Citation: LIN Jian-Jun, LIU Zhen, LÜ Ling-Zhi, FENG Yun-Long. Two Lanthanide Metal-Organic-Frameworks Based on a Tetra-carboxylate Ligand for Sensing of Small Organic Molecules[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(2): 230-236. doi: 10.11862/CJIC.2018.037 shu

Two Lanthanide Metal-Organic-Frameworks Based on a Tetra-carboxylate Ligand for Sensing of Small Organic Molecules

Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004, China

Corresponding author: FENG Yun-Long, sky37@zjnu.cn
Received Date: 19 June 2017
Revised Date: 13 November 2017

Figures(5)

5, 5'-(1H-1, 2, 4-triazole-1, 4-diyl)diisophthalic acid (H₄L) was used to synthesize two microporous three-dimension metal-organic-frameworks(MOFs) with lanthanide metal salts by intermolecular self-assembly:{[Ho₃L₂(H₂O)₆]OH·2DMF}_n (1), {[Tb₃L₂(H₂O)₆]OH·2DMF}_n (2). Single-crystal X-ray diffraction revealed the Ln-MOFs are isomorphous and belong to monoclinic C2/m space group. Three Ln(Ⅲ) ions are connected through eight carboxylic groups to form a trinuclear[Ln₃(COO)₈] SBU. The SBU polyhedrons share edges with each other generating a 1D inorganic chain, and the chains are further connected by the L^4- ligands to construct a 3D framework. The luminescence intensity of 2 can be modulated by organic small molecules, and 2 exhibited the significant quenching in nitrobenzene, which indicates that 2 is potential luminescent sensing material for nitro explosives.
- 5, 5'-(1H-1, 2, 4-triazole-1, 4-diyl)diisophthalic acid,
- rare-earth metal,
- metal-organic framework,
- crystal structure,
- luminescent property
1. [1]
  Meyer L V, Schönfeld F, Müller-Buschbaum K. Chem. Commun., 2014, 50:8093-8108 doi: 10.1039/c4cc00848k
2. [2]
  Feng X, Ling X, Liu L, et al. Dalton Trans., 2013, 42:10292-10303 doi: 10.1039/c3dt50810b
3. [3]
  Wang X, Zhang L, Yang J, et al. J. Mater. Chem. A, 2015, 3:12777-12785 doi: 10.1039/C5TA00061K
4. [4]
  Zhao X, Wong M, Mao C, et al. J. Am. Chem. Soc., 2014, 136:12572-12575 doi: 10.1021/ja5067306
5. [5]
  Yang Q Y, Pan M, Wei S C, et al. Inorg. Chem., 2015, 54:5707-5716 doi: 10.1021/acs.inorgchem.5b00271
6. [6]
  Zhang J, Zheng B, Zhao T, et al. Cryst. Growth Des., 2014, 14:2394-2400 doi: 10.1021/cg500114k
7. [7]
  Yan W, Zhang C, Chen S, et al. ACS Appl. Mater. Interfaces, 2017, 9:1629-1634 doi: 10.1021/acsami.6b14563
8. [8]
  Yao Q, Gómez A B, Su J, et al. Chem. Mater., 2015, 27:5332-5339 doi: 10.1021/acs.chemmater.5b01711
9. [9]
  Zhou L, Deng W, Wang Y, et al. Inorg. Chem., 2016, 55:6271-6277 doi: 10.1021/acs.inorgchem.6b00928
10. [10]
  Xu B, Cheng Y, Hu H, et al. CrystEngComm, 2016, 18:4613-4626 doi: 10.1039/C6CE00681G
11. [11]
  Bag P, Wang X, Cao R. Dalton Trans., 2015, 44:11954-11962 doi: 10.1039/C5DT01598G
12. [12]
  Xu H, Liu F, Cui Y, et al. Chem. Commun., 2011, 47:3153-3155 doi: 10.1039/c0cc05166g
13. [13]
  Xiao Y, Wang L, Cui Y, et al. J. Alloys Compd., 2009, 484:601-604 doi: 10.1016/j.jallcom.2009.05.004
14. [14]
  Ma D, Wang W, Li Y, et al. CrystEngComm, 2010, 12:4372-4377 doi: 10.1039/c0ce00135j
15. [15]
  LIU Zhen, CHEN Xiao, FENG Yun-Long. Chinese J. Inorg. Chem., 2016, 32:1413-1420
16. [16]
  Yang Y, Jiang F, Liu C, et al. Cryst. Growth Des., 2016, 16:2266-2276 doi: 10.1021/acs.cgd.6b00060
17. [17]
  Wang H, Qin J, Huang C, et al. Dalton Trans., 2016, 45:12710-12716 doi: 10.1039/C6DT02321E
18. [18]
  Sheldrick G M. SHELXTL 97, Program for X-ray Crystal Structure Solution and Refinement, University of Göttingen, Germany, 1997.
19. [19]
  Spek A L. Acta Crystallogr., Sect. D:Biol. Crystallogr., 2009, D65:148-155
1. [1]
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2. [2]
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18. [18]
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20. [20]
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