Vis, X-ray diffraction and the Z-scan technique. The X-ray diffraction results revealed that the complex crystallizes in Pnna space group of orthorhombic crystal system. The nonlinear optical properties were measured by the Z-scan technique and yielded a normalized transmittance of about 93% for the complex with a 45 μJ pulse at the focal point, and the nonlinear absorption coefficient, β, is -4.5×10^-11 m·W^-1, the nonlinear refractive index, γ, is 1.0×10^-19 m²·W^-1. The complex shows a self-focusing property. In the range of the UV-Vis spectrum, the maximum absorption wavelength is at 282 nm for the complex.
- imidazole complex,
- crystal structure,
- X-ray diffraction,
- nonlinear optical properties,
- Z-scan technique
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