Citation: MA Hong-Bin, MA Ling-Juan, HOU Meng-Ning, YUE Ming-Bo. Rod-like CuFe₄O_x Composite:Controllable Synthesis and Catalytic Performance in Isoamylic Alcohol Dehydrogenation[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(12): 2193-2200. doi: 10.11862/CJIC.2017.275 shu

Rod-like CuFe₄O_x Composite:Controllable Synthesis and Catalytic Performance in Isoamylic Alcohol Dehydrogenation

School of Chemistry and Chemical Engineering, Qufu Normal University, Qufu, Shandong 273165, China

Corresponding author: MA Ling-Juan, malingjuan@qfnu.edu.cn
Received Date: 12 July 2017
Revised Date: 22 September 2017

Figures(8)

Uniformly rod-shaped CuFe₄O_x catalysts were controllably fabricated through a liquid-phase precipitation method. The phase structure, morphology and reduction properties of the catalyst were characterized by in-situ powder X-ray diffraction (XRD), high resolution transmission electron microscope (HRTEM) and temperature-programmed reduction (TPR). Cu⁰/Fe₃O₄-nanorod obtained from the reduction of rod-shaped CuFe₄O_x structure and the surface phase composition of Cu⁰/Fe₃O₄ was detailed studied by in-situ X-ray photoelectron spectroscopy (XPS). CuFe₄O_x composites with rod-shape were prepared by an aqueous precipitation method that means after stirring time at 120℃ for 3 h, Na₂CO₃ solution was added until pH value equal to 9. In this case, the most uniform CuFe₄O_x composites with rod-shape were obtained. Cu⁰/Fe₃O₄-nanorod catalyst presents higher activity and stability for the dehydrogenation of isoamylic alcohol than Cu/Fe₃O₄-nanoparticles, due to Cu⁰ nanoparticles supported on the rod-shaped Fe₃O₄ exhibits higher structure stability.
- CuFe₄O_x composite,
- XPS,
- dehydrogenation of isoamylic alcohol
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Rod-like CuFe₄O_x Composite:Controllable Synthesis and Catalytic Performance in Isoamylic Alcohol Dehydrogenation