Citation: ZHU Ya-Bo, TANG Xiao-Tong, DUAN Lian-Wei, LIU Wan-Ying, CAO Xing-Xing, FENG Pei-Zhong. Mn⁴⁺ Doped Co₃O₄ Nanofibers: Preparation by Electro-Spinning and Electrochemical Performance[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(2): 317-324. doi: 10.11862/CJIC.2018.030 shu

Mn⁴⁺ Doped Co₃O₄ Nanofibers: Preparation by Electro-Spinning and Electrochemical Performance

School of Materials Science and Engineering, China University of Mining and Technology, Xuzhou, Jiangsu 221116, China

Corresponding author: ZHU Ya-Bo, zhuyabo@163.com
Received Date: 27 July 2017
Revised Date: 3 November 2017

Figures(7)

Mn⁴⁺ doped Co₃O₄ nanofibers with n_Co:n_Mn=20:2 have large surface with 68 m²·g^-1. Under the current density of 1 A·g^-1, the 20:2 sample has a maximum capacitance of 585 F·g^-1, which is obviously higher than that of pure cobalt oxide nanofiber~416 F·g^-1. After 500 cycles of charging and discharging, the specific capacitance of 20:2 sample is maintained about 82.6%, but that of the pure cobalt oxide nanofiber is only 76.4%. The mechanism of performance improvement of the composite fibers was analyzed concretely.
- electro-spinning method,
- Mn⁴⁺ doped Co₃O₄ nanofibers,
- characterization,
- electro-chemical property
1. [1]
  Zhang Y, Feng H, Wu X B, et al. Int. J. Hydrogen Energy, 2009, 34(11):4889-4899 doi: 10.1016/j.ijhydene.2009.04.005
2. [2]
  Zhang F, Yuan C Z, Lu X J, et al. J. Power Sources, 2012, 203:250-256 doi: 10.1016/j.jpowsour.2011.12.001
3. [3]
  HUANG Guo-Yong, XU Sheng-Ming, YANG Yue, et al. Chinese J. Inorg. Chem., 2016, 32(10):1693-1703
4. [4]
  LI Si-Heng, LIU Qing-He, QI Li, et al. Chin. J. Anal. Chem., 2012, 40(3):339-346
5. [5]
  Wang R, Qi J Q, Sui Y W, et al. Mater. Lett., 2016, 184:181-184 doi: 10.1016/j.matlet.2016.08.049
6. [6]
  Liang Y R, Yang Y Y, Hu Z G, et al. Int. J. Electrochem. Sci., 2016, 11(5):4092-4109
7. [7]
  Wang S S, Li Q H, Chen M, et al. Electrochim. Acta, 2016, 215:473-482 doi: 10.1016/j.electacta.2016.08.138
8. [8]
  Ni J P, Lu W C, Zhang L M, et al. J. Phys. Chem. C, 2009, 113(1):54-60 doi: 10.1021/jp806454r
9. [9]
  Zuo L X, Jiang L P, Abdel-Halim E S, et al. Ultrason. Sonochem., 2017, 35:219-225 doi: 10.1016/j.ultsonch.2016.09.021
10. [10]
  Ke B, Wang J X, Li D R, et al. J. Mater. Sci.-Mater. Electron., 2017, 28:418-425 doi: 10.1007/s10854-016-5538-6
11. [11]
  Venkateswarlu P, Umeshbabu E, Kumar U N, et al. J. Colloid Interface Sci., 2017, 503:17-27 doi: 10.1016/j.jcis.2017.05.007
12. [12]
  Feng M Y, Zhang G W, Du Q H, et al. Ionics, 2017, 23:1637-1643 doi: 10.1007/s11581-017-2013-1
13. [13]
  Liu J P, Jiang J, Cheng C W, et al. Adv. Mater., 2011, 23(18):2076-2081 doi: 10.1002/adma.v23.18
14. [14]
  Su L H, Wang Y, Sha Y F, et al. J. Alloys Compd., 2016, 656:585-589 doi: 10.1016/j.jallcom.2015.10.006
15. [15]
  Huang M, Zhang Y X, Li F, et al. J. Power Sources, 2014, 252:98-106 doi: 10.1016/j.jpowsour.2013.12.030
16. [16]
  SUN Li-Ping, ZHAO Hui, WANG Wen-Xue, et al. Chinese J. Inorg. Chem., 2014, 30(4):757-762
17. [17]
  Hou D, Tao H S, Zhu X Z, et al. Appl. Surf. Sci., 2017, 419:580-585 doi: 10.1016/j.apsusc.2017.05.080
18. [18]
  Nguyen V H, Charmaine L, Neuyen H N, et al. Mater. Lett., 2017, 208:102-106 doi: 10.1016/j.matlet.2017.05.013
19. [19]
  Du H H, Zhou C, Li H, et al. New J. Chem., 2017, 41:5161-5167 doi: 10.1039/C6NJ03828J
20. [20]
  Benhaddad L, Makhloufi L, Messaoudi B, et al. J. Mater. Sci. Technol., 2011, 27(7):585-593 doi: 10.1016/S1005-0302(11)60112-6
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Mn⁴⁺ Doped Co₃O₄ Nanofibers: Preparation by Electro-Spinning and Electrochemical Performance