Citation: HU Zhi-Yong, DENG Wei, LU Hong-Lin, HUANG Hai-Ping, YU Shu-Yan. Mononuclear Assemblies with Metal-Metal Interaction: Syntheses and Catalytical Performance in Suzuki-Coupling Reaction[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(2): 387-396. doi: 10.11862/CJIC.2018.036 shu

Mononuclear Assemblies with Metal-Metal Interaction: Syntheses and Catalytical Performance in Suzuki-Coupling Reaction

1.
Beijing Key Laboratory for Green Catalysis and Separation, Laboratory for Self-Assembly Chemistry, Department of Chemistry and Chemical Industry, College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100124, China
2.
Tianjin Minxiang Biomedical Co., Ltd., Tianjin 300350, China

Corresponding author: HUANG Hai-Ping, selfassembly@bjut.edu.cn
Received Date: 1 October 2017
Revised Date: 8 November 2017

Figures(5)

A series of mononuclear complexes named[(bpy)Pd(L)]NO₃ (1·NO₃·H₂O), [(bpy)Pt(L)]NO₃ (2·NO₃·H₂O), and[(phen)Pd(L)]NO₃ (3·NO₃·H₂O) (where bpy=2, 2'-bipyridine, phen=1, 10-phenanthroline) have been self-assembled through a directed coordination approach that involves spontaneous deprotonation of the 1, 3-diphenylpropane-1, 3-dione (L) in aqueous solution driven by coordination effect. NO₃^- in these assemblies can be effectively replaced by PF₆^- in a solution of KPF₆. All of these new mononuclear complexes have been fully characterized by ¹H NMR, ¹³C NMR and ESI-MS analysis. X-ray diffraction analysis of 1·PF₆·CH₃CN clearly shows that a dimeric crystal structure is formed by the π-π stacking interactions and weak intramolecular Pd…Pd (0.322 4 nm) interactions. More importantly, all of these three assemblies can be employed as a new kind of high-efficiency catalysts for Suzuki-coupling reaction.
- metal-metal interaction,
- self-assembly,
- catalysis,
- Suzuki-coupling reaction
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1.
沈阳化工大学材料科学与工程学院沈阳 110142