Citation: WANG Yu, CUI Yang-Zhe, LIU Min, WANG Meng-Qin, GENG Wen-Xiao, LI Zhong-Feng, JIN Qiong-Hua. Syntheses, Characterization and Luminescent Properties of Silver(Ⅰ) Complexes Based on Diphosphine Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(2): 381-386. doi: 10.11862/CJIC.2018.034 shu

Syntheses, Characterization and Luminescent Properties of Silver(Ⅰ) Complexes Based on Diphosphine Ligands

1.
Department of Chemistry, Capital Normal University, Beijing 100048, China
2.
College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China

Corresponding author: JIN Qiong-Hua, jinqh@cnu.edu.cn
Received Date: 1 August 2017
Revised Date: 10 November 2017

Figures(7)

Two novel silver(Ⅰ) complexes[Ag(XANTphos)]BF₄ (1) and [Ag₂Cl₂(DPEphos)₂]·2CH₂Cl₂ (2) (XANTphos=9, 9-dimethyl-4, 5-bis(diphenylphosphanyl)xanthene, DPEphos=bis(2-(diphenylphosphino)phenyl)ether) have been synthesized in mixed solvent CH₃OH and CH₂Cl₂ and characterized by IR, single-crystal X-ray diffraction, ¹H NMR spectroscopy and fluorescence spectra. Complex 1 is of a mononuclear complex, which was generated by the reaction of AgBF₄ and XANTphos with dmp (neocuproine) in 1:1:1 molar ratio. The central ion Ag(Ⅰ) forms a ring by the chelating bisphosphine ligand (XANTphos). While complex 2 is of a binuclear complex, which was obtained by the reaction of AgCl with DPEphos in 1:1 molar ratio. In the asymmetric unit of complex 2, each DPEphos ligand chelates one silver(Ⅰ) cation with a free dichloromethane. The luminescent spectra show that all the emissions of the complexes 1 and 2 are assigned to ligand centered π-π^* transition.
- 9, 9-dimethyl-4, 5-bis(diphenylphosphanyl)xanthene,
- bis(2-(diphenylphosphino)phenyl)ether,
- silver(Ⅰ),
- fluorescence
1. [1]
  Cook A W, Nguyen T D, Buratto W R, et al. Inorg. Chem., 2016, 55:12435-12440 doi: 10.1021/acs.inorgchem.6b02385
2. [2]
  Streitberger M, Schmied A, Hoy R, et al. Dalton Trans., 2016, 45:11644-11649 doi: 10.1039/C6DT00945J
3. [3]
  Zavras A, Khairallah G N, Connell T U, et al. Inorg. Chem., 2014, 53:7429-7437 doi: 10.1021/ic5007499
4. [4]
  LI Zhong-Feng, ZHANG Yan-Ru, CUI Yang-Zhe, et al. Chinese J. Inorg. Chem., 2015, 31(8):1637-1643
5. [5]
  Najafabadia B K, Corrigan J F. Chem. Commun., 2015, 51:665-667 doi: 10.1039/C4CC06560C
6. [6]
  Lim S H, Cohen S M. Inorg. Chem., 2013, 52:7862-7872 doi: 10.1021/ic302840x
7. [7]
  Jaros S W, Silva M C, Florek M, et al. Inorg. Chem., 2016, 55:5886-5894 doi: 10.1021/acs.inorgchem.6b00186
8. [8]
  Rajput G, Yadav M K, Drew M G B, et al. Inorg. Chem., 2015, 54:2572-2579 doi: 10.1021/ic502688h
9. [9]
  Kranenburg M, van der Burgt Y, Kamer P, et al. Organome-tallics, 1995, 14:3081-3089 doi: 10.1021/om00006a057
10. [10]
  Kaeser A, Moudam O, Accorsi G, et al. Eur. J. Inorg. Chem., 2014:1345-1355
11. [11]
  Freudenmann D, Feldmann C. Inorg. Chim. Acta, 2011, 375:311-313 doi: 10.1016/j.ica.2011.05.006
12. [12]
  Moudam O, Tsipis A C, Kommanaboyina S, et al. RSC Adv., 2015, 5:95047-95053 doi: 10.1039/C5RA12921D
13. [13]
  Gao S, Li Z F, Liu M, et al. Polyhedron, 2014, 83:10-15 doi: 10.1016/j.poly.2014.03.028
14. [14]
  Cui Y Z, Yuan Y, Han H L, et al. Z. Anorg. Allg. Chem., 2016, 642(18):953-959 doi: 10.1002/zaac.201600193
15. [15]
  Zhang Y R, Cui Y Z, Jin Q H, et al. Polyhedron, 2017, 122:86-98 doi: 10.1016/j.poly.2016.10.033
16. [16]
  Kaltzoglou A, Cox P J, Aslanidis P. Polyhedron, 2007, 26:1634-1642 doi: 10.1016/j.poly.2006.12.006
17. [17]
  ZHANG Yan-Ru, WANG Meng-Qin, CUI Yang-Zhe, et al. Chinese J. Inorg. Chem., 2015, 31(10):2089-2094
18. [18]
  SMART and SAINT, Siemens Analytical X-ray Instrument Inc., Madison, WI, 1996.
19. [19]
  Sheldrick G M. SHELXS-97 and SHELXL-97, Madison, WI, USA, 1997.
20. [20]
  Sheldrick G M. SHELXTL NT Ver. 5. 1, University of Göttingen, Germany, 1997.
21. [21]
  Li X X, Gong Y Q, Zhao H X, et al. Inorg. Chem., 2014, 53:12127-12134 doi: 10.1021/ic501978u
22. [22]
  Lee J, Kang Y, Cho N S, et al. Cryst.Growth Des., 2016, 16:996-1004 doi: 10.1021/acs.cgd.5b01544
23. [23]
  Song L L, Jin Q H, Cui L N, et al. Inorg. Chim. Acta, 2010, 363:2425-2429 doi: 10.1016/j.ica.2010.03.075
24. [24]
  Li J B, Fan W W, Liu M, et al. J. Mol. Struct., 2015, 1085:235-241 doi: 10.1016/j.molstruc.2014.12.068
25. [25]
  Sculfort S, Braunstein P. Chem. Soc. Rev., 2011, 40:2741-2760 doi: 10.1039/c0cs00102c
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沈阳化工大学材料科学与工程学院沈阳 110142