Citation: WANG Hong-Zhi, LEI Xian-Chao, CHEN Xiong-Zhuo, YAO Su-Wei, ZHANG Wei-Guo. Template Synthesis and Photoelectrochemical Properties of CdSe Nanomaterials[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(12): 2271-2277. doi: 10.11862/CJIC.2017.264 shu

Template Synthesis and Photoelectrochemical Properties of CdSe Nanomaterials

Sugiyama Laboratory of Surface Technology, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, China

Corresponding author: ZHANG Wei-Guo, zwg@tju.edu.cn
Received Date: 21 February 2017
Revised Date: 10 September 2017

Figures(8)

CdSe nanotube and nanowire arrays have been fabricated in the porous anodic aluminum oxide template (AAO) by electrodeposition method. The morphology, structure and composition of the materials were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD) and energy dispersive X-ray spectroscopy (EDS) respectively. The photocatalytic activities of the materials were investigated by UV-vis absorption spectroscopy. The results show that CdSe nanotube and nanowire arrays can be fabricated by controlling the deposited charge. The CdSe nanomaterials are composed of mixed phase nature of hexagonal and cubic phase. It can be observed that the crystal transformation from the cubic phase to the hexagonal phase after the annealing process at 350℃. Meanwhile, the open-circuit potential differences (V_oc) of the annealed CdSe nanomaterials have significantly increased, and photocurrent density at 0 V (versus SCE) has also improved, indicating that the annealed nanomaterials show better photoelectrochemical properties. Furthermore, the absorption edge and band gap of CdSe nanowires are about 710 nm and 1.85 eV respectively, CdSe nanotube arrays exhibit a better photoelectrochemical performance and a higher activity than nanowires for photodegrading rhodamine B with the degradation efficiency of 53.93% under a Xe lamp irradiation for 7 h. In addition, the growth mechanism of CdSe nanomaterials in the pore walls of AAO template has also been discussed.
- CdSe nanomaterials,
- anneal,
- photocatalysis,
- electrodeposition
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